Literature DB >> 21983699

pH-Driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes.

Celedonio M Álvarez1, Romen Carrillo, Raúl García-Rodríguez, Daniel Miguel.   

Abstract

Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre. This journal is © The Royal Society of Chemistry 2011

Entities:  

Year:  2011        PMID： 21983699     DOI： 10.1039/c1cc14799d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes.

Authors:  Nidal Saleh; Monika Srebro; Thibault Reynaldo; Nicolas Vanthuyne; Loïc Toupet; Victoria Y Chang; Gilles Muller; J A Gareth Williams; Christian Roussel; Jochen Autschbach; Jeanne Crassous
Journal:  Chem Commun (Camb)       Date:  2015-03-04       Impact factor: 6.222

2.  Characterization of Diastereomeric Equilibria of Pseudotetrahedral Bis[(R or S)-N-1-(Ar)Ethylsalicylaldiminato-κ2 N,O]zinc(II) with Λ/Δ-Chirality-At-Metal Induction.

Authors:  Mohammed Enamullah; Mohammad Mostafizur Rahman; Mohammad Khairul Islam; Dennis Woschko; Christoph Janiak; Gennaro Pescitelli
Journal:  ChemistryOpen       Date:  2022-07       Impact factor: 2.630

3.  Dirhenium Coordination Complex Endowed with an Intrinsically Chiral Helical-Shaped Diphosphine Oxide.

Authors:  Elsa Quartapelle Procopio; Davide Dova; Silvia Cauteruccio; Alessandra Forni; Emanuela Licandro; Monica Panigati
Journal:  ACS Omega       Date:  2018-09-24
  3 in total

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