Literature DB >> 22107608

Synthesis of the C1-C20 and C15-C27 segments of aplyronine A.

Wan Pyo Hong1, Mohammad N Noshi, Ahmad El-Awa, Philip L Fuchs.   

Abstract

The synthesis of C1-C20 and C15-C27 segments of Aplyronine A is described. Oxidative cleavage of cyclic vinyl sulfones has been used to prepare key fragments of Aplyronine A. Key precursors are united by Horner-Wadsworth-Emmons and Julia-Kociensky olefination for the respective elaboration of the C1-C20 and C15-C27 segments.

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Year:  2011        PMID： 22107608     DOI： 10.1021/ol2024746

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

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