Literature DB >> 22083103

Suzuki-Miyaura coupling of heteroaryl boronic acids and vinyl chlorides.

Ashish Thakur1, Kainan Zhang, Janis Louie.   

Abstract

A protocol for the Suzuki-Miyaura coupling of heteroaryl boronic acids and vinyl chlorides that minimizes protodeboronation is described. A combination of catalytic amounts of Pd(OAc)(2) and SPhos in conjunction with CsF in isopropanol effectively affords a variety of coupled products. Surprisingly, a dramatic temperature dependence in product selectivity was observed. This journal is © The Royal Society of Chemistry 2012

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Year:  2011        PMID： 22083103     DOI： 10.1039/c1cc15990a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

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  8 in total

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