Literature DB >> 22168263

Pd-catalyzed olefination of furans and thiophenes with allyl esters.

Yuexia Zhang1, Zejiang Li, Zhong-Quan Liu.   

Abstract

A direct Pd(II)-catalyzed olefination of furans and thiophenes with allyl esters is demonstrated. Under the typical conditions, the dehydrogenative Heck coupling reactions of heteroarenes with allylic esters proceeded via a β-H elimination rather than a β-OAc elimination to give the corresponding γ-substituted allylic esters.
© 2011 American Chemical Society

Entities:  

Year:  2011        PMID: 22168263     DOI: 10.1021/ol203013p

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Preparation of tetrasubstituted olefins using mono or double aerobic direct C-H functionalization strategies: importance of steric effects.

Authors:  Nicolas Gigant; François Quintin; Jan-E Bäckvall
Journal:  J Org Chem       Date:  2015-02-16       Impact factor: 4.354

2.  Catalyst-Controlled Regiodivergent C-H Alkynylation of Thiophenes*.

Authors:  Arup Mondal; Manuel van Gemmeren
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-09       Impact factor: 16.823

  2 in total

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