Literature DB >> 22094959

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state.

Xikui Fang1, Paul Kögerler, Manfred Speldrich, Helmut Schilder, Marshall Luban.   

Abstract

Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn(III)(3)Mn(IV)O(4)] core into a centrosymmetric [Mn(III)(6)Mn(IV)O(8)] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn(4)O(4)] cubane-based single-molecule magnets.

Entities:  

Year:  2011        PMID: 22094959     DOI: 10.1039/c1cc15520b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Sensitive biological detection with a soluble and stable polymeric paramagnetic nanocluster.

Authors:  Benjamin Kim; Anne H Schmieder; Allen J Stacy; Todd A Williams; Dipanjan Pan
Journal:  J Am Chem Soc       Date:  2012-06-13       Impact factor: 15.419

2.  Large Magnetic Polyoxometalates Containing the Cobalt Cubane '[CoIIICo 3II (OH)3(H2O)6-m(PW9O34)]3-' (m = 3 or 5) as a Subunit.

Authors:  Yan Duan; Juan M Clemente-Juan; Carlos Giménez-Saiz; Eugenio Coronado
Journal:  Front Chem       Date:  2018-06-19       Impact factor: 5.221

  2 in total

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