μ-Acetato-diacetato{μ-6,6'-dimethoxy-2,2'-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc.

In the heterodinuclear title complex, [GdZn(C(22)H(18)N(2)O(4))(CH(3)COO)(3)], the Zn(II) ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd(III) ion is nine-coordinated in an approximate mono-capped tetra-gonal-anti-prismatic environment defined by four O atoms from the ligand and five acetate O atoms.

Related literature

For the synthesis of the ligand, see: Costes et al. (2000 ▶). For similar 3d–4f complexes of similar ligands, see: Bao et al. (2010 ▶); Liao et al. (2010 ▶); Xu et al. (2011 ▶).

Experimental

Crystal data

[GdZn(C22H18N2O4)(C2H3O2)3]

M = 774.16

Monoclinic,

a = 14.012 (3) Å

b = 13.581 (3) Å

c = 15.426 (3) Å

β = 103.65 (3)°

V = 2852.6 (10) Å3

Z = 4

Mo Kα radiation

μ = 3.21 mm−1

T = 293 K

0.15 × 0.14 × 0.13 mm

Data collection

Rigaku R-AXIS RAPID diffractometer

Absorption correction: multi-scan (ABSCOR; Higashi, 1995 ▶) T min = 0.645, T max = 0.681

26483 measured reflections

6488 independent reflections

4513 reflections with I > 2σ(I)

R int = 0.073

Refinement

R[F 2 > 2σ(F 2)] = 0.041

wR(F 2) = 0.078

S = 1.01

6488 reflections

384 parameters

H-atom parameters constrained

Δρmax = 0.59 e Å−3

Δρmin = −0.82 e Å−3

Data collection: RAPID-AUTO (Rigaku, 1998 ▶); cell refinement: RAPID-AUTO; data reduction: CrystalClear (Rigaku/MSC, 2002 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S160053681102890X/ng5198sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S160053681102890X/ng5198Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[GdZn(C22H18N2O4)(C2H3O2)3]	F(000) = 1532
Mr = 774.16	Dx = 1.803 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 16409 reflections
a = 14.012 (3) Å	θ = 3.0–27.5°
b = 13.581 (3) Å	µ = 3.21 mm−1
c = 15.426 (3) Å	T = 293 K
β = 103.65 (3)°	Block, yellow
V = 2852.6 (10) Å3	0.15 × 0.14 × 0.13 mm
Z = 4

Rigaku R-AXIS RAPID diffractometer	6488 independent reflections
Radiation source: fine-focus sealed tube	4513 reflections with I > 2σ(I)
graphite	Rint = 0.073
ω scan	θmax = 27.5°, θmin = 3.0°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −18→18
Tmin = 0.645, Tmax = 0.681	k = −17→16
26483 measured reflections	l = −19→18

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.041	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.078	H-atom parameters constrained
S = 1.01	w = 1/[σ2(Fo2) + (0.0272P)2 + 1.1216P] where P = (Fo2 + 2Fc2)/3
6488 reflections	(Δ/σ)max < 0.001
384 parameters	Δρmax = 0.59 e Å−3
0 restraints	Δρmin = −0.82 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Gd1	0.298502 (17)	0.880640 (16)	0.188340 (16)	0.03607 (7)
Zn1	0.05908 (4)	0.84037 (4)	0.19232 (4)	0.03815 (14)
O1	0.4228 (3)	0.9767 (3)	0.2964 (3)	0.0660 (12)
O2	0.4373 (3)	0.8188 (3)	0.3022 (3)	0.0696 (12)
O3	0.1371 (2)	0.9446 (2)	0.1482 (2)	0.0457 (8)
O4	0.2720 (3)	1.0662 (2)	0.1405 (2)	0.0469 (8)
O5	0.2482 (3)	0.8884 (4)	0.3247 (3)	0.0844 (14)
O6	0.1715 (2)	0.7605 (2)	0.1712 (2)	0.0448 (9)
O7	0.3403 (2)	0.6960 (2)	0.1719 (2)	0.0459 (9)
O8	0.2722 (3)	0.8700 (3)	0.0262 (2)	0.0581 (10)
O9	0.4224 (3)	0.8956 (3)	0.1017 (3)	0.0594 (10)
O10	0.0909 (3)	0.8682 (2)	0.3216 (2)	0.0495 (9)
N1	−0.0301 (3)	0.7181 (3)	0.1660 (3)	0.0426 (10)
N2	−0.0693 (3)	0.9076 (3)	0.1312 (3)	0.0406 (9)
C1	−0.2061 (4)	0.6805 (5)	0.1540 (4)	0.0594 (15)
H1A	−0.1919	0.6148	0.1686	0.071*
C2	−0.3228 (4)	0.8097 (6)	0.1166 (4)	0.0722 (18)
H2A	−0.3877	0.8308	0.1047	0.087*
C3	0.1527 (5)	1.1987 (3)	0.0881 (3)	0.0528 (14)
H3A	0.2012	1.2443	0.0847	0.063*
C4	−0.0760 (4)	0.9959 (3)	0.0987 (3)	0.0441 (12)
H4A	−0.1388	1.0190	0.0729	0.053*
C5	0.4366 (4)	0.6643 (4)	0.1674 (5)	0.0705 (18)
H5A	0.4329	0.6302	0.1122	0.106*
H5B	0.4626	0.6208	0.2164	0.106*
H5C	0.4788	0.7205	0.1707	0.106*
C6	0.5288 (6)	0.9052 (5)	0.4231 (4)	0.095 (3)
H6A	0.5924	0.8835	0.4180	0.142*
H6B	0.5060	0.8634	0.4642	0.142*
H6C	0.5331	0.9718	0.4445	0.142*
C7	−0.3015 (5)	0.7124 (5)	0.1369 (4)	0.0728 (18)
H7A	−0.3517	0.6683	0.1390	0.087*
C8	0.2713 (4)	0.6248 (3)	0.1765 (3)	0.0399 (11)
C9	0.0535 (5)	1.2258 (4)	0.0651 (4)	0.0602 (16)
H9A	0.0361	1.2898	0.0466	0.072*
C10	0.1059 (4)	1.0339 (3)	0.1223 (3)	0.0373 (11)
C11	−0.0183 (4)	1.1587 (4)	0.0697 (4)	0.0550 (15)
H11A	−0.0838	1.1777	0.0532	0.066*
C12	0.1196 (5)	0.4954 (3)	0.1731 (4)	0.0541 (14)
H12A	0.0680	0.4512	0.1691	0.065*
C13	0.3513 (4)	1.1311 (4)	0.1360 (4)	0.0594 (15)
H13A	0.3416	1.1567	0.0765	0.089*
H13B	0.4122	1.0956	0.1513	0.089*
H13C	0.3531	1.1845	0.1771	0.089*
C14	−0.1514 (4)	0.8451 (4)	0.1298 (3)	0.0459 (12)
C15	0.0052 (4)	1.0620 (3)	0.0987 (3)	0.0426 (12)
C16	0.2889 (4)	0.5246 (3)	0.1824 (3)	0.0512 (13)
H16A	0.3522	0.5005	0.1880	0.061*
C17	−0.2486 (4)	0.8776 (5)	0.1134 (4)	0.0600 (14)
H17A	−0.2638	0.9435	0.1005	0.072*
C18	0.1774 (4)	1.1038 (3)	0.1156 (3)	0.0395 (11)
C19	−0.1301 (4)	0.7453 (4)	0.1496 (3)	0.0457 (12)
C20	0.0996 (4)	0.5986 (3)	0.1719 (3)	0.0424 (12)
C21	−0.0006 (4)	0.6290 (4)	0.1625 (3)	0.0510 (13)
H21A	−0.0482	0.5798	0.1531	0.061*
C22	0.3616 (4)	0.8806 (4)	0.0284 (4)	0.0524 (13)
C23	0.4599 (4)	0.9003 (4)	0.3355 (4)	0.0498 (13)
C24	0.2012 (5)	0.8960 (5)	0.4602 (4)	0.0749 (18)
H24A	0.2498	0.9466	0.4778	0.112*
H24B	0.2257	0.8352	0.4886	0.112*
H24C	0.1423	0.9144	0.4777	0.112*
C25	0.2112 (5)	0.4601 (4)	0.1798 (4)	0.0632 (16)
H25A	0.2223	0.3925	0.1827	0.076*
C26	0.1791 (4)	0.8833 (4)	0.3610 (3)	0.0516 (13)
C27	0.1785 (4)	0.6639 (3)	0.1738 (3)	0.0385 (11)
C28	0.3968 (5)	0.8751 (5)	−0.0560 (4)	0.084 (2)
H28A	0.4423	0.9277	−0.0570	0.125*
H28B	0.3419	0.8811	−0.1064	0.125*
H28C	0.4289	0.8131	−0.0586	0.125*

	U11	U22	U33	U12	U13	U23
Gd1	0.02645 (12)	0.03976 (12)	0.04177 (14)	−0.00167 (10)	0.00757 (9)	−0.00027 (11)
Zn1	0.0263 (3)	0.0438 (3)	0.0441 (3)	0.0004 (2)	0.0079 (2)	−0.0002 (2)
O1	0.071 (3)	0.054 (2)	0.065 (3)	−0.028 (2)	0.000 (2)	0.0017 (19)
O2	0.068 (3)	0.062 (2)	0.064 (3)	0.008 (2)	−0.014 (2)	−0.0066 (19)
O3	0.030 (2)	0.0417 (18)	0.065 (2)	0.0033 (14)	0.0124 (17)	0.0161 (15)
O4	0.041 (2)	0.0432 (18)	0.057 (2)	−0.0066 (15)	0.0117 (17)	0.0041 (15)
O5	0.045 (3)	0.166 (4)	0.044 (2)	−0.021 (3)	0.014 (2)	−0.010 (3)
O6	0.034 (2)	0.0337 (18)	0.070 (3)	−0.0015 (14)	0.0186 (18)	−0.0013 (15)
O7	0.0256 (19)	0.0440 (18)	0.066 (2)	0.0072 (14)	0.0074 (16)	−0.0030 (15)
O8	0.041 (2)	0.090 (3)	0.044 (2)	0.004 (2)	0.0114 (17)	−0.0026 (18)
O9	0.036 (2)	0.087 (3)	0.057 (3)	−0.0017 (19)	0.0137 (19)	0.001 (2)
O10	0.036 (2)	0.070 (2)	0.043 (2)	0.0000 (17)	0.0112 (16)	0.0014 (16)
N1	0.031 (2)	0.054 (2)	0.044 (3)	−0.0075 (18)	0.0116 (19)	−0.0008 (18)
N2	0.033 (2)	0.051 (2)	0.037 (2)	0.0069 (17)	0.0061 (18)	−0.0012 (17)
C1	0.041 (4)	0.088 (4)	0.051 (4)	−0.013 (3)	0.016 (3)	0.000 (3)
C2	0.022 (3)	0.134 (6)	0.061 (4)	−0.009 (3)	0.010 (3)	−0.007 (4)
C3	0.070 (4)	0.039 (3)	0.047 (3)	0.000 (3)	0.008 (3)	0.002 (2)
C4	0.034 (3)	0.062 (3)	0.036 (3)	0.017 (2)	0.008 (2)	−0.005 (2)
C5	0.028 (3)	0.069 (4)	0.112 (6)	0.011 (3)	0.014 (3)	−0.010 (3)
C6	0.096 (6)	0.110 (5)	0.064 (5)	−0.045 (5)	−0.008 (4)	−0.005 (4)
C7	0.040 (4)	0.110 (5)	0.068 (5)	−0.022 (3)	0.012 (3)	0.000 (4)
C8	0.046 (3)	0.036 (2)	0.036 (3)	0.001 (2)	0.007 (2)	−0.0035 (19)
C9	0.078 (5)	0.038 (3)	0.060 (4)	0.014 (3)	0.008 (3)	0.001 (2)
C10	0.040 (3)	0.038 (2)	0.032 (3)	0.006 (2)	0.007 (2)	−0.0005 (18)
C11	0.050 (4)	0.050 (3)	0.058 (4)	0.017 (3)	0.000 (3)	−0.002 (2)
C12	0.067 (4)	0.041 (3)	0.057 (4)	−0.011 (3)	0.020 (3)	0.001 (2)
C13	0.051 (4)	0.063 (3)	0.063 (4)	−0.017 (3)	0.010 (3)	0.012 (3)
C14	0.028 (3)	0.069 (3)	0.039 (3)	−0.001 (2)	0.005 (2)	−0.005 (2)
C15	0.042 (3)	0.048 (3)	0.036 (3)	0.011 (2)	0.005 (2)	−0.002 (2)
C16	0.058 (4)	0.046 (3)	0.050 (3)	0.015 (3)	0.014 (3)	0.006 (2)
C17	0.038 (3)	0.090 (4)	0.050 (3)	0.007 (3)	0.007 (3)	−0.002 (3)
C18	0.045 (3)	0.040 (3)	0.031 (3)	0.004 (2)	0.006 (2)	−0.0037 (18)
C19	0.029 (3)	0.066 (3)	0.041 (3)	−0.010 (2)	0.007 (2)	−0.004 (2)
C20	0.050 (3)	0.041 (3)	0.038 (3)	−0.005 (2)	0.016 (2)	0.0008 (19)
C21	0.054 (4)	0.051 (3)	0.051 (3)	−0.017 (3)	0.018 (3)	0.000 (2)
C22	0.046 (3)	0.059 (3)	0.056 (4)	0.009 (3)	0.020 (3)	0.002 (3)
C23	0.036 (3)	0.066 (4)	0.047 (3)	−0.015 (3)	0.008 (2)	0.002 (3)
C24	0.067 (5)	0.114 (5)	0.043 (4)	−0.003 (4)	0.011 (3)	−0.002 (3)
C25	0.079 (5)	0.041 (3)	0.071 (4)	0.004 (3)	0.019 (4)	0.006 (3)
C26	0.049 (4)	0.066 (3)	0.038 (3)	0.001 (3)	0.006 (3)	−0.001 (2)
C27	0.044 (3)	0.035 (2)	0.038 (3)	−0.001 (2)	0.013 (2)	0.0001 (19)
C28	0.078 (5)	0.120 (5)	0.061 (4)	0.023 (4)	0.032 (4)	−0.006 (4)

Gd1—O3	2.365 (3)	C4—C15	1.449 (7)
Gd1—O5	2.373 (4)	C4—H4A	0.9300
Gd1—O6	2.382 (3)	C5—H5A	0.9600
Gd1—O9	2.436 (4)	C5—H5B	0.9600
Gd1—O2	2.441 (4)	C5—H5C	0.9600
Gd1—O8	2.445 (4)	C6—C23	1.465 (8)
Gd1—O1	2.479 (4)	C6—H6A	0.9600
Gd1—O7	2.601 (3)	C6—H6B	0.9600
Gd1—O4	2.627 (3)	C6—H6C	0.9600
Gd1—C22	2.810 (6)	C7—H7A	0.9300
Gd1—C23	2.814 (5)	C8—C16	1.382 (6)
Gd1—Zn1	3.4139 (9)	C8—C27	1.395 (6)
Zn1—O10	1.975 (3)	C9—C11	1.371 (8)
Zn1—O6	2.002 (3)	C9—H9A	0.9300
Zn1—O3	2.003 (3)	C10—C18	1.402 (6)
Zn1—N2	2.039 (4)	C10—C15	1.425 (6)
Zn1—N1	2.060 (4)	C11—C15	1.401 (6)
O1—C23	1.250 (6)	C11—H11A	0.9300
O2—C23	1.230 (6)	C12—C25	1.351 (8)
O3—C10	1.319 (5)	C12—C20	1.429 (6)
O4—C18	1.387 (6)	C12—H12A	0.9300
O4—C13	1.434 (6)	C13—H13A	0.9600
O5—C26	1.230 (7)	C13—H13B	0.9600
O6—C27	1.315 (5)	C13—H13C	0.9600
O7—C8	1.382 (5)	C14—C17	1.397 (7)
O7—C5	1.433 (6)	C14—C19	1.406 (7)
O8—C22	1.253 (6)	C16—C25	1.390 (8)
O9—C22	1.261 (6)	C16—H16A	0.9300
O10—C26	1.259 (6)	C17—H17A	0.9300
N1—C21	1.284 (6)	C20—C27	1.413 (6)
N1—C19	1.413 (6)	C20—C21	1.438 (7)
N2—C4	1.295 (6)	C21—H21A	0.9300
N2—C14	1.427 (6)	C22—C28	1.499 (8)
C1—C7	1.370 (8)	C24—C26	1.498 (7)
C1—C19	1.396 (7)	C24—H24A	0.9600
C1—H1A	0.9300	C24—H24B	0.9600
C2—C7	1.375 (8)	C24—H24C	0.9600
C2—C17	1.398 (8)	C25—H25A	0.9300
C2—H2A	0.9300	C28—H28A	0.9600
C3—C18	1.376 (6)	C28—H28B	0.9600
C3—C9	1.400 (8)	C28—H28C	0.9600
C3—H3A	0.9300
O3—Gd1—O5	75.50 (14)	C7—C1—C19	120.8 (6)
O3—Gd1—O6	65.12 (10)	C7—C1—H1A	119.6
O5—Gd1—O6	76.04 (13)	C19—C1—H1A	119.6
O3—Gd1—O9	125.94 (12)	C7—C2—C17	121.3 (6)
O5—Gd1—O9	151.85 (14)	C7—C2—H2A	119.4
O6—Gd1—O9	127.31 (12)	C17—C2—H2A	119.4
O3—Gd1—O2	149.88 (14)	C18—C3—C9	119.1 (5)
O5—Gd1—O2	74.38 (16)	C18—C3—H3A	120.4
O6—Gd1—O2	106.97 (12)	C9—C3—H3A	120.4
O9—Gd1—O2	82.74 (14)	N2—C4—C15	126.0 (4)
O3—Gd1—O8	81.38 (13)	N2—C4—H4A	117.0
O5—Gd1—O8	154.78 (14)	C15—C4—H4A	117.0
O6—Gd1—O8	85.25 (12)	O7—C5—H5A	109.5
O9—Gd1—O8	53.03 (13)	O7—C5—H5B	109.5
O2—Gd1—O8	128.15 (14)	H5A—C5—H5B	109.5
O3—Gd1—O1	117.37 (13)	O7—C5—H5C	109.5
O5—Gd1—O1	71.90 (14)	H5A—C5—H5C	109.5
O6—Gd1—O1	145.40 (12)	H5B—C5—H5C	109.5
O9—Gd1—O1	81.16 (13)	C23—C6—H6A	109.5
O2—Gd1—O1	51.91 (13)	C23—C6—H6B	109.5
O8—Gd1—O1	129.16 (13)	H6A—C6—H6B	109.5
O3—Gd1—O7	123.52 (10)	C23—C6—H6C	109.5
O5—Gd1—O7	104.50 (14)	H6A—C6—H6C	109.5
O6—Gd1—O7	60.56 (10)	H6B—C6—H6C	109.5
O9—Gd1—O7	79.67 (12)	C1—C7—C2	119.8 (6)
O2—Gd1—O7	65.11 (11)	C1—C7—H7A	120.1
O8—Gd1—O7	79.98 (11)	C2—C7—H7A	120.1
O1—Gd1—O7	115.73 (12)	O7—C8—C16	125.2 (5)
O3—Gd1—O4	60.72 (10)	O7—C8—C27	113.0 (4)
O5—Gd1—O4	98.87 (14)	C16—C8—C27	121.8 (5)
O6—Gd1—O4	124.96 (11)	C11—C9—C3	120.6 (5)
O9—Gd1—O4	80.67 (12)	C11—C9—H9A	119.7
O2—Gd1—O4	124.60 (12)	C3—C9—H9A	119.7
O8—Gd1—O4	78.02 (11)	O3—C10—C18	117.0 (4)
O1—Gd1—O4	73.41 (12)	O3—C10—C15	124.1 (4)
O7—Gd1—O4	156.55 (11)	C18—C10—C15	118.8 (4)
O3—Gd1—C22	104.47 (14)	C9—C11—C15	121.3 (5)
O5—Gd1—C22	177.28 (16)	C9—C11—H11A	119.3
O6—Gd1—C22	106.46 (15)	C15—C11—H11A	119.3
O9—Gd1—C22	26.62 (14)	C25—C12—C20	121.9 (5)
O2—Gd1—C22	105.62 (16)	C25—C12—H12A	119.0
O8—Gd1—C22	26.43 (14)	C20—C12—H12A	119.0
O1—Gd1—C22	105.89 (16)	O4—C13—H13A	109.5
O7—Gd1—C22	77.82 (13)	O4—C13—H13B	109.5
O4—Gd1—C22	78.86 (13)	H13A—C13—H13B	109.5
O3—Gd1—C23	135.50 (14)	O4—C13—H13C	109.5
O5—Gd1—C23	68.36 (15)	H13A—C13—H13C	109.5
O6—Gd1—C23	126.30 (13)	H13B—C13—H13C	109.5
O9—Gd1—C23	83.90 (14)	C17—C14—C19	119.5 (5)
O2—Gd1—C23	25.85 (13)	C17—C14—N2	124.3 (5)
O8—Gd1—C23	136.84 (14)	C19—C14—N2	116.2 (4)
O1—Gd1—C23	26.35 (12)	C11—C15—C10	118.4 (5)
O7—Gd1—C23	90.78 (13)	C11—C15—C4	117.1 (5)
O4—Gd1—C23	99.73 (13)	C10—C15—C4	124.4 (4)
C22—Gd1—C23	110.42 (16)	C8—C16—C25	119.5 (5)
O3—Gd1—Zn1	34.95 (7)	C8—C16—H16A	120.3
O5—Gd1—Zn1	59.49 (10)	C25—C16—H16A	120.3
O6—Gd1—Zn1	35.01 (7)	C14—C17—C2	119.1 (6)
O9—Gd1—Zn1	148.60 (9)	C14—C17—H17A	120.5
O2—Gd1—Zn1	123.47 (11)	C2—C17—H17A	120.5
O8—Gd1—Zn1	95.59 (10)	C3—C18—O4	125.9 (5)
O1—Gd1—Zn1	127.58 (10)	C3—C18—C10	121.7 (5)
O7—Gd1—Zn1	95.30 (7)	O4—C18—C10	112.5 (4)
O4—Gd1—Zn1	94.82 (8)	C1—C19—C14	119.5 (5)
C22—Gd1—Zn1	121.98 (13)	C1—C19—N1	124.2 (5)
C23—Gd1—Zn1	127.37 (11)	C14—C19—N1	116.2 (4)
O10—Zn1—O6	105.65 (14)	C27—C20—C12	117.8 (5)
O10—Zn1—O3	101.36 (14)	C27—C20—C21	124.3 (4)
O6—Zn1—O3	79.28 (13)	C12—C20—C21	117.8 (5)
O10—Zn1—N2	110.22 (15)	N1—C21—C20	125.6 (5)
O6—Zn1—N2	144.04 (15)	N1—C21—H21A	117.2
O3—Zn1—N2	91.09 (15)	C20—C21—H21A	117.2
O10—Zn1—N1	109.55 (15)	O8—C22—O9	120.1 (5)
O6—Zn1—N1	89.71 (14)	O8—C22—C28	120.2 (5)
O3—Zn1—N1	148.98 (15)	O9—C22—C28	119.7 (5)
N2—Zn1—N1	80.92 (16)	O8—C22—Gd1	60.3 (3)
O10—Zn1—Gd1	89.96 (10)	O9—C22—Gd1	59.9 (3)
O6—Zn1—Gd1	43.06 (9)	C28—C22—Gd1	177.1 (4)
O3—Zn1—Gd1	42.55 (9)	O2—C23—O1	120.5 (5)
N2—Zn1—Gd1	133.10 (12)	O2—C23—C6	118.3 (5)
N1—Zn1—Gd1	132.72 (12)	O1—C23—C6	121.1 (5)
C23—O1—Gd1	92.0 (3)	O2—C23—Gd1	59.9 (3)
C23—O2—Gd1	94.3 (3)	O1—C23—Gd1	61.7 (3)
C10—O3—Zn1	125.8 (3)	C6—C23—Gd1	167.8 (5)
C10—O3—Gd1	130.2 (3)	C26—C24—H24A	109.5
Zn1—O3—Gd1	102.50 (12)	C26—C24—H24B	109.5
C18—O4—C13	117.4 (4)	H24A—C24—H24B	109.5
C18—O4—Gd1	119.6 (3)	C26—C24—H24C	109.5
C13—O4—Gd1	122.9 (3)	H24A—C24—H24C	109.5
C26—O5—Gd1	146.3 (4)	H24B—C24—H24C	109.5
C27—O6—Zn1	126.2 (3)	C12—C25—C16	120.1 (5)
C27—O6—Gd1	129.1 (3)	C12—C25—H25A	119.9
Zn1—O6—Gd1	101.93 (12)	C16—C25—H25A	119.9
C8—O7—C5	118.1 (4)	O5—C26—O10	125.3 (5)
C8—O7—Gd1	119.5 (3)	O5—C26—C24	117.6 (5)
C5—O7—Gd1	122.1 (3)	O10—C26—C24	117.0 (5)
C22—O8—Gd1	93.3 (3)	O6—C27—C8	116.3 (4)
C22—O9—Gd1	93.5 (3)	O6—C27—C20	125.0 (4)
C26—O10—Zn1	118.7 (3)	C8—C27—C20	118.7 (4)
C21—N1—C19	123.6 (4)	C22—C28—H28A	109.5
C21—N1—Zn1	125.6 (4)	C22—C28—H28B	109.5
C19—N1—Zn1	110.7 (3)	H28A—C28—H28B	109.5
C4—N2—C14	124.1 (4)	C22—C28—H28C	109.5
C4—N2—Zn1	124.7 (3)	H28A—C28—H28C	109.5
C14—N2—Zn1	111.2 (3)	H28B—C28—H28C	109.5