Literature DB >> 22037478

TBHP-mediated oxidative thiolation of an sp3 C-H bond adjacent to a nitrogen atom in an amide.

Ri-Yuan Tang1, Ye-Xiang Xie, Yi-Li Xie, Jian-Nan Xiang, Jin-Heng Li.   

Abstract

The first example of molecular sieve-promoted TBHP-mediated direct oxidative thiolation of an sp(3) C-H bond adjacent to a nitrogen atom with disulfides under metal-free conditions, which allows for preparation of numerous S,N-containing compounds, is presented. Moreover, diverse benzothiazoles and a fipronil analog can be synthesized through this strategy. This journal is © The Royal Society of Chemistry 2011

Entities:  

Year:  2011        PMID： 22037478     DOI： 10.1039/c1cc15397h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  Metal-Free Preparation of Cycloalkyl Aryl Sulfides via Di-tert-butyl Peroxide-Promoted Oxidative C(sp3)[BOND]H Bond Thiolation of Cycloalkanes.

Authors:  Jincan Zhao; Hong Fang; Jianlin Han; Yi Pan; Guigen Li
Journal:  Adv Synth Catal       Date:  2014-08-10       Impact factor: 5.837

2.  Synthesis of novel 2-methyl-3-furyl sulfide flavor derivatives as efficient preservatives.

Authors:  Jinxin Xie; Benjian Liao; Hui Zhu; Yongfei Yu; Ri-Yuan Tang
Journal:  RSC Adv       Date:  2021-07-26       Impact factor: 4.036

3.  Non-thermal atmospheric pressure plasma preferentially induces apoptosis in p53-mutated cancer cells by activating ROS stress-response pathways.

Authors:  Yonghao Ma; Chang Seung Ha; Seok Won Hwang; Hae June Lee; Gyoo Cheon Kim; Kyo-Won Lee; Kiwon Song
Journal:  PLoS One       Date:  2014-04-23       Impact factor: 3.240

4.  Non-Thermal Atmospheric Pressure Plasma Efficiently Promotes the Proliferation of Adipose Tissue-Derived Stem Cells by Activating NO-Response Pathways.

Authors:  Jeongyeon Park; Hyunyoung Lee; Hae June Lee; Gyoo Cheon Kim; Do Young Kim; Sungbum Han; Kiwon Song
Journal:  Sci Rep       Date:  2016-12-19       Impact factor: 4.379

5.  Toward Rational Understandings of α-C-H Functionalization: Energetic Studies of Representative Tertiary Amines.

Authors:  Wenzhi Luo; Jin-Dong Yang; Jin-Pei Cheng
Journal:  iScience       Date:  2020-01-21

6.  A photoexcited halogen-bonded EDA complex of the thiophenolate anion with iodobenzene for C(sp3)-H activation and thiolation.

Authors:  Tao Li; Kangjiang Liang; Jiaying Tang; Yuzhen Ding; Xiaogang Tong; Chengfeng Xia
Journal:  Chem Sci       Date:  2021-10-21       Impact factor: 9.825

7.  Catalyst-free reductive cyclization of bis(2-aminophenyl) disulfide with CO2 in the presence of BH3NH3 to synthesize 2-unsubstituted benzothiazole derivatives.

Authors:  Xiao Li; Zhenbao Liu; Hailong Hong; Limin Han; Ning Zhu
Journal:  RSC Adv       Date:  2022-06-20       Impact factor: 4.036

8.  Heterogeneous Catalytic Oxidation of Amides to Imides by Manganese Oxides.

Authors:  Sourav Biswas; Harshul S Khanna; Quddus A Nizami; Donald R Caldwell; Katherine T Cavanaugh; Amy R Howell; Sumathy Raman; Steven L Suib; Partha Nandi
Journal:  Sci Rep       Date:  2018-09-11       Impact factor: 4.379
  8 in total

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