catena-Poly[[triphenyl-tin(IV)]-μ-5-amino-2-nitro-benzoato-κO:O].

The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal-bipyramidal geometry by two monodentate carboxyl-ate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxyl-ate groups [O-Sn-O = 170.88 (3)°]. The benzene ring of the 5-amino-2-nitro-benzoate ligand forms dihedral angles of 82.92 (6), 81.10 (6) and 83.54 (6)° with respect to the three phenyl rings. In the crystal, the chains are linked by inter-molecular N-H⋯O and weak C-H⋯O inter-actions into a three-dimensional network. The crystal structure is further stabilized by weak inter-molecular C-H⋯π inter-actions.

Related literature

For general background to and the coordination environment of triphenyl­tin(IV) carboxyl­ate complexes, see: Yeap & Teoh (2003 ▶); Win et al. (2006 ▶, 2008 ▶, 2011a ▶,b ▶,c ▶). For standard bond-length data, see: Allen et al. (1987 ▶). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986 ▶).

Experimental

Crystal data

[Sn(C6H5)3(C7H5N2O4)]

M = 531.12

Monoclinic,

a = 10.9752 (1) Å

b = 11.8342 (1) Å

c = 17.4160 (2) Å

β = 102.164 (1)°

V = 2211.25 (4) Å3

Z = 4

Mo Kα radiation

μ = 1.19 mm−1

T = 100 K

0.37 × 0.25 × 0.22 mm

Data collection

Bruker SMART APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2009 ▶) T min = 0.671, T max = 0.783

27219 measured reflections

7981 independent reflections

7370 reflections with I > 2σ(I)

R int = 0.017

Refinement

R[F 2 > 2σ(F 2)] = 0.018

wR(F 2) = 0.046

S = 1.07

7981 reflections

297 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.51 e Å−3

Δρmin = −0.54 e Å−3

Data collection: APEX2 (Bruker, 2009 ▶); cell refinement: SAINT (Bruker, 2009 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536811033332/lh5316sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811033332/lh5316Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Sn(C6H5)3(C7H5N2O4)]	F(000) = 1064
Mr = 531.12	Dx = 1.595 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 9281 reflections
a = 10.9752 (1) Å	θ = 2.4–32.7°
b = 11.8342 (1) Å	µ = 1.19 mm−1
c = 17.4160 (2) Å	T = 100 K
β = 102.164 (1)°	Block, yellow
V = 2211.25 (4) Å3	0.37 × 0.25 × 0.22 mm
Z = 4

Bruker SMART APEXII CCD area-detector diffractometer	7981 independent reflections
Radiation source: fine-focus sealed tube	7370 reflections with I > 2σ(I)
graphite	Rint = 0.017
φ and ω scans	θmax = 32.7°, θmin = 1.9°
Absorption correction: multi-scan (SADABS; Bruker, 2009)	h = −16→16
Tmin = 0.671, Tmax = 0.783	k = −17→15
27219 measured reflections	l = −24→26

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.018	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.046	H atoms treated by a mixture of independent and constrained refinement
S = 1.07	w = 1/[σ2(Fo2) + (0.0187P)2 + 0.9636P] where P = (Fo2 + 2Fc2)/3
7981 reflections	(Δ/σ)max = 0.003
297 parameters	Δρmax = 0.51 e Å−3
0 restraints	Δρmin = −0.54 e Å−3

Experimental. The crystal was placed in the cold stream of an Oxford Cryosystems Cobra open-flow nitrogen cryostat (Cosier & Glazer, 1986) operating at 100.0 (1) K.

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Sn1	0.980205 (6)	0.157183 (6)	0.217102 (4)	0.01124 (2)
O1	0.93081 (8)	0.32432 (7)	0.16122 (5)	0.01487 (14)
O2	0.97650 (7)	0.46996 (7)	0.24440 (4)	0.01352 (14)
O3	0.70740 (8)	0.38800 (8)	0.21137 (5)	0.02102 (17)
O4	0.53208 (8)	0.43580 (10)	0.13585 (6)	0.0329 (2)
N1	0.89051 (11)	0.67399 (10)	−0.04786 (6)	0.0218 (2)
N2	0.64692 (9)	0.43960 (9)	0.15452 (6)	0.01829 (18)
C1	0.87574 (10)	0.17504 (9)	0.30535 (6)	0.01377 (18)
C2	0.89877 (11)	0.25962 (10)	0.36218 (7)	0.0193 (2)
H2A	0.9597	0.3158	0.3599	0.023*
C3	0.83296 (13)	0.26235 (12)	0.42251 (7)	0.0243 (2)
H3A	0.8496	0.3199	0.4613	0.029*
C4	0.74309 (12)	0.18074 (12)	0.42582 (7)	0.0247 (2)
H4A	0.6988	0.1823	0.4672	0.030*
C5	0.71792 (11)	0.09704 (12)	0.36888 (7)	0.0224 (2)
H5A	0.6557	0.0419	0.3708	0.027*
C6	0.78424 (10)	0.09427 (10)	0.30890 (7)	0.0176 (2)
H6A	0.7670	0.0368	0.2700	0.021*
C7	0.86334 (10)	0.08532 (9)	0.11625 (6)	0.01378 (18)
C8	0.73920 (10)	0.12127 (11)	0.09743 (7)	0.0191 (2)
H8A	0.7118	0.1796	0.1272	0.023*
C9	0.65528 (12)	0.07180 (14)	0.03508 (7)	0.0276 (3)
H9A	0.5712	0.0969	0.0222	0.033*
C10	0.69493 (13)	−0.01430 (14)	−0.00817 (8)	0.0293 (3)
H10A	0.6375	−0.0486	−0.0502	0.035*
C11	0.81737 (14)	−0.05009 (11)	0.00968 (7)	0.0257 (3)
H11A	0.8442	−0.1089	−0.0200	0.031*
C12	0.90166 (12)	0.00017 (10)	0.07139 (7)	0.0186 (2)
H12A	0.9861	−0.0239	0.0830	0.022*
C13	1.17373 (10)	0.19205 (10)	0.23296 (6)	0.01591 (19)
C14	1.25426 (11)	0.11915 (12)	0.20473 (7)	0.0212 (2)
H14A	1.2224	0.0527	0.1770	0.025*
C15	1.38145 (12)	0.14349 (14)	0.21712 (8)	0.0290 (3)
H15A	1.4356	0.0938	0.1974	0.035*
C16	1.42905 (12)	0.23968 (14)	0.25801 (10)	0.0352 (4)
H16A	1.5155	0.2561	0.2661	0.042*
C17	1.34983 (13)	0.31200 (13)	0.28711 (12)	0.0383 (4)
H17A	1.3825	0.3774	0.3158	0.046*
C18	1.22256 (11)	0.28880 (11)	0.27429 (9)	0.0271 (3)
H18A	1.1687	0.3391	0.2938	0.032*
C19	0.92115 (9)	0.42633 (9)	0.18082 (6)	0.01185 (17)
C20	0.84255 (9)	0.49904 (9)	0.11779 (6)	0.01259 (17)
C21	0.90148 (10)	0.55602 (9)	0.06630 (6)	0.01415 (18)
H21A	0.9895	0.5512	0.0730	0.017*
C22	0.83273 (11)	0.62117 (10)	0.00411 (6)	0.01612 (19)
C23	0.70317 (11)	0.63147 (11)	−0.00281 (7)	0.0196 (2)
H23A	0.6562	0.6784	−0.0425	0.024*
C24	0.64407 (10)	0.57407 (11)	0.04748 (7)	0.0194 (2)
H24A	0.5564	0.5806	0.0420	0.023*
C25	0.71282 (10)	0.50604 (10)	0.10674 (6)	0.01502 (19)
H1N1	0.8472 (16)	0.6975 (16)	−0.0914 (11)	0.028 (4)*
H2N1	0.9684 (18)	0.6650 (15)	−0.0455 (11)	0.032 (5)*

	U11	U22	U33	U12	U13	U23
Sn1	0.01332 (3)	0.00974 (4)	0.01053 (3)	−0.00065 (2)	0.00225 (2)	−0.00024 (2)
O1	0.0199 (3)	0.0093 (4)	0.0152 (3)	0.0003 (3)	0.0032 (3)	0.0005 (3)
O2	0.0169 (3)	0.0107 (4)	0.0122 (3)	−0.0003 (3)	0.0013 (2)	0.0001 (3)
O3	0.0179 (4)	0.0240 (5)	0.0210 (4)	0.0006 (3)	0.0037 (3)	0.0069 (3)
O4	0.0126 (4)	0.0446 (7)	0.0399 (5)	−0.0017 (4)	0.0019 (4)	0.0139 (5)
N1	0.0300 (5)	0.0202 (5)	0.0158 (4)	0.0032 (4)	0.0060 (4)	0.0064 (4)
N2	0.0147 (4)	0.0192 (5)	0.0207 (4)	0.0001 (3)	0.0032 (3)	0.0007 (4)
C1	0.0163 (4)	0.0126 (5)	0.0127 (4)	0.0008 (3)	0.0035 (3)	0.0008 (3)
C2	0.0264 (5)	0.0143 (5)	0.0187 (5)	−0.0024 (4)	0.0080 (4)	−0.0027 (4)
C3	0.0340 (6)	0.0220 (6)	0.0194 (5)	0.0012 (5)	0.0109 (5)	−0.0050 (4)
C4	0.0279 (6)	0.0298 (7)	0.0198 (5)	0.0035 (5)	0.0125 (4)	0.0028 (5)
C5	0.0205 (5)	0.0256 (6)	0.0225 (5)	−0.0029 (4)	0.0076 (4)	0.0041 (5)
C6	0.0179 (4)	0.0177 (5)	0.0169 (5)	−0.0020 (4)	0.0033 (4)	−0.0007 (4)
C7	0.0180 (4)	0.0110 (5)	0.0121 (4)	−0.0022 (4)	0.0025 (3)	0.0001 (3)
C8	0.0170 (4)	0.0239 (6)	0.0164 (5)	−0.0026 (4)	0.0037 (4)	−0.0024 (4)
C9	0.0190 (5)	0.0422 (8)	0.0203 (5)	−0.0086 (5)	0.0014 (4)	−0.0037 (5)
C10	0.0326 (6)	0.0358 (8)	0.0186 (5)	−0.0178 (6)	0.0030 (5)	−0.0081 (5)
C11	0.0426 (7)	0.0173 (6)	0.0176 (5)	−0.0072 (5)	0.0075 (5)	−0.0059 (4)
C12	0.0282 (5)	0.0120 (5)	0.0155 (5)	0.0010 (4)	0.0041 (4)	−0.0004 (4)
C13	0.0152 (4)	0.0144 (5)	0.0174 (5)	−0.0005 (4)	0.0019 (3)	0.0052 (4)
C14	0.0192 (5)	0.0284 (7)	0.0166 (5)	0.0016 (4)	0.0052 (4)	0.0017 (4)
C15	0.0184 (5)	0.0444 (9)	0.0259 (6)	0.0052 (5)	0.0082 (4)	0.0084 (6)
C16	0.0165 (5)	0.0367 (9)	0.0500 (9)	−0.0036 (5)	0.0012 (5)	0.0195 (7)
C17	0.0202 (6)	0.0196 (7)	0.0683 (11)	−0.0053 (5)	−0.0064 (6)	0.0053 (7)
C18	0.0180 (5)	0.0140 (6)	0.0453 (8)	−0.0004 (4)	−0.0020 (5)	0.0000 (5)
C19	0.0123 (4)	0.0114 (5)	0.0124 (4)	−0.0002 (3)	0.0039 (3)	0.0015 (3)
C20	0.0154 (4)	0.0096 (5)	0.0120 (4)	0.0007 (3)	0.0013 (3)	−0.0010 (3)
C21	0.0175 (4)	0.0120 (5)	0.0126 (4)	0.0011 (4)	0.0023 (3)	0.0004 (3)
C22	0.0231 (5)	0.0122 (5)	0.0125 (4)	0.0012 (4)	0.0025 (4)	0.0000 (4)
C23	0.0221 (5)	0.0173 (5)	0.0170 (5)	0.0038 (4)	−0.0017 (4)	0.0031 (4)
C24	0.0163 (4)	0.0194 (6)	0.0202 (5)	0.0030 (4)	−0.0012 (4)	0.0016 (4)
C25	0.0154 (4)	0.0137 (5)	0.0152 (4)	0.0002 (4)	0.0016 (3)	0.0003 (4)

Sn1—C1	2.1129 (11)	C9—C10	1.390 (2)
Sn1—C7	2.1222 (10)	C9—H9A	0.9500
Sn1—C13	2.1239 (11)	C10—C11	1.381 (2)
Sn1—O1	2.2205 (8)	C10—H10A	0.9500
Sn1—O2i	2.3345 (8)	C11—C12	1.3949 (17)
O1—C19	1.2651 (13)	C11—H11A	0.9500
O2—C19	1.2563 (12)	C12—H12A	0.9500
O2—Sn1ii	2.3345 (8)	C13—C14	1.3965 (17)
O3—N2	1.2315 (13)	C13—C18	1.3978 (18)
O4—N2	1.2344 (12)	C14—C15	1.3968 (17)
N1—C22	1.3616 (15)	C14—H14A	0.9500
N1—H1N1	0.852 (18)	C15—C16	1.385 (2)
N1—H2N1	0.853 (19)	C15—H15A	0.9500
N2—C25	1.4447 (15)	C16—C17	1.390 (2)
C1—C2	1.3928 (16)	C16—H16A	0.9500
C1—C6	1.3972 (16)	C17—C18	1.3947 (18)
C2—C3	1.3952 (17)	C17—H17A	0.9500
C2—H2A	0.9500	C18—H18A	0.9500
C3—C4	1.390 (2)	C19—C20	1.5135 (14)
C3—H3A	0.9500	C20—C21	1.3862 (15)
C4—C5	1.3876 (19)	C20—C25	1.3984 (14)
C4—H4A	0.9500	C21—C22	1.4116 (15)
C5—C6	1.3937 (16)	C21—H21A	0.9500
C5—H5A	0.9500	C22—C23	1.4068 (16)
C6—H6A	0.9500	C23—C24	1.3742 (17)
C7—C12	1.3933 (16)	C23—H23A	0.9500
C7—C8	1.3988 (15)	C24—C25	1.3982 (15)
C8—C9	1.3960 (16)	C24—H24A	0.9500
C8—H8A	0.9500
C1—Sn1—C7	108.43 (4)	C9—C10—H10A	119.9
C1—Sn1—C13	124.55 (4)	C10—C11—C12	119.92 (12)
C7—Sn1—C13	126.79 (4)	C10—C11—H11A	120.0
C1—Sn1—O1	96.31 (4)	C12—C11—H11A	120.0
C7—Sn1—O1	86.85 (4)	C7—C12—C11	120.73 (11)
C13—Sn1—O1	91.67 (4)	C7—C12—H12A	119.6
C1—Sn1—O2i	89.71 (4)	C11—C12—H12A	119.6
C7—Sn1—O2i	84.74 (3)	C14—C13—C18	119.01 (11)
C13—Sn1—O2i	90.55 (4)	C14—C13—Sn1	121.60 (9)
O1—Sn1—O2i	170.88 (3)	C18—C13—Sn1	119.37 (9)
C19—O1—Sn1	139.32 (7)	C13—C14—C15	120.28 (13)
C19—O2—Sn1ii	132.42 (7)	C13—C14—H14A	119.9
C22—N1—H1N1	119.4 (12)	C15—C14—H14A	119.9
C22—N1—H2N1	120.9 (13)	C16—C15—C14	120.35 (13)
H1N1—N1—H2N1	116.6 (17)	C16—C15—H15A	119.8
O3—N2—O4	122.76 (11)	C14—C15—H15A	119.8
O3—N2—C25	118.84 (9)	C15—C16—C17	119.76 (12)
O4—N2—C25	118.39 (10)	C15—C16—H16A	120.1
C2—C1—C6	119.00 (10)	C17—C16—H16A	120.1
C2—C1—Sn1	122.94 (8)	C16—C17—C18	120.20 (15)
C6—C1—Sn1	117.97 (8)	C16—C17—H17A	119.9
C1—C2—C3	120.43 (11)	C18—C17—H17A	119.9
C1—C2—H2A	119.8	C17—C18—C13	120.40 (14)
C3—C2—H2A	119.8	C17—C18—H18A	119.8
C4—C3—C2	119.97 (12)	C13—C18—H18A	119.8
C4—C3—H3A	120.0	O2—C19—O1	125.29 (10)
C2—C3—H3A	120.0	O2—C19—C20	120.10 (10)
C5—C4—C3	120.16 (11)	O1—C19—C20	114.46 (9)
C5—C4—H4A	119.9	C21—C20—C25	118.85 (9)
C3—C4—H4A	119.9	C21—C20—C19	118.26 (9)
C4—C5—C6	119.71 (12)	C25—C20—C19	122.80 (9)
C4—C5—H5A	120.1	C20—C21—C22	121.02 (10)
C6—C5—H5A	120.1	C20—C21—H21A	119.5
C5—C6—C1	120.71 (11)	C22—C21—H21A	119.5
C5—C6—H6A	119.6	N1—C22—C23	120.48 (11)
C1—C6—H6A	119.6	N1—C22—C21	120.82 (11)
C12—C7—C8	118.86 (10)	C23—C22—C21	118.70 (10)
C12—C7—Sn1	123.56 (8)	C24—C23—C22	120.46 (10)
C8—C7—Sn1	117.46 (8)	C24—C23—H23A	119.8
C9—C8—C7	120.34 (12)	C22—C23—H23A	119.8
C9—C8—H8A	119.8	C23—C24—C25	120.09 (10)
C7—C8—H8A	119.8	C23—C24—H24A	120.0
C10—C9—C8	119.88 (12)	C25—C24—H24A	120.0
C10—C9—H9A	120.1	C24—C25—C20	120.74 (10)
C8—C9—H9A	120.1	C24—C25—N2	118.73 (10)
C11—C10—C9	120.25 (11)	C20—C25—N2	120.48 (9)
C11—C10—H10A	119.9
C1—Sn1—O1—C19	44.23 (11)	O2i—Sn1—C13—C14	45.61 (9)
C7—Sn1—O1—C19	152.44 (11)	C1—Sn1—C13—C18	−42.79 (11)
C13—Sn1—O1—C19	−80.80 (11)	C7—Sn1—C13—C18	143.36 (9)
C7—Sn1—C1—C2	−150.32 (9)	O1—Sn1—C13—C18	56.05 (10)
C13—Sn1—C1—C2	34.87 (11)	O2i—Sn1—C13—C18	−132.81 (10)
O1—Sn1—C1—C2	−61.55 (10)	C18—C13—C14—C15	−0.60 (18)
O2i—Sn1—C1—C2	125.33 (9)	Sn1—C13—C14—C15	−179.01 (9)
C7—Sn1—C1—C6	33.28 (10)	C13—C14—C15—C16	0.5 (2)
C13—Sn1—C1—C6	−141.54 (8)	C14—C15—C16—C17	0.3 (2)
O1—Sn1—C1—C6	122.05 (8)	C15—C16—C17—C18	−0.9 (2)
O2i—Sn1—C1—C6	−51.08 (9)	C16—C17—C18—C13	0.8 (2)
C6—C1—C2—C3	1.14 (17)	C14—C13—C18—C17	0.0 (2)
Sn1—C1—C2—C3	−175.23 (9)	Sn1—C13—C18—C17	178.42 (12)
C1—C2—C3—C4	−0.5 (2)	Sn1ii—O2—C19—O1	161.05 (8)
C2—C3—C4—C5	−0.5 (2)	Sn1ii—O2—C19—C20	−14.22 (14)
C3—C4—C5—C6	0.8 (2)	Sn1—O1—C19—O2	23.95 (17)
C4—C5—C6—C1	−0.13 (18)	Sn1—O1—C19—C20	−160.54 (8)
C2—C1—C6—C5	−0.84 (17)	O2—C19—C20—C21	84.57 (13)
Sn1—C1—C6—C5	175.71 (9)	O1—C19—C20—C21	−91.18 (12)
C1—Sn1—C7—C12	−137.16 (9)	O2—C19—C20—C25	−99.06 (12)
C13—Sn1—C7—C12	37.51 (11)	O1—C19—C20—C25	85.18 (13)
O1—Sn1—C7—C12	127.23 (10)	C25—C20—C21—C22	0.66 (16)
O2i—Sn1—C7—C12	−49.23 (9)	C19—C20—C21—C22	177.17 (10)
C1—Sn1—C7—C8	38.72 (10)	C20—C21—C22—N1	−177.84 (11)
C13—Sn1—C7—C8	−146.61 (8)	C20—C21—C22—C23	2.76 (17)
O1—Sn1—C7—C8	−56.89 (9)	N1—C22—C23—C24	177.06 (12)
O2i—Sn1—C7—C8	126.65 (9)	C21—C22—C23—C24	−3.54 (18)
C12—C7—C8—C9	0.47 (18)	C22—C23—C24—C25	0.88 (19)
Sn1—C7—C8—C9	−175.60 (10)	C23—C24—C25—C20	2.66 (18)
C7—C8—C9—C10	0.5 (2)	C23—C24—C25—N2	−175.00 (11)
C8—C9—C10—C11	−0.8 (2)	C21—C20—C25—C24	−3.40 (16)
C9—C10—C11—C12	0.1 (2)	C19—C20—C25—C24	−179.75 (10)
C8—C7—C12—C11	−1.23 (17)	C21—C20—C25—N2	174.21 (10)
Sn1—C7—C12—C11	174.60 (9)	C19—C20—C25—N2	−2.13 (16)
C10—C11—C12—C7	0.96 (19)	O3—N2—C25—C24	−173.22 (11)
C1—Sn1—C13—C14	135.63 (9)	O4—N2—C25—C24	7.77 (17)
C7—Sn1—C13—C14	−38.23 (11)	O3—N2—C25—C20	9.12 (16)
O1—Sn1—C13—C14	−125.54 (9)	O4—N2—C25—C20	−169.90 (11)

Cg1 and Cg2 are the centroids of the C1–C6 and C7–C12 phenyl rings, respectively.

D—H···A	D—H	H···A	D···A	D—H···A
N1—H2N1···O1iii	0.85 (2)	2.498 (19)	3.0619 (14)	124.3 (15)
C5—H5A···O4iv	0.95	2.40	3.3288 (16)	167
C3—H3A···Cg2v	0.95	2.58	3.4430 (14)	152
C21—H21A···Cg1ii	0.95	2.70	3.4669 (12)	138

Table 1

Hydrogen-bond geometry (Å, °)

Cg1 and Cg2 are the centroids of the C1–C6 and C7–C12 phenyl rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H2N1⋯O1i	0.85 (2)	2.498 (19)	3.0619 (14)	124.3 (15)
C5—H5A⋯O4ii	0.95	2.40	3.3288 (16)	167
C3—H3A⋯Cg2iii	0.95	2.58	3.4430 (14)	152
C21—H21A⋯Cg1iv	0.95	2.70	3.4669 (12)	138

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .