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Literature DB >> 22022702

Simple inexpensive boron electrophiles for direct arene borylation.

Alessandro Del Grosso¹, Matthew D Helm, Sophia A Solomon, Dolores Caras-Quintero, Michael J Ingleson.

Abstract

Electrophilic direct borylation is facilitated, and arene substrate scope enhanced, by using electrophiles derived from inexpensive reagents; specifically an amine, BCl(3) and AlCl(3).

Entities: Chemical Gene

Year: 2011 PMID： 22022702 DOI： 10.1039/c1cc14226g

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

14 in total

1. Cationic tricoordinate boron intermediates: borenium chemistry from the organic perspective.

Authors: Timothy S De Vries; Aleksandrs Prokofjevs; Edwin Vedejs
Journal: Chem Rev Date: 2012-04-20 Impact factor: 60.622

2. Thermal Dehydrogenation of Base-Stabilized B2H5(+) Complexes and Its Role in C-H Borylation.

Authors: Aleksandrs Prokofjevs
Journal: Angew Chem Int Ed Engl Date: 2015-09-17 Impact factor: 15.336

3. Electrophilic C-H Borylation and Related Reactions of B-H Boron Cations.

Authors: Aleksandrs Prokofjevs; Janis Jermaks; Alina Borovika; Jeff W Kampf; Edwin Vedejs
Journal: Organometallics Date: 2013-11-25 Impact factor: 3.876

4. Haloboration of internal alkynes with boronium and borenium cations as a route to tetrasubstituted alkenes.

Authors: James R Lawson; Ewan R Clark; Ian A Cade; Sophia A Solomon; Michael J Ingleson
Journal: Angew Chem Int Ed Engl Date: 2013-06-05 Impact factor: 15.336

5. Probing the Boundaries between Lewis-Basic and Redox Behavior of a Parent Borylene.

Authors: Merle Arrowsmith; Sara Endres; Myron Heinz; Vincent Nestler; Max C Holthausen; Holger Braunschweig
Journal: Chemistry Date: 2021-11-11 Impact factor: 5.020

6. Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates: Application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenes.

Authors: George Iakobson; Junyi Du; Alexandra M Z Slawin; Petr Beier
Journal: Beilstein J Org Chem Date: 2015-08-26 Impact factor: 2.883

10. Use of N-methyliminodiacetic acid boronate esters in suzuki-miyaura cross-coupling polymerizations of triarylamine and fluorene monomers.

Authors: Andrew B Foster; Viktor Bagutski; Josue I Ayuso-Carrillo; Martin J Humphries; Michael J Ingleson; Michael L Turner
Journal: J Polym Sci A Polym Chem Date: 2017-07-03 Impact factor: 2.702