Literature DB >> 21932847

Laser spark formamide decomposition studied by FT-IR spectroscopy.

M Ferus1, P Kubelík, S Civiš.   

Abstract

High-resolution FT-IR spectroscopy was used for the analysis of the products of formamide dissociation using a high-energy Asterix laser. In the experiment, the detected products of the formamide LIDB dissociation were hydrogen cyanide, ammonia, carbon monoxide, carbon dioxide, nitrous oxide, hydroxylamine, and methanol. The molecular dynamics of the process was simulated with the use of a chemical model. The chemistry shared by formamide and the products of its dissociation is discussed with the respect to the formation of biomolecules.

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Year:  2011        PMID: 21932847     DOI: 10.1021/jp205413d

Source DB:  PubMed          Journal:  J Phys Chem A        ISSN: 1089-5639            Impact factor:   2.781


  4 in total

1.  Meteorite-catalyzed syntheses of nucleosides and of other prebiotic compounds from formamide under proton irradiation.

Authors:  Raffaele Saladino; Eleonora Carota; Giorgia Botta; Mikhail Kapralov; Gennady N Timoshenko; Alexei Y Rozanov; Eugene Krasavin; Ernesto Di Mauro
Journal:  Proc Natl Acad Sci U S A       Date:  2015-04-13       Impact factor: 11.205

2.  Theoretical study of formamide decomposition pathways over (6,0) silicon-carbide nanotube.

Authors:  Mehdi D Esrafili; Mozhgan Ghanbari; Roghaye Nurazar; Parisa Nematollahi
Journal:  J Mol Model       Date:  2015-03-19       Impact factor: 1.810

3.  High-energy chemistry of formamide: a unified mechanism of nucleobase formation.

Authors:  Martin Ferus; David Nesvorný; Jiří Šponer; Petr Kubelík; Regina Michalčíková; Violetta Shestivská; Judit E Šponer; Svatopluk Civiš
Journal:  Proc Natl Acad Sci U S A       Date:  2014-12-08       Impact factor: 11.205

4.  High Energy Radical Chemistry Formation of HCN-rich Atmospheres on early Earth.

Authors:  Martin Ferus; Petr Kubelík; Antonín Knížek; Adam Pastorek; John Sutherland; Svatopluk Civiš
Journal:  Sci Rep       Date:  2017-07-24       Impact factor: 4.379

  4 in total

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