Literature DB >> 22038098

Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols.

Ekambaram Balaraman1, Eran Fogler, David Milstein.   

Abstract

The unprecedented homogeneous hydrogenation of cyclic di-esters, in particular biomass-derived glycolide and lactide, to the corresponding 1,2-diols is catalyzed by Ru(II) PNN (1) and Ru(II) CNN (2) pincer complexes under mild hydrogen pressure and (in the case of 1) neutral conditions. No racemization was observed when a chiral di-ester was used.

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Year:  2011        PMID： 22038098     DOI： 10.1039/c1cc15778g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions.

Authors:  Sandra Y de Boer; Ties J Korstanje; Stefan R La Rooij; Rogier Kox; Joost N H Reek; Jarl Ivar van der Vlugt
Journal:  Organometallics       Date:  2017-04-06       Impact factor: 3.876

2.  Biocatalytic Production of Amino Carbohydrates through Oxidoreductase and Transaminase Cascades.

Authors:  Ville Aumala; Filip Mollerup; Edita Jurak; Fabian Blume; Johanna Karppi; Antti E Koistinen; Eva Schuiten; Moritz Voß; Uwe Bornscheuer; Jan Deska; Emma R Master
Journal:  ChemSusChem       Date:  2019-01-29       Impact factor: 8.928

3.  Ruthenium-Catalyzed Hydrogenative Degradation of End-of-Life Poly(lactide) to Produce 1,2-Propanediol as Platform Chemical.

Authors:  Tim-Oliver Kindler; Christoph Alberti; Elena Fedorenko; Nicolo Santangelo; Stephan Enthaler
Journal:  ChemistryOpen       Date:  2020-04-01       Impact factor: 2.911
  3 in total

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