Tetra-kis(diethyl ether)tetra-μ(4)-oxido-octa-kis-(penta-fluoro-phen-yl)octa-zinc.

Mol-ecules of the title compound, [Zn(8)(C(6)F(5))(8)O(4)(C(4)H(10)O)(4)], are located on a special position of site symmetry [Formula: see text]. As a result, there is just one quarter-mol-ecule in the asymmetric unit. The title compound features a Zn(4)O(4) cube. Each Zn atom in the cube carries a pentafluorophenyl substituent. Each O atom is bonded to a further Zn atom, which is connected to a pentafluorophenyl substituent and the O atom of a diethyl ether mol-ecule. All ether C atoms are disordered over two sets of sites with a site occupation factor of 0.51 (2) for the major occupied site.

Related literature

For background to metal organyls bearing pentafluorophenyl groups, see: Noltes & van den Hurk (1964 ▶); Hayashi et al. (2011 ▶); Sun et al. (1998 ▶); Weidenbruch et al. (1989 ▶). For the chemical shift values of the signals observed in the 1H NMR spectrum of free Et2O in [D8]THF, see: Fulmer et al. (2010 ▶).

Experimental

Crystal data

[Zn8(C6F5)8O4(C4H10O)4]

M = 2219.92

Cubic,

a = 23.4948 (6) Å

V = 12969.3 (6) Å3

Z = 6

Mo Kα radiation

μ = 2.31 mm−1

T = 173 K

0.35 × 0.33 × 0.32 mm

Data collection

Stoe IPDS II two-circle diffractometer

Absorption correction: multi-scan (MULABS; Spek, 2009 ▶; Blessing, 1995 ▶) T min = 0.498, T max = 0.525

75864 measured reflections

4000 independent reflections

3655 reflections with I > 2σ(I)

R int = 0.096

Refinement

R[F 2 > 2σ(F 2)] = 0.038

wR(F 2) = 0.093

S = 1.08

4000 reflections

271 parameters

H-atom parameters constrained

Δρmax = 0.57 e Å−3

Δρmin = −0.40 e Å−3

Absolute structure: Flack (1983 ▶), 1839 Friedel pairs

Flack parameter: −0.002 (19)

Data collection: X-AREA (Stoe & Cie, 2001 ▶); cell refinement: X-AREA; data reduction: X-AREA; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: XP in SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S160053681103697X/kj2188sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S160053681103697X/kj2188Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Zn8(C6F5)8O4(C4H10O)4]	Dx = 1.705 Mg m−3
Mr = 2219.92	Mo Kα radiation, λ = 0.71073 Å
Cubic, P43n	Cell parameters from 44493 reflections
Hall symbol: P -4n 2 3	θ = 2.5–25.8°
a = 23.4948 (6) Å	µ = 2.31 mm−1
V = 12969.3 (6) Å3	T = 173 K
Z = 6	Block, colourless
F(000) = 6528	0.35 × 0.33 × 0.32 mm

Stoe IPDS II two-circle diffractometer	4000 independent reflections
Radiation source: fine-focus sealed tube	3655 reflections with I > 2σ(I)
graphite	Rint = 0.096
ω scans	θmax = 25.5°, θmin = 2.5°
Absorption correction: multi-scan (MULABS; Spek, 2009; Blessing, 1995)	h = −27→28
Tmin = 0.498, Tmax = 0.525	k = −18→28
75864 measured reflections	l = −28→28

Refinement on F2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F2 > 2σ(F2)] = 0.038	w = 1/[σ2(Fo2) + (0.0574P)2] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.093	(Δ/σ)max = 0.001
S = 1.08	Δρmax = 0.57 e Å−3
4000 reflections	Δρmin = −0.40 e Å−3
271 parameters	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
0 restraints	Extinction coefficient: 0.00131 (12)
Primary atom site location: structure-invariant direct methods	Absolute structure: Flack (1983), 1839 Friedel pairs
Secondary atom site location: difference Fourier map	Flack parameter: −0.002 (19)

Experimental. ;

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Zn1	0.50037 (3)	0.061641 (18)	0.20605 (2)	0.03607 (14)
Zn2	0.48836 (2)	0.12803 (2)	0.33083 (3)	0.04580 (17)
O1	0.50255 (15)	0.06020 (12)	0.29312 (12)	0.0371 (6)
C1	0.4214 (3)	0.1702 (3)	0.3561 (3)	0.0620 (16)
C2	0.4150 (3)	0.1966 (3)	0.4078 (3)	0.077 (2)
C3	0.3657 (5)	0.2226 (4)	0.4255 (4)	0.110 (3)
C4	0.3189 (5)	0.2225 (5)	0.3911 (6)	0.135 (5)
C5	0.3221 (3)	0.1967 (4)	0.3404 (5)	0.114 (4)
C6	0.3732 (3)	0.1700 (3)	0.3230 (4)	0.078 (2)
C11	0.51854 (19)	0.1320 (2)	0.1628 (2)	0.0425 (10)
C12	0.5218 (2)	0.18472 (19)	0.1880 (2)	0.0441 (11)
C13	0.5437 (3)	0.2323 (2)	0.1619 (3)	0.0557 (14)
C14	0.5638 (3)	0.2287 (2)	0.1076 (3)	0.0542 (13)
C15	0.5611 (3)	0.1768 (3)	0.0799 (2)	0.0552 (13)
C16	0.5389 (2)	0.1301 (2)	0.1077 (2)	0.0483 (12)
F2	0.4605 (3)	0.1988 (2)	0.44346 (18)	0.1052 (16)
F3	0.3626 (4)	0.2482 (3)	0.4764 (3)	0.179 (4)
F4	0.2699 (4)	0.2452 (4)	0.4065 (4)	0.230 (6)
F5	0.2763 (2)	0.1940 (3)	0.3044 (4)	0.169 (3)
F6	0.37461 (18)	0.1443 (2)	0.2707 (2)	0.0906 (13)
F12	0.5028 (2)	0.19094 (11)	0.24282 (12)	0.0634 (8)
F13	0.5465 (2)	0.28246 (13)	0.18992 (18)	0.0851 (12)
F14	0.58640 (19)	0.27394 (15)	0.08172 (19)	0.0782 (11)
F15	0.5811 (2)	0.17297 (16)	0.02661 (16)	0.0878 (13)
F16	0.53988 (18)	0.08019 (14)	0.07952 (15)	0.0698 (10)
O2	0.5635 (2)	0.1608 (3)	0.3571 (3)	0.100 (2)
C21	0.6146 (17)	0.1819 (17)	0.3404 (17)	0.146 (15)*	0.38 (2)
H21A	0.6265	0.1634	0.3044	0.175*	0.38 (2)
H21B	0.6437	0.1733	0.3697	0.175*	0.38 (2)
C21'	0.5649 (6)	0.2278 (6)	0.3605 (6)	0.082 (4)*	0.62 (2)
H21C	0.5293	0.2433	0.3442	0.099*	0.62 (2)
H21D	0.5671	0.2397	0.4008	0.099*	0.62 (2)
C22	0.6107 (12)	0.2494 (8)	0.3312 (10)	0.265 (12)
H22A	0.5833	0.2656	0.3583	0.397*	0.38 (2)
H22B	0.5981	0.2575	0.2923	0.397*	0.38 (2)
H22C	0.6482	0.2665	0.3375	0.397*	0.38 (2)
H22D	0.6171	0.2890	0.3428	0.397*	0.62 (2)
H22E	0.6030	0.2480	0.2903	0.397*	0.62 (2)
H22F	0.6447	0.2268	0.3398	0.397*	0.62 (2)
C23	0.5877 (7)	0.1302 (8)	0.4201 (8)	0.079 (5)*	0.49 (2)
H23A	0.6238	0.1099	0.4125	0.095*	0.49 (2)
H23B	0.5959	0.1609	0.4479	0.095*	0.49 (2)
C24	0.5464 (9)	0.0897 (8)	0.4457 (8)	0.089 (6)*	0.49 (2)
H24A	0.5658	0.0663	0.4743	0.133*	0.49 (2)
H24B	0.5307	0.0652	0.4159	0.133*	0.49 (2)
H24C	0.5155	0.1110	0.4639	0.133*	0.49 (2)
C23'	0.6024 (6)	0.1326 (6)	0.3793 (6)	0.069 (5)*	0.51 (2)
H23C	0.6346	0.1576	0.3901	0.083*	0.51 (2)
H23D	0.6165	0.1031	0.3527	0.083*	0.51 (2)
C24'	0.5754 (9)	0.1044 (9)	0.4335 (8)	0.086 (5)*	0.51 (2)
H24D	0.6040	0.0808	0.4526	0.129*	0.51 (2)
H24E	0.5431	0.0806	0.4221	0.129*	0.51 (2)
H24F	0.5622	0.1341	0.4596	0.129*	0.51 (2)

	U11	U22	U33	U12	U13	U23
Zn1	0.0371 (3)	0.0301 (2)	0.0410 (3)	−0.0003 (2)	0.0001 (3)	0.00158 (19)
Zn2	0.0421 (3)	0.0406 (3)	0.0547 (3)	0.0011 (2)	0.0038 (2)	−0.0109 (2)
O1	0.0337 (14)	0.0367 (14)	0.0410 (14)	0.0009 (14)	0.0006 (15)	−0.0018 (12)
C1	0.066 (4)	0.047 (3)	0.073 (4)	0.006 (3)	0.025 (3)	0.010 (3)
C2	0.085 (5)	0.067 (4)	0.078 (5)	0.028 (4)	0.026 (4)	0.010 (3)
C3	0.137 (9)	0.108 (7)	0.084 (6)	0.046 (6)	0.057 (6)	0.008 (5)
C4	0.109 (8)	0.163 (10)	0.133 (9)	0.086 (8)	0.072 (8)	0.056 (8)
C5	0.059 (5)	0.123 (7)	0.160 (9)	0.030 (5)	0.027 (5)	0.080 (7)
C6	0.062 (4)	0.068 (4)	0.103 (6)	0.012 (3)	0.022 (4)	0.035 (4)
C11	0.042 (2)	0.039 (2)	0.047 (3)	0.0014 (19)	−0.0014 (19)	0.004 (2)
C12	0.052 (3)	0.032 (2)	0.049 (3)	−0.0018 (19)	0.008 (2)	0.0038 (19)
C13	0.066 (3)	0.033 (3)	0.068 (4)	0.000 (2)	0.011 (3)	0.000 (2)
C14	0.059 (3)	0.039 (3)	0.065 (3)	−0.003 (2)	0.013 (3)	0.014 (2)
C15	0.065 (3)	0.055 (3)	0.045 (3)	0.001 (3)	0.014 (2)	0.014 (2)
C16	0.057 (3)	0.037 (3)	0.051 (3)	0.000 (2)	−0.001 (2)	0.005 (2)
F2	0.143 (4)	0.107 (3)	0.066 (3)	0.031 (3)	0.020 (3)	−0.018 (2)
F3	0.243 (9)	0.166 (6)	0.128 (5)	0.095 (6)	0.100 (5)	−0.006 (4)
F4	0.170 (7)	0.269 (10)	0.251 (9)	0.169 (7)	0.136 (7)	0.128 (8)
F5	0.064 (3)	0.209 (7)	0.234 (8)	0.047 (4)	0.016 (4)	0.103 (6)
F6	0.066 (2)	0.094 (3)	0.111 (4)	−0.005 (2)	−0.013 (2)	0.017 (3)
F12	0.093 (2)	0.0402 (14)	0.0566 (16)	−0.0037 (18)	0.024 (2)	0.0002 (12)
F13	0.131 (3)	0.0357 (17)	0.089 (3)	−0.0218 (19)	0.031 (3)	−0.0054 (17)
F14	0.092 (3)	0.0508 (19)	0.092 (3)	−0.0078 (18)	0.029 (2)	0.0174 (18)
F15	0.135 (4)	0.067 (2)	0.061 (2)	0.004 (2)	0.044 (2)	0.0093 (18)
F16	0.110 (3)	0.0468 (17)	0.0532 (18)	−0.0039 (18)	0.0130 (19)	−0.0072 (14)
O2	0.064 (3)	0.113 (4)	0.124 (5)	−0.027 (3)	0.006 (3)	−0.065 (4)
C22	0.39 (3)	0.168 (18)	0.24 (2)	−0.10 (2)	0.00 (2)	−0.021 (16)

Zn1—C11	1.987 (5)	C15—F15	1.339 (6)
Zn1—O1i	1.988 (3)	C15—C16	1.379 (7)
Zn1—O1	2.047 (3)	C16—F16	1.347 (6)
Zn1—O1ii	2.062 (3)	O2—C23'	1.244 (14)
Zn1—Zn1iii	2.8965 (8)	O2—C21	1.36 (4)
Zn1—Zn1ii	2.9087 (8)	O2—C21'	1.576 (14)
Zn1—Zn1i	2.9087 (8)	O2—C23	1.74 (2)
Zn2—O1	1.854 (3)	C21—C22	1.61 (4)
Zn2—C1	1.951 (6)	C21—H21A	0.9900
Zn2—O2	2.022 (5)	C21—H21B	0.9900
O1—Zn1ii	1.988 (3)	C21'—C22	1.37 (2)
O1—Zn1i	2.062 (3)	C21'—H21C	0.9900
C1—C2	1.373 (10)	C21'—H21D	0.9900
C1—C6	1.373 (11)	C22—H22A	0.9800
C2—F2	1.359 (9)	C22—H22B	0.9800
C2—C3	1.373 (11)	C22—H22C	0.9800
C3—F3	1.340 (11)	C22—H22D	0.9800
C3—C4	1.365 (17)	C22—H22E	0.9800
C4—F4	1.319 (9)	C22—H22F	0.9800
C4—C5	1.339 (17)	C23—C24	1.49 (3)
C5—F5	1.371 (12)	C23—H23A	0.9900
C5—C6	1.415 (11)	C23—H23B	0.9900
C6—F6	1.370 (10)	C24—H24A	0.9800
C11—C12	1.375 (7)	C24—H24B	0.9800
C11—C16	1.381 (7)	C24—H24C	0.9800
C12—F12	1.373 (6)	C23'—C24'	1.57 (2)
C12—C13	1.374 (7)	C23'—H23C	0.9900
C13—F13	1.352 (7)	C23'—H23D	0.9900
C13—C14	1.363 (8)	C24'—H24D	0.9800
C14—F14	1.335 (6)	C24'—H24E	0.9800
C14—C15	1.385 (8)	C24'—H24F	0.9800
C11—Zn1—O1i	137.71 (16)	F16—C16—C11	119.6 (4)
C11—Zn1—O1	121.31 (16)	C15—C16—C11	123.3 (5)
O1i—Zn1—O1	89.80 (12)	C23'—O2—C21	70.4 (17)
C11—Zn1—O1ii	117.83 (16)	C23'—O2—C21'	119.7 (9)
O1i—Zn1—O1ii	88.69 (11)	C21—O2—C23	96.1 (18)
O1—Zn1—O1ii	87.78 (12)	C21'—O2—C23	111.2 (9)
C11—Zn1—Zn1iii	146.43 (14)	C23'—O2—Zn2	124.5 (8)
O1i—Zn1—Zn1iii	45.37 (9)	C21—O2—Zn2	145.4 (18)
O1—Zn1—Zn1iii	89.06 (8)	C21'—O2—Zn2	114.4 (6)
O1ii—Zn1—Zn1iii	43.33 (9)	C23—O2—Zn2	112.8 (7)
C11—Zn1—Zn1ii	132.34 (14)	O2—C21—C22	110 (3)
O1i—Zn1—Zn1ii	89.85 (8)	O2—C21—H21A	109.6
O1—Zn1—Zn1ii	43.08 (9)	C22—C21—H21A	109.6
O1ii—Zn1—Zn1ii	44.72 (8)	O2—C21—H21B	109.6
Zn1iii—Zn1—Zn1ii	60.137 (9)	C22—C21—H21B	109.6
C11—Zn1—Zn1i	151.96 (14)	H21A—C21—H21B	108.1
O1i—Zn1—Zn1i	44.68 (8)	C22—C21'—O2	111.2 (13)
O1—Zn1—Zn1i	45.14 (9)	C22—C21'—H21C	109.4
O1ii—Zn1—Zn1i	88.44 (8)	O2—C21'—H21C	109.4
Zn1iii—Zn1—Zn1i	60.137 (9)	C22—C21'—H21D	109.4
Zn1ii—Zn1—Zn1i	59.724 (18)	O2—C21'—H21D	109.4
O1—Zn2—C1	136.6 (2)	H21C—C21'—H21D	108.0
O1—Zn2—O2	108.4 (2)	C21'—C22—C21	67.1 (16)
C1—Zn2—O2	114.7 (2)	C21'—C22—H22A	46.1
Zn2—O1—Zn1ii	137.41 (17)	C21—C22—H22A	109.5
Zn2—O1—Zn1	117.33 (14)	C21'—C22—H22B	107.6
Zn1ii—O1—Zn1	92.24 (12)	C21—C22—H22B	109.5
Zn2—O1—Zn1i	116.75 (17)	H22A—C22—H22B	109.5
Zn1ii—O1—Zn1i	91.30 (11)	C21'—C22—H22C	141.3
Zn1—O1—Zn1i	90.14 (12)	C21—C22—H22C	109.5
C2—C1—C6	114.3 (6)	H22A—C22—H22C	109.5
C2—C1—Zn2	125.9 (6)	H22B—C22—H22C	109.5
C6—C1—Zn2	119.4 (5)	C21'—C22—H22D	109.5
F2—C2—C3	117.4 (8)	C21—C22—H22D	153.1
F2—C2—C1	118.4 (6)	C21'—C22—H22E	109.5
C3—C2—C1	124.1 (9)	H22C—C22—H22E	109.2
F3—C3—C4	119.0 (9)	H22D—C22—H22E	109.5
F3—C3—C2	121.0 (11)	C21'—C22—H22F	109.5
C4—C3—C2	120.0 (9)	H22D—C22—H22F	109.5
F4—C4—C5	118.4 (14)	H22E—C22—H22F	109.5
F4—C4—C3	122.8 (13)	C24—C23—O2	113.2 (12)
C5—C4—C3	118.8 (8)	C24—C23—H23A	108.9
C4—C5—F5	121.7 (9)	O2—C23—H23A	108.9
C4—C5—C6	120.4 (10)	C24—C23—H23B	108.9
F5—C5—C6	117.9 (11)	O2—C23—H23B	108.9
F6—C6—C1	119.3 (6)	H23A—C23—H23B	107.7
F6—C6—C5	118.4 (8)	C23—C24—H24A	109.5
C1—C6—C5	122.3 (9)	C23—C24—H24B	109.5
C12—C11—C16	114.4 (4)	H24A—C24—H24B	109.5
C12—C11—Zn1	122.8 (4)	C23—C24—H24C	109.5
C16—C11—Zn1	121.8 (4)	H24A—C24—H24C	109.5
C11—C12—F12	118.8 (4)	H24B—C24—H24C	109.5
C11—C12—C13	124.2 (5)	O2—C23'—C24'	105.6 (12)
F12—C12—C13	117.0 (4)	O2—C23'—H23C	110.6
F13—C13—C14	119.5 (5)	C24'—C23'—H23C	110.6
F13—C13—C12	120.7 (5)	O2—C23'—H23D	110.6
C14—C13—C12	119.7 (5)	C24'—C23'—H23D	110.6
F14—C14—C13	121.0 (5)	H23C—C23'—H23D	108.8
F14—C14—C15	120.3 (5)	C23'—C24'—H24D	109.5
C13—C14—C15	118.7 (5)	C23'—C24'—H24E	109.5
F15—C15—C16	121.5 (5)	H24D—C24'—H24E	109.5
F15—C15—C14	118.9 (5)	C23'—C24'—H24F	109.5
C16—C15—C14	119.6 (5)	H24D—C24'—H24F	109.5
F16—C16—C15	117.0 (5)	H24E—C24'—H24F	109.5
C1—Zn2—O1—Zn1ii	−146.6 (3)	O1—Zn1—C11—C16	154.2 (4)
O2—Zn2—O1—Zn1ii	26.8 (4)	O1ii—Zn1—C11—C16	48.6 (5)
C1—Zn2—O1—Zn1	84.5 (3)	Zn1iii—Zn1—C11—C16	2.3 (6)
O2—Zn2—O1—Zn1	−102.0 (3)	Zn1ii—Zn1—C11—C16	101.3 (4)
C1—Zn2—O1—Zn1i	−20.8 (4)	Zn1i—Zn1—C11—C16	−153.7 (3)
O2—Zn2—O1—Zn1i	152.7 (3)	C16—C11—C12—F12	−179.8 (5)
C11—Zn1—O1—Zn2	27.9 (3)	Zn1—C11—C12—F12	−11.1 (7)
O1i—Zn1—O1—Zn2	−121.8 (2)	C16—C11—C12—C13	−0.5 (8)
O1ii—Zn1—O1—Zn2	149.5 (2)	Zn1—C11—C12—C13	168.2 (4)
Zn1iii—Zn1—O1—Zn2	−167.19 (17)	C11—C12—C13—F13	−178.7 (5)
Zn1ii—Zn1—O1—Zn2	148.2 (3)	F12—C12—C13—F13	0.6 (8)
Zn1i—Zn1—O1—Zn2	−120.5 (2)	C11—C12—C13—C14	0.0 (9)
C11—Zn1—O1—Zn1ii	−120.25 (17)	F12—C12—C13—C14	179.4 (5)
O1ii—Zn1—O1—Zn1ii	1.30 (11)	F13—C13—C14—F14	0.2 (10)
Zn1iii—Zn1—O1—Zn1ii	44.64 (9)	C12—C13—C14—F14	−178.6 (6)
Zn1i—Zn1—O1—Zn1ii	91.31 (11)	F13—C13—C14—C15	179.4 (6)
C11—Zn1—O1—Zn1i	148.44 (17)	C12—C13—C14—C15	0.6 (9)
O1i—Zn1—O1—Zn1i	−1.31 (11)	F14—C14—C15—F15	−0.5 (9)
Zn1iii—Zn1—O1—Zn1i	−46.67 (9)	C13—C14—C15—F15	−179.7 (6)
Zn1ii—Zn1—O1—Zn1i	−91.31 (11)	F14—C14—C15—C16	178.5 (6)
O1—Zn2—C1—C2	136.8 (5)	C13—C14—C15—C16	−0.7 (9)
O2—Zn2—C1—C2	−36.4 (7)	F15—C15—C16—F16	2.1 (9)
O1—Zn2—C1—C6	−36.3 (6)	C14—C15—C16—F16	−176.9 (5)
O2—Zn2—C1—C6	150.5 (5)	F15—C15—C16—C11	179.3 (6)
C6—C1—C2—F2	179.8 (6)	C14—C15—C16—C11	0.3 (9)
Zn2—C1—C2—F2	6.4 (10)	C12—C11—C16—F16	177.5 (5)
C6—C1—C2—C3	−1.9 (11)	Zn1—C11—C16—F16	8.7 (7)
Zn2—C1—C2—C3	−175.4 (6)	C12—C11—C16—C15	0.3 (8)
F2—C2—C3—F3	−1.0 (13)	Zn1—C11—C16—C15	−168.5 (5)
C1—C2—C3—F3	−179.2 (8)	O1—Zn2—O2—C23'	−43.3 (10)
F2—C2—C3—C4	179.2 (9)	C1—Zn2—O2—C23'	131.7 (10)
C1—C2—C3—C4	0.9 (15)	O1—Zn2—O2—C21	63 (3)
F3—C3—C4—F4	−1.9 (17)	C1—Zn2—O2—C21	−122 (3)
C2—C3—C4—F4	178.0 (9)	O1—Zn2—O2—C21'	150.0 (6)
F3—C3—C4—C5	−179.8 (10)	C1—Zn2—O2—C21'	−35.0 (7)
C2—C3—C4—C5	0.1 (17)	O1—Zn2—O2—C23	−81.5 (7)
F4—C4—C5—F5	0.7 (16)	C1—Zn2—O2—C23	93.6 (7)
C3—C4—C5—F5	178.7 (9)	C23'—O2—C21—C22	−147 (3)
F4—C4—C5—C6	−177.8 (8)	C21'—O2—C21—C22	−12.3 (19)
C3—C4—C5—C6	0.2 (16)	C23—O2—C21—C22	−123 (2)
C2—C1—C6—F6	−179.5 (6)	Zn2—O2—C21—C22	90 (4)
Zn2—C1—C6—F6	−5.7 (8)	C23'—O2—C21'—C22	64.6 (18)
C2—C1—C6—C5	2.2 (10)	C21—O2—C21'—C22	14 (2)
Zn2—C1—C6—C5	176.0 (6)	C23—O2—C21'—C22	102.7 (16)
C4—C5—C6—F6	−179.7 (8)	Zn2—O2—C21'—C22	−128.0 (14)
F5—C5—C6—F6	1.7 (10)	O2—C21'—C22—C21	−12 (2)
C4—C5—C6—C1	−1.4 (13)	O2—C21—C22—C21'	14 (2)
F5—C5—C6—C1	−179.9 (7)	C23'—O2—C23—C24	−123 (2)
O1i—Zn1—C11—C12	117.9 (4)	C21—O2—C23—C24	−166 (2)
O1—Zn1—C11—C12	−13.6 (5)	C21'—O2—C23—C24	124.9 (13)
O1ii—Zn1—C11—C12	−119.3 (4)	Zn2—O2—C23—C24	−5.3 (15)
Zn1iii—Zn1—C11—C12	−165.5 (3)	C21—O2—C23'—C24'	157 (2)
Zn1ii—Zn1—C11—C12	−66.6 (5)	C21'—O2—C23'—C24'	107.9 (13)
Zn1i—Zn1—C11—C12	38.5 (6)	C23—O2—C23'—C24'	22.7 (14)
O1i—Zn1—C11—C16	−74.3 (5)	Zn2—O2—C23'—C24'	−58.2 (15)