Dynamic assembly of block-copolymers.

Block copolymers (BCs) are well-known building blocks for the creation of a large variety of nanostructured materials or objects through a dynamic assembly stage which can be either autonomous or guided by an external force. Today's nanotechnologies require sharp control of the overall architecture from the nanoscale to the macroscale. BCs enable this dynamic assembly through all the scales, from few aggregated polymer chains to large bulk polymer materials. Since the discovery of controlled methods to polymerize monomers with different functionalities, a broad diversity of BCs exists, giving rise to many different nanoobjects and nanostructured materials. This chapter will explore the potentialities of block copolymer chains to be assembled through dynamic interactions either in solution or in bulk.