Literature DB >> 21936560

Copper-catalyzed C(sp3)-C(sp3) bond formation using a hypervalent iodine reagent: an efficient allylic trifluoromethylation.

Xi Wang1, Yuxuan Ye, Songnan Zhang, Jiajie Feng, Yan Xu, Yan Zhang, Jianbo Wang.   

Abstract

An efficient copper-catalyzed allylic trifluoromethylation reaction has been developed. This reaction provides a general and straightforward way to synthesize allylic trifluoromethylated compounds under mild conditions.

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Year:  2011        PMID： 21936560     DOI： 10.1021/ja207775a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  29 in total

1.  Synthesis and applications of α-trifluoromethylated alkylboron compounds.

Authors:  O Andreea Argintaru; DaWeon Ryu; Ioana Aron; Gary A Molander
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-07       Impact factor: 15.336

2.  Allylic functionalization of unactivated olefins with Grignard reagents.

Authors:  Hongli Bao; Liela Bayeh; Uttam K Tambar
Journal:  Angew Chem Int Ed Engl       Date:  2014-01-23       Impact factor: 15.336

3.  Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes Mediated by a Metastable Charge-Transfer Complex.

Authors:  Juno C Siu; Joseph B Parry; Song Lin
Journal:  J Am Chem Soc       Date:  2019-01-28       Impact factor: 15.419

4.  Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.

Authors:  Rong Zhu; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2012-07-23       Impact factor: 15.419

5.  Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis.

Authors:  Xuesong Wu; Jan Riedel; Vy M Dong
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-10       Impact factor: 15.336

6.  Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates.

Authors:  Andrew T Parsons; Todd D Senecal; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2012-02-10       Impact factor: 15.336

7.  Mechanistic studies on intramolecular C-H trifluoromethoxylation of (hetero)arenes via OCF3-migration.

Authors:  Katarzyna N Lee; Zhen Lei; Cristian A Morales-Rivera; Peng Liu; Ming-Yu Ngai
Journal:  Org Biomol Chem       Date:  2016-06-15       Impact factor: 3.876

8.  Electrochemical Azidooxygenation of Alkenes Mediated by a TEMPO-N3 Charge-Transfer Complex.

Authors:  Juno C Siu; Gregory S Sauer; Ambarneil Saha; Reed L Macey; Niankai Fu; Timothée Chauviré; Kyle M Lancaster; Song Lin
Journal:  J Am Chem Soc       Date:  2018-09-12       Impact factor: 15.419

9.  Iron(II)-Catalyzed Azidotrifluoromethylation of Olefins and N-Heterocycles for Expedient Vicinal Trifluoromethyl Amine Synthesis.

Authors:  Cheng-Liang Zhu; Cheng Wang; Qi-Xue Qin; Sam Yruegas; Caleb D Martin; Hao Xu
Journal:  ACS Catal       Date:  2018-04-20       Impact factor: 13.084

10.  Enantioselective functionalization of radical intermediates in redox catalysis: copper-catalyzed asymmetric oxytrifluoromethylation of alkenes.

Authors:  Rong Zhu; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2013-10-16       Impact factor: 15.336
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