| Literature DB >> 21936508 |
Ryo Shintani1, Kohei Moriya, Tamio Hayashi.
Abstract
A palladium-catalyzed desymmetrization of alkyne-tethered silacyclobutanes to give silacycles possessing a tetraorganosilicon stereocenter has been developed, and high chemo- and enantioselectivities have been achieved by the use of a newly synthesized chiral phosphoramidite ligand.Entities:
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Year: 2011 PMID： 21936508 DOI： 10.1021/ja208621x
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419