Literature DB >> 22113959

Sensing of aqueous fluoride anions by cationic stibine-palladium complexes.

Casey R Wade1, Iou-Sheng Ke, François P Gabbaï.   

Abstract

Turn on the lantern! The stibine donor ligand of a cationic palladium complex acts as a Lewis acid and reacts with a fluoride anion to afford the corresponding fluorostiboranyl-palladium species (see scheme). Bindung of the fluoride anion to the antimony center induces a change in denticity of the triphosphine unit and leads to a bright-orange trigonal-bipyramidal d(8) lantern complex.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2011        PMID： 22113959     DOI： 10.1002/anie.201106242

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  Synthetic anionophores for basic anions as "presumably, OH⁻/Cl⁻ antiporters": from the synthetic ion channels to multi-ion hopping, anti-Hofmeister selectivity, and strong positive AMFE.

Authors:  Sofya Kostina Berezin
Journal:  J Membr Biol       Date:  2014-06-11       Impact factor: 1.843

2.  Fluorinated antimony(v) derivatives: strong Lewis acidic properties and application to the complexation of formaldehyde in aqueous solutions.

Authors:  Daniel Tofan; François P Gabbaï
Journal:  Chem Sci       Date:  2016-07-11       Impact factor: 9.825

3.  Structural Evidence for Pnictogen-Centered Lewis Acidity in Cationic Platinum-Stibine Complexes Featuring Pendent Amino or Ammonium Groups.

Authors:  Roberta R Rodrigues; François P Gabbaï
Journal:  Molecules       Date:  2021-04-01       Impact factor: 4.411

4.  Synthesis and Structure of Mono-, Di-, and Trinuclear Fluorotriarylbismuthonium Cations.

Authors:  Jennifer Kuziola; Marc Magre; Nils Nöthling; Josep Cornella
Journal:  Organometallics       Date:  2022-05-09       Impact factor: 3.837

5.  Binuclear Triphenylantimony(V) Catecholates through N-Donor Linkers: Structural Features and Redox Properties.

Authors:  Andrey I Poddel'sky; Ivan V Smolyaninov; Aleksandra I Shataeva; Evgenii V Baranov; Georgy K Fukin
Journal:  Molecules       Date:  2022-10-01       Impact factor: 4.927

Review 6.  Catalysis using transition metal complexes featuring main group metal and metalloid compounds as supporting ligands.

Authors:  Jun Takaya
Journal:  Chem Sci       Date:  2020-09-10       Impact factor: 9.825

7.  IDTI Dyes for Fluoride Anion Chemosensors.

Authors:  Xinqiang Yuan; Xin Shi; Cheng Wang; Yuqian Du; Peng Jiang; Xizhou Jiang; Yongqiang Sui; Xiaoli Hao; Lin Li
Journal:  Front Chem       Date:  2020-10-23       Impact factor: 5.221
  7 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.