| Literature DB >> 22023086 |
Nebojša Momčilović1, Paul G Clark, Andrew J Boydston, Robert H Grubbs.
Abstract
A one-pot synthesis of polyrotaxanes has been developed. The method employs a supramolecular monomer comprising a polymerizable ammonium salt and crown ether, in combination with dynamic ADMet polymerization. Ultimately, highly efficient complexation, polymerization, and end-capping were accomplished in a single operation to yield polyrotaxanes with M(w) up to 19.3 kDa and >80% of the repeat units being complexed.Entities:
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Year: 2011 PMID: 22023086 PMCID: PMC3236677 DOI: 10.1021/ja208515r
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419