Tetra-μ(2)-acetato-diaqua-bis-(μ(2)-2-{[1,3-dihy-droxy-2-(oxidometh-yl)propan-2-yl]imino-meth-yl}phenolato)trimanganese(II,III) acetonitrile disolvate dihydrate.

In the title complex, [Mn(II)Mn(III) (2)(C(11)H(13)NO(4))(2)(CH(3)CO(2))(4)(H(2)O)(2)]·2CH(3)CN·2H(2)O, there are two Mn(III) and one Mn(II) atoms. The Mn(II) atom lies on an inversion center and the Mn(III)-Mn(II)-Mn(III) angle is therefore 180°, as required by crystallographic symmetry. The Mn(III) and Mn(II) atoms are six-coordinated in a distorted octa-hedral geometry. In the crystal, complex mol-ecules and solvent mol-ecules are linked into a three-dimensional network by O-H⋯O and O-H⋯N hydrogen-bonding inter-actions.

Related literature

For the importance of Mn complexes in magnetism and biomimetics, see: Stamatatos & Christou (2009 ▶); Ferreira et al. (2004 ▶). For properties and structures of related compounds, see: Kessissoglou et al. (1992 ▶); Liu et al. (2010 ▶).

Experimental

Crystal data

[Mn3(C11H13NO4)2(C2H3O2)4(H2O)2]·2C2H3N·2H2O

M = 1001.62

Monoclinic,

a = 10.6032 (5) Å

b = 12.2114 (6) Å

c = 19.1608 (9) Å

β = 118.856 (3)°

V = 2172.89 (18) Å3

Z = 2

Mo Kα radiation

μ = 0.94 mm−1

T = 293 K

0.20 × 0.20 × 0.20 mm

Data collection

Bruker APEXII CCD diffractometer

53356 measured reflections

5507 independent reflections

3798 reflections with I > 2σ(I)

R int = 0.086

Refinement

R[F 2 > 2σ(F 2)] = 0.047

wR(F 2) = 0.133

S = 1.07

5507 reflections

294 parameters

7 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.72 e Å−3

Δρmin = −0.61 e Å−3

Data collection: APEX2 (Bruker, 1996 ▶); cell refinement: SAINT (Bruker, 1996 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536811027899/pv2425sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811027899/pv2425Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Mn3(C11H13NO4)2(C2H3O2)4(H2O)2]·2C2H3N·2H2O	F(000) = 1038
Mr = 1001.62	Dx = 1.531 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 9948 reflections
a = 10.6032 (5) Å	θ = 2.4–28.4°
b = 12.2114 (6) Å	µ = 0.94 mm−1
c = 19.1608 (9) Å	T = 293 K
β = 118.856 (3)°	Block, black
V = 2172.89 (18) Å3	0.20 × 0.20 × 0.20 mm
Z = 2

Bruker APEXII CCD diffractometer	3798 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.086
graphite	θmax = 28.6°, θmin = 2.1°
φ and ω scans	h = −14→14
53356 measured reflections	k = −16→16
5507 independent reflections	l = −25→25

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.047	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.133	H atoms treated by a mixture of independent and constrained refinement
S = 1.07	w = 1/[σ2(Fo2) + (0.0525P)2 + 2.7933P] where P = (Fo2 + 2Fc2)/3
5507 reflections	(Δ/σ)max = 0.024
294 parameters	Δρmax = 0.72 e Å−3
7 restraints	Δρmin = −0.61 e Å−3

	x	y	z	Uiso*/Ueq
C1	−0.1569 (3)	0.8511 (2)	0.84008 (18)	0.0317 (6)
C2	−0.2687 (4)	0.8090 (3)	0.8512 (2)	0.0419 (8)
H2A	−0.2506	0.7888	0.9020	0.050*
C3	−0.4053 (4)	0.7971 (3)	0.7877 (2)	0.0548 (10)
H3A	−0.4788	0.7710	0.7966	0.066*
C4	−0.4352 (4)	0.8235 (4)	0.7105 (3)	0.0604 (11)
H4	−0.5274	0.8140	0.6680	0.072*
C5	−0.3275 (4)	0.8635 (3)	0.6980 (2)	0.0475 (9)
H5	−0.3469	0.8808	0.6465	0.057*
C6	−0.1874 (3)	0.8789 (2)	0.76201 (18)	0.0345 (7)
C7	−0.0836 (3)	0.9291 (2)	0.74451 (18)	0.0334 (6)
H7	−0.1103	0.9400	0.6911	0.040*
C9	0.1393 (3)	1.0157 (3)	0.77120 (18)	0.0352 (7)
C10	0.0585 (4)	1.0849 (3)	0.6962 (2)	0.0464 (9)
H10A	0.1265	1.1269	0.6868	0.056*
H10B	0.0049	1.0376	0.6506	0.056*
C11	0.2297 (4)	0.9275 (3)	0.7590 (2)	0.0486 (9)
H11A	0.2880	0.9621	0.7388	0.058*
H11B	0.2946	0.8953	0.8102	0.058*
C12	0.2357 (3)	1.0870 (3)	0.84214 (18)	0.0342 (7)
H12A	0.3199	1.1091	0.8382	0.041*
H12B	0.1840	1.1525	0.8422	0.041*
C13	0.3707 (3)	0.7594 (2)	0.94069 (19)	0.0357 (7)
C14	0.3997 (5)	0.6436 (3)	0.9255 (4)	0.0821 (17)
H14A	0.4021	0.6404	0.8761	0.123*
H14B	0.3248	0.5965	0.9226	0.123*
H14C	0.4907	0.6200	0.9682	0.123*
C15	0.3292 (3)	0.9424 (2)	1.09183 (17)	0.0315 (6)
C16	0.3403 (4)	0.9114 (3)	1.1703 (2)	0.0440 (8)
H16A	0.4374	0.9225	1.2120	0.066*
H16B	0.3147	0.8358	1.1690	0.066*
H16C	0.2761	0.9561	1.1801	0.066*
C17	0.1100 (6)	0.8401 (4)	0.5308 (3)	0.0706 (13)
H17B	0.0142	0.8391	0.4864	0.106*
H17A	0.1057	0.8323	0.5794	0.106*
H17C	0.1644	0.7806	0.5258	0.106*
C18	0.1775 (5)	0.9407 (4)	0.5317 (3)	0.0742 (14)
H9A	0.082 (4)	1.158 (2)	0.938 (3)	0.111*
H9B	−0.014 (5)	1.099 (3)	0.953 (3)	0.111*
H10C	0.320 (2)	0.242 (4)	0.984 (3)	0.111*
H10D	0.235 (5)	0.327 (3)	0.987 (3)	0.111*
N1	0.0433 (3)	0.9604 (2)	0.79651 (14)	0.0299 (5)
N2	0.2282 (7)	1.0199 (4)	0.5303 (5)	0.146 (3)
O1	−0.0288 (2)	0.86304 (18)	0.90298 (12)	0.0356 (5)
O2	0.1473 (4)	0.8430 (3)	0.7059 (2)	0.0775 (9)
H2	0.1298	0.7957	0.7305	0.116*
O3	−0.0374 (3)	1.1568 (2)	0.70565 (16)	0.0569 (7)
H3	−0.0849	1.1909	0.6642	0.085*
O4	0.2792 (2)	1.02733 (16)	0.91436 (11)	0.0290 (4)
O5	0.4759 (2)	0.82092 (18)	0.97622 (15)	0.0466 (6)
O6	0.2412 (2)	0.78562 (16)	0.91590 (13)	0.0359 (5)
O7	0.4363 (2)	0.9780 (2)	1.08976 (14)	0.0480 (6)
O8	0.2062 (2)	0.92758 (18)	1.03081 (12)	0.0358 (5)
O9	0.0281 (3)	1.10148 (19)	0.92495 (16)	0.0451 (6)
O10	0.2353 (3)	0.2668 (3)	0.9640 (2)	0.0640 (8)
Mn1	0.13180 (4)	0.94343 (3)	0.91490 (2)	0.02691 (13)
Mn2	0.5000	1.0000	1.0000	0.02878 (16)

	U11	U22	U33	U12	U13	U23
C1	0.0261 (14)	0.0260 (14)	0.0358 (16)	−0.0014 (11)	0.0091 (12)	−0.0011 (11)
C2	0.0379 (17)	0.0424 (18)	0.0430 (19)	−0.0061 (14)	0.0176 (15)	0.0013 (14)
C3	0.0326 (17)	0.061 (2)	0.064 (3)	−0.0180 (17)	0.0181 (17)	−0.0055 (19)
C4	0.0317 (18)	0.069 (3)	0.057 (2)	−0.0176 (18)	0.0032 (17)	−0.003 (2)
C5	0.0363 (18)	0.050 (2)	0.0377 (19)	−0.0101 (15)	0.0030 (14)	−0.0016 (15)
C6	0.0258 (14)	0.0306 (15)	0.0382 (17)	−0.0024 (12)	0.0085 (12)	−0.0031 (12)
C7	0.0313 (15)	0.0351 (16)	0.0260 (14)	0.0012 (12)	0.0075 (12)	0.0006 (12)
C9	0.0302 (15)	0.0398 (16)	0.0328 (16)	−0.0026 (13)	0.0129 (13)	0.0056 (13)
C10	0.0397 (18)	0.055 (2)	0.0352 (18)	−0.0057 (16)	0.0104 (15)	0.0132 (15)
C11	0.049 (2)	0.059 (2)	0.042 (2)	0.0034 (17)	0.0253 (17)	−0.0003 (16)
C12	0.0273 (14)	0.0342 (15)	0.0340 (16)	−0.0017 (12)	0.0092 (12)	0.0082 (12)
C13	0.0308 (15)	0.0274 (14)	0.0443 (18)	−0.0002 (12)	0.0145 (14)	−0.0049 (13)
C14	0.045 (2)	0.040 (2)	0.139 (5)	0.0000 (17)	0.026 (3)	−0.030 (3)
C15	0.0321 (15)	0.0281 (14)	0.0313 (15)	0.0043 (12)	0.0130 (12)	−0.0022 (12)
C16	0.0445 (19)	0.0471 (19)	0.0348 (18)	0.0055 (15)	0.0148 (15)	0.0028 (14)
C17	0.102 (4)	0.049 (2)	0.069 (3)	−0.006 (2)	0.047 (3)	−0.004 (2)
C18	0.074 (3)	0.047 (2)	0.087 (3)	0.001 (2)	0.027 (3)	0.011 (2)
N1	0.0262 (12)	0.0323 (13)	0.0284 (12)	−0.0012 (10)	0.0110 (10)	0.0024 (10)
N2	0.124 (5)	0.065 (3)	0.225 (8)	−0.021 (3)	0.065 (5)	0.031 (4)
O1	0.0247 (10)	0.0422 (12)	0.0327 (11)	−0.0046 (9)	0.0080 (9)	0.0057 (9)
O2	0.101 (3)	0.072 (2)	0.068 (2)	−0.0063 (19)	0.047 (2)	−0.0187 (17)
O3	0.0442 (14)	0.0612 (17)	0.0493 (15)	0.0126 (12)	0.0099 (12)	0.0258 (13)
O4	0.0218 (9)	0.0311 (10)	0.0286 (10)	0.0003 (8)	0.0078 (8)	0.0061 (8)
O5	0.0310 (11)	0.0290 (11)	0.0633 (16)	−0.0016 (9)	0.0096 (11)	−0.0065 (11)
O6	0.0285 (10)	0.0283 (10)	0.0440 (13)	−0.0011 (8)	0.0120 (9)	−0.0063 (9)
O7	0.0313 (12)	0.0740 (17)	0.0372 (13)	−0.0035 (12)	0.0152 (10)	−0.0003 (12)
O8	0.0306 (11)	0.0434 (12)	0.0291 (11)	−0.0049 (9)	0.0109 (9)	−0.0004 (9)
O9	0.0436 (14)	0.0384 (13)	0.0596 (16)	0.0039 (10)	0.0299 (12)	−0.0016 (11)
O10	0.0495 (16)	0.0581 (18)	0.081 (2)	0.0004 (13)	0.0286 (16)	−0.0148 (15)
Mn1	0.0215 (2)	0.0281 (2)	0.0258 (2)	−0.00170 (16)	0.00718 (17)	0.00117 (17)
Mn2	0.0204 (3)	0.0280 (3)	0.0314 (3)	−0.0005 (2)	0.0073 (2)	−0.0008 (2)

C1—O1	1.319 (3)	C14—H14B	0.9600
C1—C2	1.400 (4)	C14—H14C	0.9600
C1—C6	1.411 (4)	C15—O7	1.234 (4)
C2—C3	1.378 (5)	C15—O8	1.276 (3)
C2—H2A	0.9300	C15—C16	1.498 (4)
C3—C4	1.393 (6)	C16—H16A	0.9600
C3—H3A	0.9300	C16—H16B	0.9600
C4—C5	1.365 (5)	C16—H16C	0.9600
C4—H4	0.9300	C17—C18	1.418 (6)
C5—C6	1.410 (4)	C17—H17B	0.9600
C5—H5	0.9300	C17—H17A	0.9600
C6—C7	1.434 (4)	C17—H17C	0.9600
C7—N1	1.287 (4)	C18—N2	1.113 (6)
C7—H7	0.9300	N1—Mn1	2.004 (2)
C9—N1	1.484 (4)	O1—Mn1	1.882 (2)
C9—C12	1.520 (4)	O2—H2	0.8200
C9—C10	1.525 (4)	O3—H3	0.8200
C9—C11	1.533 (5)	O4—Mn1	1.8729 (19)
C10—O3	1.420 (5)	O4—Mn2	2.1395 (18)
C10—H10A	0.9700	O5—Mn2	2.223 (2)
C10—H10B	0.9700	O6—Mn1	2.244 (2)
C11—O2	1.416 (5)	O7—Mn2	2.147 (2)
C11—H11A	0.9700	O8—Mn1	1.975 (2)
C11—H11B	0.9700	O9—Mn1	2.275 (2)
C12—O4	1.429 (3)	O9—H9A	0.851 (10)
C12—H12A	0.9700	O9—H9B	0.851 (10)
C12—H12B	0.9700	O10—H10C	0.851 (10)
C13—O5	1.241 (4)	O10—H10D	0.849 (10)
C13—O6	1.258 (4)	Mn2—O4i	2.1395 (18)
C13—C14	1.505 (5)	Mn2—O7i	2.147 (2)
C14—H14A	0.9600	Mn2—O5i	2.223 (2)
O1—C1—C2	118.4 (3)	H16A—C16—H16B	109.5
O1—C1—C6	123.4 (3)	C15—C16—H16C	109.5
C2—C1—C6	118.2 (3)	H16A—C16—H16C	109.5
C3—C2—C1	120.7 (3)	H16B—C16—H16C	109.5
C3—C2—H2A	119.7	C18—C17—H17B	109.5
C1—C2—H2A	119.7	C18—C17—H17A	109.5
C2—C3—C4	121.1 (3)	H17B—C17—H17A	109.5
C2—C3—H3A	119.4	C18—C17—H17C	109.5
C4—C3—H3A	119.4	H17B—C17—H17C	109.5
C5—C4—C3	119.3 (3)	H17A—C17—H17C	109.5
C5—C4—H4	120.4	N2—C18—C17	178.1 (7)
C3—C4—H4	120.4	C7—N1—C9	120.5 (3)
C4—C5—C6	120.9 (3)	C7—N1—Mn1	126.1 (2)
C4—C5—H5	119.6	C9—N1—Mn1	113.37 (18)
C6—C5—H5	119.6	C1—O1—Mn1	129.90 (19)
C5—C6—C1	119.8 (3)	C11—O2—H2	109.5
C5—C6—C7	117.3 (3)	C10—O3—H3	109.5
C1—C6—C7	122.8 (3)	C12—O4—Mn1	113.83 (16)
N1—C7—C6	125.4 (3)	C12—O4—Mn2	122.99 (17)
N1—C7—H7	117.3	Mn1—O4—Mn2	121.17 (9)
C6—C7—H7	117.3	C13—O5—Mn2	133.8 (2)
N1—C9—C12	103.9 (2)	C13—O6—Mn1	133.38 (19)
N1—C9—C10	113.5 (3)	C15—O7—Mn2	136.1 (2)
C12—C9—C10	110.8 (3)	C15—O8—Mn1	133.9 (2)
N1—C9—C11	108.0 (3)	Mn1—O9—H9A	116 (2)
C12—C9—C11	109.8 (3)	Mn1—O9—H9B	116 (3)
C10—C9—C11	110.7 (3)	H9A—O9—H9B	109 (2)
O3—C10—C9	109.5 (3)	H10C—O10—H10D	110 (3)
O3—C10—H10A	109.8	O4—Mn1—O1	173.45 (9)
C9—C10—H10A	109.8	O4—Mn1—O8	100.27 (9)
O3—C10—H10B	109.8	O1—Mn1—O8	86.11 (9)
C9—C10—H10B	109.8	O4—Mn1—N1	82.72 (9)
H10A—C10—H10B	108.2	O1—Mn1—N1	90.84 (9)
O2—C11—C9	114.0 (3)	O8—Mn1—N1	176.23 (10)
O2—C11—H11A	108.8	O4—Mn1—O6	92.33 (8)
C9—C11—H11A	108.8	O1—Mn1—O6	89.24 (9)
O2—C11—H11B	108.8	O8—Mn1—O6	88.97 (9)
C9—C11—H11B	108.8	N1—Mn1—O6	93.22 (9)
H11A—C11—H11B	107.6	O4—Mn1—O9	88.58 (9)
O4—C12—C9	109.7 (2)	O1—Mn1—O9	90.39 (9)
O4—C12—H12A	109.7	O8—Mn1—O9	86.27 (9)
C9—C12—H12A	109.7	N1—Mn1—O9	91.54 (10)
O4—C12—H12B	109.7	O6—Mn1—O9	175.23 (9)
C9—C12—H12B	109.7	O4i—Mn2—O4	180.000 (1)
H12A—C12—H12B	108.2	O4i—Mn2—O7i	89.03 (8)
O5—C13—O6	125.6 (3)	O4—Mn2—O7i	90.98 (8)
O5—C13—C14	117.5 (3)	O4i—Mn2—O7	90.97 (8)
O6—C13—C14	117.0 (3)	O4—Mn2—O7	89.02 (8)
C13—C14—H14A	109.5	O7i—Mn2—O7	180.000 (1)
C13—C14—H14B	109.5	O4i—Mn2—O5	88.78 (8)
H14A—C14—H14B	109.5	O4—Mn2—O5	91.22 (8)
C13—C14—H14C	109.5	O7i—Mn2—O5	90.48 (10)
H14A—C14—H14C	109.5	O7—Mn2—O5	89.52 (10)
H14B—C14—H14C	109.5	O4i—Mn2—O5i	91.22 (8)
O7—C15—O8	124.7 (3)	O4—Mn2—O5i	88.78 (8)
O7—C15—C16	119.5 (3)	O7i—Mn2—O5i	89.52 (10)
O8—C15—C16	115.7 (3)	O7—Mn2—O5i	90.48 (10)
C15—C16—H16A	109.5	O5—Mn2—O5i	180.000 (1)
C15—C16—H16B	109.5
O1—C1—C2—C3	178.6 (3)	Mn2—O4—Mn1—O6	−51.58 (12)
C6—C1—C2—C3	−1.2 (5)	C12—O4—Mn1—O9	−71.9 (2)
C1—C2—C3—C4	1.9 (6)	Mn2—O4—Mn1—O9	123.73 (12)
C2—C3—C4—C5	−1.1 (7)	C1—O1—Mn1—O4	−2.9 (10)
C3—C4—C5—C6	−0.4 (6)	C1—O1—Mn1—O8	164.2 (3)
C4—C5—C6—C1	1.0 (5)	C1—O1—Mn1—N1	−13.6 (3)
C4—C5—C6—C7	−175.3 (4)	C1—O1—Mn1—O6	−106.8 (3)
O1—C1—C6—C5	180.0 (3)	C1—O1—Mn1—O9	78.0 (3)
C2—C1—C6—C5	−0.2 (5)	C15—O8—Mn1—O4	−15.7 (3)
O1—C1—C6—C7	−3.9 (5)	C15—O8—Mn1—O1	165.8 (3)
C2—C1—C6—C7	175.9 (3)	C15—O8—Mn1—N1	−158.1 (13)
C5—C6—C7—N1	171.7 (3)	C15—O8—Mn1—O6	76.5 (3)
C1—C6—C7—N1	−4.5 (5)	C15—O8—Mn1—O9	−103.6 (3)
N1—C9—C10—O3	51.4 (4)	C7—N1—Mn1—O4	−173.7 (3)
C12—C9—C10—O3	−65.0 (3)	C9—N1—Mn1—O4	5.8 (2)
C11—C9—C10—O3	173.0 (3)	C7—N1—Mn1—O1	5.1 (3)
N1—C9—C11—O2	54.4 (4)	C9—N1—Mn1—O1	−175.4 (2)
C12—C9—C11—O2	167.1 (3)	C7—N1—Mn1—O8	−30.9 (16)
C10—C9—C11—O2	−70.3 (4)	C9—N1—Mn1—O8	148.6 (14)
N1—C9—C12—O4	42.2 (3)	C7—N1—Mn1—O6	94.4 (3)
C10—C9—C12—O4	164.4 (3)	C9—N1—Mn1—O6	−86.1 (2)
C11—C9—C12—O4	−73.1 (3)	C7—N1—Mn1—O9	−85.3 (3)
C6—C7—N1—C9	−177.5 (3)	C9—N1—Mn1—O9	94.2 (2)
C6—C7—N1—Mn1	1.9 (4)	C13—O6—Mn1—O4	26.9 (3)
C12—C9—N1—C7	152.4 (3)	C13—O6—Mn1—O1	−159.5 (3)
C10—C9—N1—C7	32.1 (4)	C13—O6—Mn1—O8	−73.4 (3)
C11—C9—N1—C7	−91.0 (3)	C13—O6—Mn1—N1	109.7 (3)
C12—C9—N1—Mn1	−27.1 (3)	C13—O6—Mn1—O9	−74.0 (11)
C10—C9—N1—Mn1	−147.4 (2)	C12—O4—Mn2—O4i	150 (48)
C11—C9—N1—Mn1	89.5 (3)	Mn1—O4—Mn2—O4i	−47 (48)
C2—C1—O1—Mn1	−164.9 (2)	C12—O4—Mn2—O7i	−23.4 (2)
C6—C1—O1—Mn1	14.9 (4)	Mn1—O4—Mn2—O7i	139.47 (13)
C9—C12—O4—Mn1	−41.2 (3)	C12—O4—Mn2—O7	156.6 (2)
C9—C12—O4—Mn2	122.8 (2)	Mn1—O4—Mn2—O7	−40.53 (13)
O6—C13—O5—Mn2	−9.9 (6)	C12—O4—Mn2—O5	−113.9 (2)
C14—C13—O5—Mn2	169.9 (3)	Mn1—O4—Mn2—O5	48.97 (13)
O5—C13—O6—Mn1	3.4 (5)	C12—O4—Mn2—O5i	66.1 (2)
C14—C13—O6—Mn1	−176.4 (3)	Mn1—O4—Mn2—O5i	−131.03 (13)
O8—C15—O7—Mn2	−15.7 (5)	C15—O7—Mn2—O4i	−148.5 (3)
C16—C15—O7—Mn2	163.0 (2)	C15—O7—Mn2—O4	31.5 (3)
O7—C15—O8—Mn1	3.5 (5)	C15—O7—Mn2—O7i	112 (100)
C16—C15—O8—Mn1	−175.3 (2)	C15—O7—Mn2—O5	−59.7 (3)
C12—O4—Mn1—O1	9.0 (9)	C15—O7—Mn2—O5i	120.3 (3)
Mn2—O4—Mn1—O1	−155.3 (8)	C13—O5—Mn2—O4i	166.7 (3)
C12—O4—Mn1—O8	−157.9 (2)	C13—O5—Mn2—O4	−13.3 (3)
Mn2—O4—Mn1—O8	37.79 (13)	C13—O5—Mn2—O7i	−104.3 (3)
C12—O4—Mn1—N1	19.8 (2)	C13—O5—Mn2—O7	75.7 (3)
Mn2—O4—Mn1—N1	−144.53 (13)	C13—O5—Mn2—O5i	30 (100)
C12—O4—Mn1—O6	112.8 (2)

D—H···A	D—H	H···A	D···A	D—H···A
O9—H9A···O10ii	0.85 (1)	1.97 (1)	2.806 (4)	167 (3)
O9—H9B···O8iii	0.85 (1)	2.23 (3)	3.008 (3)	153 (5)
O9—H9B···O1iii	0.85 (1)	2.61 (3)	3.322 (3)	142 (5)
O10—H10C···O5iv	0.85 (1)	2.06 (1)	2.907 (4)	176 (5)
O10—H10D···N2v	0.85 (1)	2.07 (1)	2.914 (6)	174 (6)
O2—H2···O3vi	0.82	2.55	3.362 (5)	172.
O3—H3···O6vii	0.82	2.00	2.777 (3)	159.

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O9—H9A⋯O10i	0.85 (1)	1.97 (1)	2.806 (4)	167 (3)
O9—H9B⋯O8ii	0.85 (1)	2.23 (3)	3.008 (3)	153 (5)
O9—H9B⋯O1ii	0.85 (1)	2.61 (3)	3.322 (3)	142 (5)
O10—H10C⋯O5iii	0.85 (1)	2.06 (1)	2.907 (4)	176 (5)
O10—H10D⋯N2iv	0.85 (1)	2.07 (1)	2.914 (6)	174 (6)
O2—H2⋯O3v	0.82	2.55	3.362 (5)	172
O3—H3⋯O6vi	0.82	2.00	2.777 (3)	159

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) ; (vi) .