| Literature DB >> 22012482 |
Akihiro Hashikawa1, Makiko Fujimoto, Yoshihito Hayashi, Hitoshi Miyasaka.
Abstract
A polyoxotetradecamolybdate cluster [Mo(14)O(38)(OAc)(6)](2-), which has a lacunary core of the Wells-Dawson structure, is isolated by the reduction of [Mo(6)O(19)](2-). The Mo(14) core is comprised of a mixed valence of [Mo(V)(4)Mo(VI)(10)], exhibiting multi-step reversible redox processes that experience both oxidation and reduction.Entities:
Year: 2011 PMID： 22012482 DOI： 10.1039/c1cc15439g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222