| Literature DB >> 21999823 |
Laura C H Gerber1, Richard R Schrock, Peter Müller, Michael K Takase.
Abstract
Compounds that have the formula M(NR)(CHR')(OR″)(Pyrrolide), where OR″ is "large" relative to NR and M = Mo or W, have been shown to be Z-selective olefin metathesis catalysts. In this communication we report a new route to Mo complexes in which the relationship between NR and OR″ has been reversed; i.e., the imido ligand is the sterically demanding 2,6-dimesitylphenylimido ligand (NAr*).Entities:
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Year: 2011 PMID： 21999823 DOI： 10.1021/ja208936s
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419