| Literature DB >> 22113228 |
Christian Unkelbach1, Bors C Abele, Klaus Lehmen, Daniel Schildbach, Benedikt Waerder, Kerstin Wild, Carsten Strohmann.
Abstract
A dimeric α-silylated ethyllithium compound is presented featuring stereogenic metalated carbon centres with defined configurations. It can be generated by diastereoselective deprotonation of the corresponding ethylsilane. Reaction with Me(3)SnCl proceeds under inversion and the transfer of the stereoinformation is possible with dr's of up to 97:3. This journal is © The Royal Society of Chemistry 2012Entities:
Year: 2011 PMID： 22113228 DOI： 10.1039/c1cc15872d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222