| Literature DB >> 21972002 |
Elena Rabinovich1, Israel Goldberg, Zeev Gross.
Abstract
Corrole complexes with gold(I) and gold(III) were synthesized and their structural, photophysical, and electrochemical properties investigated. This work includes the X-ray crystallography characterization of gold(I) and gold(III) complexes, both chelated by a corrole with fully brominated β-pyrrole carbon atoms. The mononuclear and chiral gold(I) corrole appears to be the first of its kind within the porphyrinoid family, while the most unique property of the gold(III) corrole is that it displays phosphorescence at ambient temperatures.Entities:
Year: 2011 PMID: 21972002 DOI: 10.1002/chem.201102348
Source DB: PubMed Journal: Chemistry ISSN: 0947-6539 Impact factor: 5.236