Literature DB >> 22072516

A new synthesis of triarylsilylium ions and their application in dihydrogen activation.

André Schäfer1, Matti Reissmann, Annemarie Schäfer, Wolfgang Saak, Detlev Haase, Thomas Müller.   

Abstract

Well-shuffled: An unexpected substituent distribution reaction via alkyldiarylsilylium ions leads to a distribution of substituents. Starting from alkyldiaryl silanes, this reaction provides a facile synthetic approach to sterically highly hindered triarylsilylium ions. These silylium ions can be applied in dihydrogen activation reactions.
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2011        PMID： 22072516     DOI： 10.1002/anie.201106582

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  13 in total

1.  Accessing Cationic α-Silylated and α-Germylated Phosphorus Ylides.

Authors:  Felix Krämer; Michael Radius; Alexander Hinz; Melina E A Dilanas; Frank Breher
Journal:  Chemistry       Date:  2021-12-09       Impact factor: 5.020

2.  Reactivity of the Bicyclic Amido-Substituted Silicon(I) Ring Compound Si4 {N(SiMe3 )Mes}4 with FLP-Type Character.

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Journal:  Chemistry       Date:  2021-11-05       Impact factor: 5.020

3.  Cationic Si-H-Si Bridges in Polysilanes: Their Detection and Targeted Formation in Stable Ion Studies.

Authors:  Lena Albers; Judith Baumgartner; Christoph Marschner; Thomas Müller
Journal:  Chemistry       Date:  2016-04-23       Impact factor: 5.236

4.  Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines.

Authors:  Michael H Holthausen; Rashi R Hiranandani; Douglas W Stephan
Journal:  Chem Sci       Date:  2015-01-27       Impact factor: 9.825

5.  Transition-Metal-Free Cleavage of CO.

Authors:  Marc Devillard; Bas de Bruin; Maxime A Siegler; J I van der Vlugt
Journal:  Chemistry       Date:  2017-09-07       Impact factor: 5.236

6.  Thermodynamic versus kinetic control in substituent redistribution reactions of silylium ions steered by the counteranion.

Authors:  Lukas Omann; Bimal Pudasaini; Elisabeth Irran; Hendrik F T Klare; Mu-Hyun Baik; Martin Oestreich
Journal:  Chem Sci       Date:  2018-05-21       Impact factor: 9.825

7.  On Silylated Oxonium and Sulfonium Ions and Their Interaction with Weakly Coordinating Borate Anions.

Authors:  Kevin Bläsing; Rene Labbow; Dirk Michalik; Fabian Reiß; Axel Schulz; Alexander Villinger; Svenja Walker
Journal:  Chemistry       Date:  2020-01-24       Impact factor: 5.236

8.  An Experimental Acidity Scale for Intramolecularly Stabilized Silyl Lewis Acids.

Authors:  Sandra Künzler; Saskia Rathjen; Anastasia Merk; Marc Schmidtmann; Thomas Müller
Journal:  Chemistry       Date:  2019-10-31       Impact factor: 5.236

9.  Transcriptional Induction of Metallothionein by Tris(pentafluorophenyl)stibane in Cultured Bovine Aortic Endothelial Cells.

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10.  Synthesis of a Counteranion-Stabilized Bis(silylium) Ion.

Authors:  Qian Wu; Avijit Roy; Guoqiang Wang; Elisabeth Irran; Hendrik F T Klare; Martin Oestreich
Journal:  Angew Chem Int Ed Engl       Date:  2020-04-17       Impact factor: 15.336
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