| Literature DB >> 21962171 |
Cheng-Hua Yang1, Ch Prabhakar, Shou-Ling Huang, Ying-Chih Lin, Wei Shyang Tan, Nimesh C Misra, Wei-Ting Sun, Jye-Shane Yang.
Abstract
A pentiptycene-derived p-phenylenediamine mimics a molecular double-rotor system that displays redox-dependent rotation rates for the amino rotors about the pentiptycene-amine C-N bond. The rotation is accelerated in the radical cation state but stopped in the di(radical cation) state. Electronic interplay of the two rotors is also discussed.Entities:
Year: 2011 PMID： 21962171 DOI： 10.1021/ol202356t
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005