Literature DB >> 22043810

Magic acid free generation of antiaromatic dications at room temperature.

Sean P McClintock1, Nancy S Mills.   

Abstract

A new method for the generation of dicationic species via ionization of diols is described. The method makes use of milder reagents at room temperatures, an advantage over use of Magic Acid at -78 °C. A series of mono- and dications were synthesized successfully, including previously unattainable species.

Entities:  

Year:  2011        PMID: 22043810     DOI: 10.1021/jo201512n

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

Review 1.  Superelectrophiles: Recent Advances.

Authors:  Douglas A Klumpp; Maksim V Anokhin
Journal:  Molecules       Date:  2020-07-19       Impact factor: 4.411

  1 in total

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