Literature DB >> 22170755

Sequential continuous flow processes for the oxidation of amines and azides by using HOF·MeCN.

Christopher B McPake1, Christopher B Murray, Graham Sandford.   

Abstract

The generation and use of the highly potent oxidising agent HOF·MeCN in a controlled single continuous flow process is described. Oxidations of amines and azides to corresponding nitrated systems by using fluorine gas, water and acetonitrile by sequential gas-liquid/liquid-liquid continuous flow procedures are reported.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2011        PMID: 22170755     DOI: 10.1002/cssc.201100423

Source DB:  PubMed          Journal:  ChemSusChem        ISSN: 1864-5631            Impact factor:   8.928


  1 in total

1.  Mechanism for Six-Electron Aryl-N-Oxygenation by the Non-Heme Diiron Enzyme CmlI.

Authors:  Anna J Komor; Brent S Rivard; Ruixi Fan; Yisong Guo; Lawrence Que; John D Lipscomb
Journal:  J Am Chem Soc       Date:  2016-06-03       Impact factor: 15.419

  1 in total

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