| Literature DB >> 22109845 |
Karin Haiser1, Benjamin P Fingerhut, Korbinian Heil, Andreas Glas, Teja T Herzog, Bert M Pilles, Wolfgang J Schreier, Wolfgang Zinth, Regina de Vivie-Riedle, Thomas Carell.
Abstract
The importance of a backbone: The mechanism of formation of Dewar lesions has been investigated by using femtosecond IR spectroscopy and ab initio calculations of the exited state. The 4π electrocyclization is rather slow, occurs with an unusual high quantum yield, and--surprisingly--is controlled by the phosphate backbone.Entities:
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Year: 2011 PMID： 22109845 DOI： 10.1002/anie.201106231
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336