2-(Biphenyl-4-yl)-5-[3-(4,5,6,7-tetra-hydro-thieno[3,2-c]pyridine-5-ylsulfon-yl)thio-phen-2-yl]-1,3,4-oxa-diazole.

In the title mol-ecule, C(25)H(19)N(3)O(3)S(3), the tetra-hydro-pyridine ring adopts a half-chair conformation. The dihedral angle between the least-squares plane through the tetra-hydro-pyridine ring and two thio-phene and two benzene rings are 6.25 (9), 89.49 (9), 76.43 (9) and 84.93 (8)°, respectively, while the dihedral angle between the 1,3,4-oxadiazole and tetra-hydro-pyridine rings is 81.14 (9)°. In the crystal, adjacent mol-ecules are connected via weak C-H⋯N hydrogen bonds, forming a chain along the b axis.

Related literature

For applications of 4,5,6,7-tetra­hydro­thieno[3,2-c]pyridine derivatives, see: Lopez-Rodriguez et al. (2001 ▶); Roth et al. (1994 ▶); Ying & Rusak (1997 ▶). For a related structure, see: Fun et al. (2011 ▶). For ring conformational analysis, see: Cremer & Pople (1975 ▶). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986 ▶).

Experimental

Crystal data

C25H19N3O3S3

M = 505.61

Triclinic,

a = 7.9108 (1) Å

b = 12.0943 (1) Å

c = 12.9498 (2) Å

α = 69.253 (1)°

β = 76.794 (1)°

γ = 77.460 (1)°

V = 1115.30 (2) Å3

Z = 2

Mo Kα radiation

μ = 0.37 mm−1

T = 100 K

0.33 × 0.16 × 0.09 mm

Data collection

Bruker SMART APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2009 ▶) T min = 0.889, T max = 0.966

33050 measured reflections

8887 independent reflections

5904 reflections with I > 2σ(I)

R int = 0.058

Refinement

R[F 2 > 2σ(F 2)] = 0.053

wR(F 2) = 0.122

S = 1.03

8887 reflections

307 parameters

H-atom parameters constrained

Δρmax = 0.47 e Å−3

Δρmin = −0.56 e Å−3

Data collection: APEX2 (Bruker, 2009 ▶); cell refinement: SAINT (Bruker, 2009 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536811038621/tk2792sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811038621/tk2792Isup2.hkl

Supplementary material file. DOI: 10.1107/S1600536811038621/tk2792Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C25H19N3O3S3	Z = 2
Mr = 505.61	F(000) = 524
Triclinic, P1	Dx = 1.506 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 7.9108 (1) Å	Cell parameters from 6236 reflections
b = 12.0943 (1) Å	θ = 2.7–33.5°
c = 12.9498 (2) Å	µ = 0.37 mm−1
α = 69.253 (1)°	T = 100 K
β = 76.794 (1)°	Block, colourless
γ = 77.460 (1)°	0.33 × 0.16 × 0.09 mm
V = 1115.30 (2) Å3

Bruker SMART APEXII CCD area-detector diffractometer	8887 independent reflections
Radiation source: fine-focus sealed tube	5904 reflections with I > 2σ(I)
graphite	Rint = 0.058
φ and ω scans	θmax = 33.8°, θmin = 1.8°
Absorption correction: multi-scan (SADABS; Bruker, 2009)	h = −12→12
Tmin = 0.889, Tmax = 0.966	k = −18→18
33050 measured reflections	l = −19→20

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.053	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.122	H-atom parameters constrained
S = 1.03	w = 1/[σ2(Fo2) + (0.0478P)2 + 0.3497P] where P = (Fo2 + 2Fc2)/3
8887 reflections	(Δ/σ)max = 0.001
307 parameters	Δρmax = 0.47 e Å−3
0 restraints	Δρmin = −0.56 e Å−3

Experimental. The crystal was placed in the cold stream of an Oxford Cryosystems Cobra open-flow nitrogen cryostat (Cosier & Glazer, 1986) operating at 100.0 (1) K.

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
S1	0.68865 (5)	0.88728 (4)	0.30396 (4)	0.01750 (9)
S2	0.21890 (5)	1.13555 (4)	0.34716 (4)	0.02341 (10)
S3	0.87479 (6)	0.36589 (4)	0.41597 (5)	0.03181 (13)
O1	0.72380 (15)	1.15330 (10)	0.22602 (10)	0.0197 (2)
O2	0.79409 (15)	0.90109 (11)	0.37398 (11)	0.0232 (3)
O3	0.74563 (16)	0.92047 (11)	0.18551 (11)	0.0230 (3)
N1	0.66367 (19)	1.34718 (13)	0.20268 (14)	0.0253 (3)
N2	0.51049 (19)	1.29548 (13)	0.25770 (14)	0.0250 (3)
N3	0.66204 (18)	0.74881 (12)	0.34721 (12)	0.0185 (3)
C1	1.5791 (2)	1.37068 (16)	−0.08077 (16)	0.0227 (3)
H1A	1.5056	1.4454	−0.0869	0.027*
C2	1.7532 (2)	1.36806 (17)	−0.13241 (16)	0.0252 (4)
H2A	1.7985	1.4409	−0.1724	0.030*
C3	1.8621 (2)	1.25980 (18)	−0.12625 (18)	0.0293 (4)
H3A	1.9800	1.2582	−0.1643	0.035*
C4	1.7966 (2)	1.15442 (17)	−0.06408 (18)	0.0290 (4)
H4A	1.8711	1.0801	−0.0579	0.035*
C5	1.6239 (2)	1.15597 (16)	−0.01085 (16)	0.0232 (4)
H5A	1.5816	1.0827	0.0323	0.028*
C6	1.5102 (2)	1.26432 (15)	−0.01967 (15)	0.0201 (3)
C7	1.3224 (2)	1.26503 (15)	0.03247 (14)	0.0192 (3)
C8	1.2404 (2)	1.16451 (16)	0.05717 (16)	0.0237 (4)
H8A	1.3061	1.0961	0.0392	0.028*
C9	1.0665 (2)	1.16279 (16)	0.10701 (16)	0.0233 (4)
H9A	1.0143	1.0934	0.1239	0.028*
C10	0.9670 (2)	1.26333 (15)	0.13265 (15)	0.0197 (3)
C11	1.0453 (2)	1.36463 (15)	0.10693 (16)	0.0214 (3)
H11A	0.9782	1.4338	0.1228	0.026*
C12	1.2206 (2)	1.36495 (15)	0.05825 (15)	0.0208 (3)
H12A	1.2727	1.4343	0.0421	0.025*
C13	0.7844 (2)	1.26086 (15)	0.18576 (15)	0.0195 (3)
C14	0.5534 (2)	1.18253 (15)	0.26865 (15)	0.0197 (3)
C15	0.4398 (2)	1.09154 (15)	0.31380 (15)	0.0186 (3)
C16	0.4768 (2)	0.97000 (15)	0.32871 (15)	0.0188 (3)
C17	0.3231 (2)	0.91496 (16)	0.36701 (16)	0.0242 (4)
H17A	0.3234	0.8322	0.3819	0.029*
C18	0.1748 (2)	0.99439 (16)	0.38000 (17)	0.0256 (4)
H18A	0.0600	0.9732	0.4046	0.031*
C19	0.6485 (2)	0.67707 (16)	0.46603 (15)	0.0224 (3)
H19A	0.5237	0.6786	0.5020	0.027*
H19B	0.7095	0.7098	0.5051	0.027*
C20	0.7328 (2)	0.55051 (15)	0.47309 (16)	0.0218 (3)
C21	0.7922 (2)	0.46336 (18)	0.56962 (18)	0.0300 (4)
H21A	0.7774	0.4762	0.6396	0.036*
C22	0.8730 (2)	0.35916 (18)	0.5505 (2)	0.0353 (5)
H22A	0.9222	0.2912	0.6051	0.042*
C23	0.7665 (2)	0.51108 (15)	0.38342 (16)	0.0220 (3)
C24	0.7232 (2)	0.58363 (15)	0.26954 (16)	0.0232 (4)
H24A	0.6660	0.5368	0.2420	0.028*
H24B	0.8321	0.6043	0.2163	0.028*
C25	0.5997 (2)	0.69765 (15)	0.27725 (16)	0.0215 (3)
H25A	0.5965	0.7564	0.2013	0.026*
H25B	0.4793	0.6791	0.3106	0.026*

	U11	U22	U33	U12	U13	U23
S1	0.01654 (16)	0.01276 (18)	0.0226 (2)	−0.00104 (13)	−0.00308 (15)	−0.00578 (16)
S2	0.01898 (18)	0.0208 (2)	0.0301 (3)	0.00215 (15)	−0.00360 (17)	−0.01094 (19)
S3	0.0246 (2)	0.0142 (2)	0.0525 (3)	0.00070 (16)	−0.0087 (2)	−0.0063 (2)
O1	0.0199 (5)	0.0135 (6)	0.0258 (7)	−0.0021 (4)	−0.0021 (5)	−0.0078 (5)
O2	0.0226 (6)	0.0184 (6)	0.0317 (7)	−0.0033 (5)	−0.0089 (5)	−0.0088 (5)
O3	0.0250 (6)	0.0167 (6)	0.0232 (7)	−0.0003 (5)	−0.0006 (5)	−0.0051 (5)
N1	0.0236 (7)	0.0159 (7)	0.0382 (10)	−0.0021 (5)	−0.0056 (6)	−0.0108 (7)
N2	0.0219 (7)	0.0157 (7)	0.0392 (10)	−0.0024 (5)	−0.0043 (6)	−0.0118 (7)
N3	0.0232 (6)	0.0120 (6)	0.0207 (7)	−0.0023 (5)	−0.0059 (5)	−0.0046 (6)
C1	0.0264 (8)	0.0192 (8)	0.0242 (9)	−0.0018 (6)	−0.0054 (7)	−0.0091 (7)
C2	0.0290 (8)	0.0233 (9)	0.0263 (10)	−0.0076 (7)	−0.0032 (7)	−0.0102 (8)
C3	0.0225 (8)	0.0309 (10)	0.0386 (12)	−0.0037 (7)	−0.0016 (8)	−0.0184 (9)
C4	0.0249 (8)	0.0232 (9)	0.0426 (12)	0.0038 (7)	−0.0097 (8)	−0.0167 (9)
C5	0.0258 (8)	0.0179 (8)	0.0278 (10)	−0.0006 (6)	−0.0090 (7)	−0.0083 (7)
C6	0.0246 (7)	0.0177 (8)	0.0208 (9)	−0.0016 (6)	−0.0083 (6)	−0.0076 (7)
C7	0.0242 (7)	0.0156 (8)	0.0177 (8)	−0.0027 (6)	−0.0055 (6)	−0.0042 (7)
C8	0.0277 (8)	0.0169 (8)	0.0281 (10)	−0.0029 (6)	−0.0025 (7)	−0.0107 (7)
C9	0.0275 (8)	0.0156 (8)	0.0288 (10)	−0.0050 (6)	−0.0038 (7)	−0.0090 (7)
C10	0.0232 (7)	0.0155 (8)	0.0213 (9)	−0.0027 (6)	−0.0053 (6)	−0.0060 (7)
C11	0.0255 (8)	0.0126 (7)	0.0260 (9)	−0.0008 (6)	−0.0057 (7)	−0.0062 (7)
C12	0.0243 (8)	0.0142 (8)	0.0241 (9)	−0.0041 (6)	−0.0046 (7)	−0.0053 (7)
C13	0.0229 (7)	0.0134 (7)	0.0237 (9)	−0.0027 (6)	−0.0070 (6)	−0.0060 (7)
C14	0.0195 (7)	0.0177 (8)	0.0228 (9)	0.0009 (6)	−0.0058 (6)	−0.0084 (7)
C15	0.0192 (7)	0.0165 (8)	0.0204 (8)	−0.0003 (6)	−0.0035 (6)	−0.0075 (7)
C16	0.0182 (7)	0.0158 (8)	0.0218 (9)	−0.0007 (6)	−0.0032 (6)	−0.0065 (7)
C17	0.0208 (7)	0.0187 (8)	0.0323 (10)	−0.0048 (6)	−0.0009 (7)	−0.0082 (8)
C18	0.0203 (7)	0.0232 (9)	0.0311 (10)	−0.0043 (7)	0.0003 (7)	−0.0080 (8)
C19	0.0258 (8)	0.0191 (8)	0.0216 (9)	−0.0048 (6)	−0.0029 (7)	−0.0052 (7)
C20	0.0199 (7)	0.0161 (8)	0.0262 (9)	−0.0056 (6)	−0.0056 (7)	−0.0001 (7)
C21	0.0296 (9)	0.0261 (10)	0.0310 (11)	−0.0134 (7)	−0.0100 (8)	0.0032 (8)
C22	0.0275 (9)	0.0190 (9)	0.0505 (14)	−0.0079 (7)	−0.0179 (9)	0.0094 (9)
C23	0.0174 (7)	0.0134 (8)	0.0328 (10)	−0.0033 (6)	−0.0038 (7)	−0.0042 (7)
C24	0.0266 (8)	0.0163 (8)	0.0281 (10)	−0.0031 (6)	−0.0039 (7)	−0.0091 (7)
C25	0.0252 (8)	0.0169 (8)	0.0248 (9)	−0.0021 (6)	−0.0095 (7)	−0.0070 (7)

S1—O3	1.4295 (13)	C8—C9	1.381 (2)
S1—O2	1.4350 (12)	C8—H8A	0.9500
S1—N3	1.6116 (14)	C9—C10	1.400 (2)
S1—C16	1.7793 (16)	C9—H9A	0.9500
S2—C18	1.7012 (19)	C10—C11	1.393 (2)
S2—C15	1.7138 (16)	C10—C13	1.453 (2)
S3—C22	1.712 (3)	C11—C12	1.387 (2)
S3—C23	1.7270 (17)	C11—H11A	0.9500
O1—C14	1.3561 (19)	C12—H12A	0.9500
O1—C13	1.367 (2)	C14—C15	1.447 (2)
N1—C13	1.298 (2)	C15—C16	1.386 (2)
N1—N2	1.409 (2)	C16—C17	1.417 (2)
N2—C14	1.298 (2)	C17—C18	1.365 (2)
N3—C19	1.467 (2)	C17—H17A	0.9500
N3—C25	1.477 (2)	C18—H18A	0.9500
C1—C2	1.386 (2)	C19—C20	1.510 (2)
C1—C6	1.401 (2)	C19—H19A	0.9900
C1—H1A	0.9500	C19—H19B	0.9900
C2—C3	1.389 (3)	C20—C23	1.357 (3)
C2—H2A	0.9500	C20—C21	1.419 (3)
C3—C4	1.382 (3)	C21—C22	1.363 (3)
C3—H3A	0.9500	C21—H21A	0.9500
C4—C5	1.382 (3)	C22—H22A	0.9500
C4—H4A	0.9500	C23—C24	1.499 (3)
C5—C6	1.403 (2)	C24—C25	1.528 (2)
C5—H5A	0.9500	C24—H24A	0.9900
C6—C7	1.484 (2)	C24—H24B	0.9900
C7—C12	1.400 (2)	C25—H25A	0.9900
C7—C8	1.405 (2)	C25—H25B	0.9900
O3—S1—O2	119.80 (8)	C7—C12—H12A	119.4
O3—S1—N3	107.36 (7)	N1—C13—O1	112.21 (15)
O2—S1—N3	107.62 (7)	N1—C13—C10	129.83 (16)
O3—S1—C16	107.66 (8)	O1—C13—C10	117.95 (14)
O2—S1—C16	107.45 (7)	N2—C14—O1	112.94 (15)
N3—S1—C16	106.22 (8)	N2—C14—C15	127.56 (15)
C18—S2—C15	92.10 (8)	O1—C14—C15	119.40 (14)
C22—S3—C23	91.92 (9)	C16—C15—C14	130.54 (15)
C14—O1—C13	102.72 (12)	C16—C15—S2	111.12 (12)
C13—N1—N2	106.34 (14)	C14—C15—S2	118.16 (12)
C14—N2—N1	105.78 (14)	C15—C16—C17	112.11 (14)
C19—N3—C25	114.76 (13)	C15—C16—S1	126.07 (13)
C19—N3—S1	121.74 (11)	C17—C16—S1	121.82 (13)
C25—N3—S1	121.27 (12)	C18—C17—C16	112.37 (16)
C2—C1—C6	120.71 (16)	C18—C17—H17A	123.8
C2—C1—H1A	119.6	C16—C17—H17A	123.8
C6—C1—H1A	119.6	C17—C18—S2	112.29 (13)
C1—C2—C3	120.59 (18)	C17—C18—H18A	123.9
C1—C2—H2A	119.7	S2—C18—H18A	123.9
C3—C2—H2A	119.7	N3—C19—C20	107.80 (14)
C4—C3—C2	119.14 (17)	N3—C19—H19A	110.1
C4—C3—H3A	120.4	C20—C19—H19A	110.1
C2—C3—H3A	120.4	N3—C19—H19B	110.1
C5—C4—C3	120.74 (17)	C20—C19—H19B	110.1
C5—C4—H4A	119.6	H19A—C19—H19B	108.5
C3—C4—H4A	119.6	C23—C20—C21	113.21 (17)
C4—C5—C6	120.89 (17)	C23—C20—C19	122.01 (16)
C4—C5—H5A	119.6	C21—C20—C19	124.71 (17)
C6—C5—H5A	119.6	C22—C21—C20	112.31 (19)
C1—C6—C5	117.87 (16)	C22—C21—H21A	123.8
C1—C6—C7	121.56 (15)	C20—C21—H21A	123.8
C5—C6—C7	120.56 (16)	C21—C22—S3	111.67 (16)
C12—C7—C8	117.65 (15)	C21—C22—H22A	124.2
C12—C7—C6	121.74 (15)	S3—C22—H22A	124.2
C8—C7—C6	120.61 (15)	C20—C23—C24	125.40 (15)
C9—C8—C7	121.50 (15)	C20—C23—S3	110.88 (14)
C9—C8—H8A	119.2	C24—C23—S3	123.68 (13)
C7—C8—H8A	119.2	C23—C24—C25	108.88 (14)
C8—C9—C10	120.02 (16)	C23—C24—H24A	109.9
C8—C9—H9A	120.0	C25—C24—H24A	109.9
C10—C9—H9A	120.0	C23—C24—H24B	109.9
C11—C10—C9	119.27 (15)	C25—C24—H24B	109.9
C11—C10—C13	120.89 (15)	H24A—C24—H24B	108.3
C9—C10—C13	119.84 (15)	N3—C25—C24	109.48 (13)
C12—C11—C10	120.28 (15)	N3—C25—H25A	109.8
C12—C11—H11A	119.9	C24—C25—H25A	109.8
C10—C11—H11A	119.9	N3—C25—H25B	109.8
C11—C12—C7	121.25 (16)	C24—C25—H25B	109.8
C11—C12—H12A	119.4	H25A—C25—H25B	108.2
C13—N1—N2—C14	−0.1 (2)	C13—O1—C14—C15	176.18 (15)
O3—S1—N3—C19	163.96 (12)	N2—C14—C15—C16	−179.39 (18)
O2—S1—N3—C19	33.75 (15)	O1—C14—C15—C16	4.5 (3)
C16—S1—N3—C19	−81.09 (14)	N2—C14—C15—S2	5.9 (3)
O3—S1—N3—C25	−33.90 (14)	O1—C14—C15—S2	−170.19 (12)
O2—S1—N3—C25	−164.11 (12)	C18—S2—C15—C16	−0.32 (14)
C16—S1—N3—C25	81.06 (14)	C18—S2—C15—C14	175.35 (15)
C6—C1—C2—C3	1.2 (3)	C14—C15—C16—C17	−174.82 (18)
C1—C2—C3—C4	−2.6 (3)	S2—C15—C16—C17	0.16 (19)
C2—C3—C4—C5	1.6 (3)	C14—C15—C16—S1	5.0 (3)
C3—C4—C5—C6	0.8 (3)	S2—C15—C16—S1	179.99 (10)
C2—C1—C6—C5	1.2 (3)	O3—S1—C16—C15	−71.56 (17)
C2—C1—C6—C7	−177.54 (16)	O2—S1—C16—C15	58.74 (17)
C4—C5—C6—C1	−2.2 (3)	N3—S1—C16—C15	173.69 (15)
C4—C5—C6—C7	176.57 (16)	O3—S1—C16—C17	108.25 (16)
C1—C6—C7—C12	−22.9 (3)	O2—S1—C16—C17	−121.45 (15)
C5—C6—C7—C12	158.41 (17)	N3—S1—C16—C17	−6.50 (17)
C1—C6—C7—C8	156.82 (17)	C15—C16—C17—C18	0.1 (2)
C5—C6—C7—C8	−21.9 (3)	S1—C16—C17—C18	−179.69 (14)
C12—C7—C8—C9	−1.2 (3)	C16—C17—C18—S2	−0.4 (2)
C6—C7—C8—C9	179.15 (17)	C15—S2—C18—C17	0.41 (16)
C7—C8—C9—C10	0.9 (3)	C25—N3—C19—C20	50.82 (18)
C8—C9—C10—C11	0.3 (3)	S1—N3—C19—C20	−145.95 (12)
C8—C9—C10—C13	−179.58 (17)	N3—C19—C20—C23	−16.1 (2)
C9—C10—C11—C12	−1.1 (3)	N3—C19—C20—C21	160.65 (16)
C13—C10—C11—C12	178.72 (17)	C23—C20—C21—C22	0.9 (2)
C10—C11—C12—C7	0.8 (3)	C19—C20—C21—C22	−176.09 (16)
C8—C7—C12—C11	0.3 (3)	C20—C21—C22—S3	−0.7 (2)
C6—C7—C12—C11	179.98 (16)	C23—S3—C22—C21	0.29 (15)
N2—N1—C13—O1	−0.2 (2)	C21—C20—C23—C24	−178.48 (16)
N2—N1—C13—C10	−179.90 (17)	C19—C20—C23—C24	−1.4 (3)
C14—O1—C13—N1	0.41 (19)	C21—C20—C23—S3	−0.71 (19)
C14—O1—C13—C10	−179.86 (15)	C19—C20—C23—S3	176.41 (13)
C11—C10—C13—N1	10.6 (3)	C22—S3—C23—C20	0.25 (14)
C9—C10—C13—N1	−169.55 (18)	C22—S3—C23—C24	178.07 (15)
C11—C10—C13—O1	−169.08 (15)	C20—C23—C24—C25	−12.7 (2)
C9—C10—C13—O1	10.8 (2)	S3—C23—C24—C25	169.83 (12)
N1—N2—C14—O1	0.4 (2)	C19—N3—C25—C24	−67.81 (18)
N1—N2—C14—C15	−175.96 (17)	S1—N3—C25—C24	128.87 (14)
C13—O1—C14—N2	−0.48 (19)	C23—C24—C25—N3	43.51 (19)

D—H···A	D—H	H···A	D···A	D—H···A
C24—H24A···N1i	0.99	2.52	3.417 (2)	150

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C24—H24A⋯N1i	0.99	2.52	3.417 (2)	150

Symmetry code: (i) .