Literature DB >> 22125129

Catalytic C-H bond activation at nanoscale Lewis acidic aluminium fluorides: H/D exchange reactions at aromatic and aliphatic hydrocarbons.

Martin H G Prechtl1, Michael Teltewskoi, Anton Dimitrov, Erhard Kemnitz, Thomas Braun.   

Abstract

Nanoscopic amorphous Lewis acidic aluminium fluorides, such as aluminium chlorofluoride (ACF) and high-surface aluminium fluoride (HS-AlF(3)), are capable of activating C-H bonds of aliphatic hydrocarbons. H/D exchange reactions are catalysed under mild conditions (40 °C).
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2011        PMID： 22125129     DOI： 10.1002/chem.201102853

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  3 in total

1.  A HF Loaded Lewis-Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions.

Authors:  Maëva-Charlotte Kervarec; Erhard Kemnitz; Gudrun Scholz; Svemir Rudić; Thomas Braun; Christian Jäger; Adam A L Michalchuk; Franziska Emmerling
Journal:  Chemistry       Date:  2020-05-26       Impact factor: 5.236

2.  Activation of pentafluoropropane isomers at a nanoscopic aluminum chlorofluoride: hydrodefluorination versus dehydrofluorination.

Authors:  Maëva-Charlotte Kervarec; Thomas Braun; Mike Ahrens; Erhard Kemnitz
Journal:  Beilstein J Org Chem       Date:  2020-10-23       Impact factor: 2.883

3.  Cation-Ligand Complexation Mediates the Temporal Evolution of Colloidal Fluoride Nanocrystals through Transient Aggregation.

Authors:  Reut Mashiach; Haim Weissman; Liat Avram; Lothar Houben; Yael Diskin-Posner; Vaishali Arunachalam; Michal Leskes; Boris Rybtchinski; Amnon Bar-Shir
Journal:  Nano Lett       Date:  2021-11-23       Impact factor: 11.189
  3 in total

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