Literature DB >> 21961877

Diels-Alder via molecular recognition in a crystalline molecular flask.

Koki Ikemoto1, Yasuhide Inokuma, Makoto Fujita.   

Abstract

In the pore of a porous coordination network, Diels-Alder reactants, a diene and a dienophile, are recognized by donor-acceptor and multiple H-bond interactions, respectively, and fixed at ideal positions for the reaction. Heating the crystals promoted the Diels-Alder reactions with enhanced reactivity and controlled regioselectivity as clearly monitored by in situ X-ray crystallography.

Entities:  

Year:  2011        PMID： 21961877     DOI： 10.1021/ja2079064

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Virtual screening for high affinity guests for synthetic supramolecular receptors.

Authors:  William Cullen; Simon Turega; Christopher A Hunter; Michael D Ward
Journal:  Chem Sci       Date:  2015-03-10       Impact factor: 9.825

2.  A concerted two-prong approach to the in situ allosteric regulation of bifunctional catalysis.

Authors:  C Michael McGuirk; Jose Mendez-Arroyo; Andrea I d'Aquino; Charlotte L Stern; Yuan Liu; Chad A Mirkin
Journal:  Chem Sci       Date:  2016-07-18       Impact factor: 9.825

3.  Tailored oxido-vanadium(V) cage complexes for selective sulfoxidation in confined spaces.

Authors:  Dawei Zhang; Kelsey Jamieson; Laure Guy; Guohua Gao; Jean-Pierre Dutasta; Alexandre Martinez
Journal:  Chem Sci       Date:  2016-09-05       Impact factor: 9.825

4.  Coordination templated [2+2+2] cyclotrimerization in a porous coordination framework.

Authors:  Yong-Sheng Wei; Mei Zhang; Pei-Qin Liao; Rui-Biao Lin; Tai-Yang Li; Guang Shao; Jie-Peng Zhang; Xiao-Ming Chen
Journal:  Nat Commun       Date:  2015-09-18       Impact factor: 14.919

5.  An Iodine-Vapor-Induced Cyclization in a Crystalline Molecular Flask.

Authors:  Jane V Knichal; Helena J Shepherd; Chick C Wilson; Paul R Raithby; William J Gee; Andrew D Burrows
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-06       Impact factor: 15.336

6.  Design and self-assembly of hexahedral coordination cages for cascade reactions.

Authors:  Jingjing Jiao; Zijian Li; Zhiwei Qiao; Xu Li; Yan Liu; Jinqiao Dong; Jianwen Jiang; Yong Cui
Journal:  Nat Commun       Date:  2018-10-24       Impact factor: 14.919
  6 in total

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