| Literature DB >> 22046963 |
Joseph B Edson1, Liam P Spencer, James M Boncella.
Abstract
Visible-light-absorbing tris(bipyridyl)ruthenium(II) has been used to mediate electron transfer to N-methylpicolinium carbamates that undergo C-O bond fragmentation followed by spontaneous carbon dioxide release to give free amines. Release of several aliphatic and aromatic primary amines has been demonstrated under mild conditions using visible light.Entities:
Year: 2011 PMID: 22046963 DOI: 10.1021/ol202456d
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005