Literature DB >> 22060018

Catalytic hydroacylation as an approach to homoaldol products.

Stephen K Murphy1, David A Petrone, Matthew M Coulter, Vy M Dong.   

Abstract

A method has been developed for the intermolecular hydroacylation of homoallyl alcohols with salicylaldehydes to furnish homoaldol products in 50-98% yields. The method also applies to the hydroacylation of 2-hydroxystyrenes. This work highlights the use of hydroacylation as a unified approach to both aldol and homoaldol products.

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Year:  2011        PMID： 22060018     DOI： 10.1021/ol202663p

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  10 in total

1.  Intermolecular Markovnikov-Selective Hydroacylation of Olefins Catalyzed by a Cationic Ruthenium-Hydride Complex.

Authors:  Junghwa Kim; Chae S Yi
Journal:  ACS Catal       Date:  2016-04-19       Impact factor: 13.084

2.  Rhodium(I)-Catalyzed Intermolecular Hydroacylation of α-Keto Amides and Isatins with Non-Chelating Aldehydes.

Authors:  Kevin G M Kou; Lauren E Longobardi; Vy M Dong
Journal:  Adv Synth Catal       Date:  2015-07-14       Impact factor: 5.837

3.  Substrate-directed hydroacylation: rhodium-catalyzed coupling of vinylphenols and nonchelating aldehydes.

Authors:  Stephen K Murphy; Achim Bruch; Vy M Dong
Journal:  Angew Chem Int Ed Engl       Date:  2014-01-29       Impact factor: 15.336

Review 4.  Teaching Aldehydes New Tricks Using Rhodium- and Cobalt-Hydride Catalysis.

Authors:  Ryan T Davison; Erin L Kuker; Vy M Dong
Journal:  Acc Chem Res       Date:  2021-02-03       Impact factor: 22.384

5.  Mechanistic insights into hydroacylation with non-chelating aldehydes†Electronic supplementary information (ESI) available: Materials and methods, reaction procedures, characterization data. CCDC 1012849. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02026jClick here for additional data file.

Authors:  Stephen K Murphy; Achim Bruch; Vy M Dong
Journal:  Chem Sci       Date:  2014-09-22       Impact factor: 9.825

6.  Direct Synthesis of Highly Substituted Pyrroles and Dihydropyrroles Using Linear Selective Hydroacylation Reactions.

Authors:  Manjeet K Majhail; Paul M Ylioja; Michael C Willis
Journal:  Chemistry       Date:  2016-04-23       Impact factor: 5.236

7.  Sequential Catalytic Functionalization of Aryltriazenyl Aldehydes for the Synthesis of Complex Benzenes.

Authors:  Sangwon Seo; Ming Gao; Eva Paffenholz; Michael C Willis
Journal:  ACS Catal       Date:  2021-05-05       Impact factor: 13.084

8.  2-Aminobenzaldehydes as versatile substrates for rhodium-catalyzed alkyne hydroacylation: application to dihydroquinolone synthesis.

Authors:  Matthias Castaing; Sacha L Wason; Beatriz Estepa; Joel F Hooper; Michael C Willis
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-12       Impact factor: 15.336

9.  Regioselective hydroacylation of 1,3-dienes by cobalt catalysis.

Authors:  Qing-An Chen; Daniel K Kim; Vy M Dong
Journal:  J Am Chem Soc       Date:  2014-03-03       Impact factor: 15.419

10.  Traceless Rhodium-Catalyzed Hydroacylation Using Alkyl Aldehydes: The Enantioselective Synthesis of β-Aryl Ketones.

Authors:  Anaïs Bouisseau; Ming Gao; Michael C Willis
Journal:  Chemistry       Date:  2016-09-26       Impact factor: 5.236
  10 in total

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