Ethyl 1-(4-methyl-phen-yl)-5-phenyl-4-phenyl-sulfon-yl-1H-pyrazole-3-carboxyl-ate.

The title compound, C(25)H(22)N(2)O(4)S, features a tetra-substituted pyrazole ring. The dihedral angles formed between the five-membered ring (r.m.s. deviation = 0.007 Å) and the N- and C-bound phenyl rings are 48.10 (7) and 72.01 (7) °, respectively, indicating that the planes through the residues are significantly twisted from the plane through the heterocycle. The ester-CO(2) group is also twisted out of this plane, with an O-C-C-N torsion angle of -29.04 (11)°. The sulfonyl-O atoms lie to one side of the pyrazole plane and the sulfonyl-phenyl ring to the other. The dihedral angle between the two ring planes is 70.63 (7) °. Supra-molecular arrays are formed in the crystal structure sustained by C-H⋯O and C-H⋯π(pyrazole) inter-actions and methyl-C-H⋯π(N-bound benzene) contacts.

Related literature

For background to the chemistry and biological activity of pyrazole derivatives, see: Abdel-Wahab et al. (2009 ▶); Abdel-Aziz et al. (2009 ▶, 2010 ▶).

Experimental

Crystal data

C25H22N2O4S

M = 446.51

Triclinic,

a = 7.2440 (3) Å

b = 11.0798 (5) Å

c = 14.8247 (5) Å

α = 68.818 (4)°

β = 87.773 (3)°

γ = 81.241 (4)°

V = 1096.36 (8) Å3

Z = 2

Cu Kα radiation

μ = 1.60 mm−1

T = 100 K

0.40 × 0.30 × 0.20 mm

Data collection

Agilent SuperNova Dual diffractometer with Atlas detector

Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2010 ▶) T min = 0.566, T max = 0.740

7378 measured reflections

4304 independent reflections

4106 reflections with I > 2σ(I)

R int = 0.014

Refinement

R[F 2 > 2σ(F 2)] = 0.034

wR(F 2) = 0.091

S = 0.85

4304 reflections

290 parameters

H-atom parameters constrained

Δρmax = 0.35 e Å−3

Δρmin = −0.42 e Å−3

Data collection: CrysAlis PRO (Agilent, 2010 ▶); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶) and DIAMOND (Brandenburg, 2006 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536811036580/bt5639sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811036580/bt5639Isup2.hkl

Supplementary material file. DOI: 10.1107/S1600536811036580/bt5639Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C25H22N2O4S	Z = 2
Mr = 446.51	F(000) = 468
Triclinic, P1	Dx = 1.353 Mg m−3
Hall symbol: -P 1	Cu Kα radiation, λ = 1.54184 Å
a = 7.2440 (3) Å	Cell parameters from 5331 reflections
b = 11.0798 (5) Å	θ = 3.2–74.1°
c = 14.8247 (5) Å	µ = 1.60 mm−1
α = 68.818 (4)°	T = 100 K
β = 87.773 (3)°	Block, yellow
γ = 81.241 (4)°	0.40 × 0.30 × 0.20 mm
V = 1096.36 (8) Å3

Agilent SuperNova Dual diffractometer with Atlas detector	4304 independent reflections
Radiation source: SuperNova (Cu) X-ray Source	4106 reflections with I > 2σ(I)
mirror	Rint = 0.014
Detector resolution: 10.4041 pixels mm-1	θmax = 74.3°, θmin = 3.2°
ω scan	h = −8→8
Absorption correction: multi-scan (CrysAlis PRO; Agilent, 2010)	k = −12→13
Tmin = 0.566, Tmax = 0.740	l = −18→15
7378 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.034	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.091	H-atom parameters constrained
S = 0.85	w = 1/[σ2(Fo2) + (0.060P)2 + 0.8665P] where P = (Fo2 + 2Fc2)/3
4304 reflections	(Δ/σ)max < 0.001
290 parameters	Δρmax = 0.35 e Å−3
0 restraints	Δρmin = −0.42 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
S1	0.44173 (4)	0.70984 (3)	0.10567 (2)	0.01551 (10)
O1	0.24561 (13)	0.75817 (9)	0.09106 (7)	0.0201 (2)
O2	0.54033 (14)	0.66162 (9)	0.03658 (7)	0.0202 (2)
O3	0.08177 (14)	0.59487 (10)	0.38398 (9)	0.0275 (2)
O4	0.19467 (16)	0.77438 (10)	0.28475 (8)	0.0280 (2)
N1	0.40421 (15)	0.44865 (11)	0.36938 (8)	0.0161 (2)
N2	0.55383 (15)	0.39169 (10)	0.33340 (8)	0.0150 (2)
C1	−0.2495 (2)	0.66923 (19)	0.37793 (12)	0.0333 (4)
H1A	−0.3481	0.7238	0.3990	0.050*
H1B	−0.2743	0.5785	0.4023	0.050*
H1C	−0.2470	0.7016	0.3071	0.050*
C2	−0.0656 (2)	0.67488 (16)	0.41664 (13)	0.0286 (3)
H2A	−0.0413	0.7666	0.3935	0.034*
H2B	−0.0672	0.6418	0.4882	0.034*
C3	0.20136 (18)	0.65804 (13)	0.31954 (9)	0.0171 (3)
C4	0.35304 (18)	0.56389 (12)	0.30001 (9)	0.0156 (3)
C5	0.46821 (18)	0.58099 (12)	0.21819 (9)	0.0152 (3)
C6	0.59874 (18)	0.46782 (12)	0.24248 (9)	0.0148 (3)
C7	0.55863 (19)	0.83215 (12)	0.11696 (9)	0.0171 (3)
C8	0.7518 (2)	0.82100 (14)	0.10621 (10)	0.0225 (3)
H8	0.8189	0.7490	0.0927	0.027*
C9	0.8443 (2)	0.91673 (15)	0.11553 (12)	0.0272 (3)
H9	0.9760	0.9106	0.1086	0.033*
C10	0.7444 (2)	1.02163 (14)	0.13504 (11)	0.0271 (3)
H10	0.8083	1.0868	0.1417	0.033*
C11	0.5522 (2)	1.03192 (14)	0.14486 (11)	0.0247 (3)
H11	0.4851	1.1045	0.1577	0.030*
C12	0.4571 (2)	0.93691 (13)	0.13606 (10)	0.0206 (3)
H12	0.3254	0.9434	0.1429	0.025*
C13	0.76709 (18)	0.42800 (12)	0.19410 (9)	0.0149 (3)
C14	0.94252 (19)	0.42706 (13)	0.23053 (10)	0.0182 (3)
H14	0.9520	0.4530	0.2845	0.022*
C15	1.10313 (19)	0.38814 (13)	0.18770 (10)	0.0207 (3)
H15	1.2224	0.3885	0.2120	0.025*
C16	1.0902 (2)	0.34872 (13)	0.10965 (10)	0.0209 (3)
H16	1.2004	0.3216	0.0808	0.025*
C17	0.9159 (2)	0.34899 (13)	0.07374 (10)	0.0204 (3)
H17	0.9071	0.3216	0.0205	0.025*
C18	0.75398 (19)	0.38910 (13)	0.11527 (9)	0.0179 (3)
H18	0.6350	0.3900	0.0901	0.022*
C19	0.63396 (17)	0.26085 (12)	0.39171 (9)	0.0155 (3)
C20	0.66215 (19)	0.16297 (13)	0.35283 (10)	0.0184 (3)
H20	0.6400	0.1831	0.2859	0.022*
C21	0.72330 (19)	0.03502 (13)	0.41333 (10)	0.0203 (3)
H21	0.7447	−0.0321	0.3869	0.024*
C22	0.75393 (19)	0.00307 (13)	0.51205 (10)	0.0185 (3)
C23	0.72672 (19)	0.10390 (13)	0.54866 (10)	0.0188 (3)
H23	0.7490	0.0843	0.6155	0.023*
C24	0.66765 (18)	0.23258 (13)	0.48902 (10)	0.0173 (3)
H24	0.6506	0.3005	0.5148	0.021*
C25	0.8151 (2)	−0.13619 (13)	0.57784 (11)	0.0236 (3)
H25A	0.7437	−0.1943	0.5618	0.035*
H25B	0.7929	−0.1440	0.6452	0.035*
H25C	0.9485	−0.1610	0.5694	0.035*

	U11	U22	U33	U12	U13	U23
S1	0.01730 (17)	0.01487 (16)	0.01383 (16)	−0.00005 (12)	−0.00058 (11)	−0.00538 (12)
O1	0.0178 (5)	0.0213 (5)	0.0204 (5)	0.0010 (4)	−0.0032 (4)	−0.0078 (4)
O2	0.0245 (5)	0.0202 (5)	0.0160 (5)	0.0000 (4)	0.0020 (4)	−0.0081 (4)
O3	0.0186 (5)	0.0235 (5)	0.0454 (7)	−0.0040 (4)	0.0133 (4)	−0.0193 (5)
O4	0.0408 (6)	0.0168 (5)	0.0235 (5)	0.0020 (4)	0.0076 (4)	−0.0071 (4)
N1	0.0138 (5)	0.0168 (5)	0.0186 (5)	−0.0007 (4)	0.0022 (4)	−0.0082 (4)
N2	0.0137 (5)	0.0147 (5)	0.0161 (5)	0.0000 (4)	0.0019 (4)	−0.0059 (4)
C1	0.0208 (8)	0.0498 (10)	0.0336 (9)	0.0035 (7)	0.0001 (6)	−0.0237 (8)
C2	0.0190 (7)	0.0290 (8)	0.0450 (9)	−0.0018 (6)	0.0104 (6)	−0.0237 (7)
C3	0.0162 (6)	0.0197 (6)	0.0172 (6)	−0.0001 (5)	−0.0026 (5)	−0.0096 (5)
C4	0.0145 (6)	0.0162 (6)	0.0174 (6)	−0.0017 (5)	−0.0006 (5)	−0.0079 (5)
C5	0.0158 (6)	0.0146 (6)	0.0159 (6)	−0.0019 (5)	−0.0003 (5)	−0.0065 (5)
C6	0.0153 (6)	0.0156 (6)	0.0151 (6)	−0.0035 (5)	−0.0003 (5)	−0.0068 (5)
C7	0.0204 (7)	0.0145 (6)	0.0143 (6)	−0.0021 (5)	−0.0003 (5)	−0.0029 (5)
C8	0.0215 (7)	0.0195 (7)	0.0240 (7)	−0.0006 (5)	0.0022 (5)	−0.0062 (6)
C9	0.0211 (7)	0.0243 (7)	0.0330 (8)	−0.0051 (6)	0.0006 (6)	−0.0059 (6)
C10	0.0314 (8)	0.0199 (7)	0.0294 (8)	−0.0087 (6)	−0.0025 (6)	−0.0059 (6)
C11	0.0310 (8)	0.0150 (6)	0.0271 (7)	−0.0011 (6)	−0.0006 (6)	−0.0072 (6)
C12	0.0212 (7)	0.0172 (6)	0.0208 (7)	0.0002 (5)	−0.0005 (5)	−0.0050 (5)
C13	0.0164 (6)	0.0118 (6)	0.0152 (6)	−0.0012 (5)	0.0020 (5)	−0.0037 (5)
C14	0.0192 (7)	0.0178 (6)	0.0193 (6)	−0.0036 (5)	0.0011 (5)	−0.0083 (5)
C15	0.0160 (7)	0.0202 (7)	0.0249 (7)	−0.0030 (5)	0.0014 (5)	−0.0070 (5)
C16	0.0209 (7)	0.0169 (6)	0.0223 (7)	−0.0007 (5)	0.0075 (5)	−0.0055 (5)
C17	0.0264 (7)	0.0179 (6)	0.0171 (6)	−0.0013 (5)	0.0033 (5)	−0.0075 (5)
C18	0.0195 (7)	0.0173 (6)	0.0173 (6)	−0.0020 (5)	−0.0006 (5)	−0.0068 (5)
C19	0.0122 (6)	0.0137 (6)	0.0188 (6)	−0.0014 (5)	0.0018 (5)	−0.0040 (5)
C20	0.0184 (7)	0.0191 (6)	0.0183 (6)	−0.0026 (5)	0.0015 (5)	−0.0077 (5)
C21	0.0200 (7)	0.0167 (6)	0.0258 (7)	−0.0025 (5)	0.0037 (5)	−0.0099 (5)
C22	0.0134 (6)	0.0166 (6)	0.0233 (7)	−0.0025 (5)	0.0029 (5)	−0.0046 (5)
C23	0.0169 (6)	0.0199 (7)	0.0177 (6)	−0.0028 (5)	0.0013 (5)	−0.0046 (5)
C24	0.0165 (6)	0.0168 (6)	0.0192 (6)	−0.0022 (5)	0.0020 (5)	−0.0073 (5)
C25	0.0216 (7)	0.0168 (7)	0.0278 (7)	−0.0017 (5)	0.0031 (6)	−0.0033 (6)

S1—O1	1.4354 (10)	C11—C12	1.388 (2)
S1—O2	1.4378 (10)	C11—H11	0.9500
S1—C5	1.7544 (13)	C12—H12	0.9500
S1—C7	1.7624 (14)	C13—C18	1.3947 (18)
O3—C3	1.3380 (17)	C13—C14	1.3971 (19)
O3—C2	1.4635 (16)	C14—C15	1.3894 (19)
O4—C3	1.1968 (17)	C14—H14	0.9500
N1—C4	1.3274 (17)	C15—C16	1.387 (2)
N1—N2	1.3592 (15)	C15—H15	0.9500
N2—C6	1.3646 (17)	C16—C17	1.389 (2)
N2—C19	1.4362 (16)	C16—H16	0.9500
C1—C2	1.489 (2)	C17—C18	1.3909 (19)
C1—H1A	0.9800	C17—H17	0.9500
C1—H1B	0.9800	C18—H18	0.9500
C1—H1C	0.9800	C19—C24	1.3843 (19)
C2—H2A	0.9900	C19—C20	1.3875 (18)
C2—H2B	0.9900	C20—C21	1.3897 (19)
C3—C4	1.4913 (17)	C20—H20	0.9500
C4—C5	1.4165 (18)	C21—C22	1.394 (2)
C5—C6	1.3911 (18)	C21—H21	0.9500
C6—C13	1.4809 (17)	C22—C23	1.3942 (19)
C7—C12	1.3891 (19)	C22—C25	1.5054 (18)
C7—C8	1.394 (2)	C23—C24	1.3893 (19)
C8—C9	1.387 (2)	C23—H23	0.9500
C8—H8	0.9500	C24—H24	0.9500
C9—C10	1.389 (2)	C25—H25A	0.9800
C9—H9	0.9500	C25—H25B	0.9800
C10—C11	1.386 (2)	C25—H25C	0.9800
C10—H10	0.9500
O1—S1—O2	119.33 (6)	C12—C11—H11	119.8
O1—S1—C5	106.92 (6)	C10—C11—H11	119.8
O2—S1—C5	106.93 (6)	C11—C12—C7	118.58 (13)
O1—S1—C7	109.11 (6)	C11—C12—H12	120.7
O2—S1—C7	107.81 (6)	C7—C12—H12	120.7
C5—S1—C7	105.98 (6)	C18—C13—C14	119.85 (12)
C3—O3—C2	117.09 (11)	C18—C13—C6	121.66 (12)
C4—N1—N2	104.77 (10)	C14—C13—C6	118.48 (11)
N1—N2—C6	113.13 (10)	C15—C14—C13	119.85 (12)
N1—N2—C19	117.27 (10)	C15—C14—H14	120.1
C6—N2—C19	129.49 (11)	C13—C14—H14	120.1
C2—C1—H1A	109.5	C16—C15—C14	120.34 (13)
C2—C1—H1B	109.5	C16—C15—H15	119.8
H1A—C1—H1B	109.5	C14—C15—H15	119.8
C2—C1—H1C	109.5	C15—C16—C17	119.82 (12)
H1A—C1—H1C	109.5	C15—C16—H16	120.1
H1B—C1—H1C	109.5	C17—C16—H16	120.1
O3—C2—C1	109.39 (12)	C16—C17—C18	120.42 (13)
O3—C2—H2A	109.8	C16—C17—H17	119.8
C1—C2—H2A	109.8	C18—C17—H17	119.8
O3—C2—H2B	109.8	C17—C18—C13	119.72 (13)
C1—C2—H2B	109.8	C17—C18—H18	120.1
H2A—C2—H2B	108.2	C13—C18—H18	120.1
O4—C3—O3	125.36 (12)	C24—C19—C20	120.89 (12)
O4—C3—C4	123.58 (13)	C24—C19—N2	118.50 (11)
O3—C3—C4	110.98 (11)	C20—C19—N2	120.40 (12)
N1—C4—C5	111.39 (11)	C21—C20—C19	119.00 (12)
N1—C4—C3	118.83 (11)	C21—C20—H20	120.5
C5—C4—C3	129.57 (12)	C19—C20—H20	120.5
C6—C5—C4	105.42 (11)	C20—C21—C22	121.40 (13)
C6—C5—S1	126.52 (10)	C20—C21—H21	119.3
C4—C5—S1	127.84 (10)	C22—C21—H21	119.3
N2—C6—C5	105.29 (11)	C23—C22—C21	118.19 (12)
N2—C6—C13	121.29 (11)	C23—C22—C25	120.56 (13)
C5—C6—C13	133.20 (12)	C21—C22—C25	121.25 (13)
C12—C7—C8	121.65 (13)	C24—C23—C22	121.16 (13)
C12—C7—S1	119.59 (11)	C24—C23—H23	119.4
C8—C7—S1	118.76 (10)	C22—C23—H23	119.4
C9—C8—C7	118.91 (13)	C19—C24—C23	119.33 (12)
C9—C8—H8	120.5	C19—C24—H24	120.3
C7—C8—H8	120.5	C23—C24—H24	120.3
C10—C9—C8	119.93 (14)	C22—C25—H25A	109.5
C10—C9—H9	120.0	C22—C25—H25B	109.5
C8—C9—H9	120.0	H25A—C25—H25B	109.5
C9—C10—C11	120.51 (14)	C22—C25—H25C	109.5
C9—C10—H10	119.7	H25A—C25—H25C	109.5
C11—C10—H10	119.7	H25B—C25—H25C	109.5
C12—C11—C10	120.40 (13)
C4—N1—N2—C6	−0.25 (14)	C12—C7—C8—C9	0.4 (2)
C4—N1—N2—C19	−176.77 (11)	S1—C7—C8—C9	−179.68 (11)
C3—O3—C2—C1	110.72 (15)	C7—C8—C9—C10	−0.2 (2)
C2—O3—C3—O4	−2.0 (2)	C8—C9—C10—C11	−0.3 (2)
C2—O3—C3—C4	174.84 (12)	C9—C10—C11—C12	0.5 (2)
N2—N1—C4—C5	0.83 (14)	C10—C11—C12—C7	−0.2 (2)
N2—N1—C4—C3	−174.42 (11)	C8—C7—C12—C11	−0.3 (2)
O4—C3—C4—N1	147.76 (14)	S1—C7—C12—C11	179.87 (11)
O3—C3—C4—N1	−29.15 (17)	N2—C6—C13—C18	109.94 (15)
O4—C3—C4—C5	−26.5 (2)	C5—C6—C13—C18	−76.46 (19)
O3—C3—C4—C5	156.60 (13)	N2—C6—C13—C14	−68.59 (16)
N1—C4—C5—C6	−1.11 (15)	C5—C6—C13—C14	105.00 (17)
C3—C4—C5—C6	173.49 (13)	C18—C13—C14—C15	0.40 (19)
N1—C4—C5—S1	173.74 (10)	C6—C13—C14—C15	178.96 (12)
C3—C4—C5—S1	−11.7 (2)	C13—C14—C15—C16	−0.8 (2)
O1—S1—C5—C6	145.06 (11)	C14—C15—C16—C17	0.4 (2)
O2—S1—C5—C6	16.17 (13)	C15—C16—C17—C18	0.3 (2)
C7—S1—C5—C6	−98.65 (12)	C16—C17—C18—C13	−0.6 (2)
O1—S1—C5—C4	−28.76 (13)	C14—C13—C18—C17	0.31 (19)
O2—S1—C5—C4	−157.65 (12)	C6—C13—C18—C17	−178.21 (12)
C7—S1—C5—C4	87.53 (13)	N1—N2—C19—C24	−46.78 (16)
N1—N2—C6—C5	−0.43 (14)	C6—N2—C19—C24	137.37 (14)
C19—N2—C6—C5	175.56 (12)	N1—N2—C19—C20	127.96 (13)
N1—N2—C6—C13	174.73 (11)	C6—N2—C19—C20	−47.90 (19)
C19—N2—C6—C13	−9.3 (2)	C24—C19—C20—C21	0.6 (2)
C4—C5—C6—N2	0.88 (14)	N2—C19—C20—C21	−173.97 (12)
S1—C5—C6—N2	−174.06 (10)	C19—C20—C21—C22	1.0 (2)
C4—C5—C6—C13	−173.44 (13)	C20—C21—C22—C23	−1.8 (2)
S1—C5—C6—C13	11.6 (2)	C20—C21—C22—C25	178.30 (13)
O1—S1—C7—C12	16.54 (13)	C21—C22—C23—C24	1.1 (2)
O2—S1—C7—C12	147.52 (11)	C25—C22—C23—C24	−179.04 (12)
C5—S1—C7—C12	−98.27 (11)	C20—C19—C24—C23	−1.4 (2)
O1—S1—C7—C8	−163.34 (10)	N2—C19—C24—C23	173.35 (11)
O2—S1—C7—C8	−32.36 (12)	C22—C23—C24—C19	0.5 (2)
C5—S1—C7—C8	81.85 (12)

Cg1 and Cg2 are the centroids of the N1,N2,C4–C6 and C19–C24 rings, respectively.

D—H···A	D—H	H···A	D···A	D—H···A
C9—H9···O1i	0.95	2.45	3.2392 (19)	140
C16—H16···O2ii	0.95	2.49	3.3928 (18)	158
C17—H17···O1iii	0.95	2.50	3.3895 (18)	157
C18—H18···O2iii	0.95	2.58	3.4031 (17)	145
C23—H23···O4iv	0.95	2.59	3.3155 (18)	133
C15—H15···Cg1i	0.95	2.80	3.6781 (15)	154
C25—H25c···Cg2v	0.98	2.64	3.5649 (16)	157

Table 1

Hydrogen-bond geometry (Å, °)

Cg1 and Cg2 are the centroids of the N1,N2,C4–C6 and C19–C24 rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C9—H9⋯O1i	0.95	2.45	3.2392 (19)	140
C16—H16⋯O2ii	0.95	2.49	3.3928 (18)	158
C17—H17⋯O1iii	0.95	2.50	3.3895 (18)	157
C18—H18⋯O2iii	0.95	2.58	3.4031 (17)	145
C23—H23⋯O4iv	0.95	2.59	3.3155 (18)	133
C15—H15⋯Cg1i	0.95	2.80	3.6781 (15)	154
C25—H25c⋯Cg2v	0.98	2.64	3.5649 (16)	157

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) .