| Literature DB >> 22025345 |
Juan Nicasio-Collazo1, Eleuterio Álvarez, José C Alvarado-Monzón, Gabriel Andreu-de-Riquer, J Oscar C Jimenez-Halla, Luis M De León-Rodríguez, Gabriel Merino, Ubaldo Morales, Oracio Serrano, Jorge A López.
Abstract
C-Br bond activation followed by a C-C coupling reaction of the 2-bromo-pyridyl unit of [1-phenyl-2-(6-bromopyridin-2-yl)-benzoimidazole] was performed by Pd(CH(2)CMe(2)-o-C(6)H(4))(η(4)-COD). Two new seven membered palladacycles were obtained. A combined experimental and theoretical DFT study elucidates the mechanism for this reaction.Entities:
Year: 2011 PMID： 22025345 DOI： 10.1039/c1dt11451d
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390