Kai Hong1, James P Morken. 1. Department of Chemistry, Boston College, Chestnut Hill, Massachusetts 02467, United States.
Abstract
The enantioselective 1,4-diboration of cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4-diol, whereas homologation can be used to deliver a chiral 1,6-diol.
The enantioselective 1,4-diboration of n class="Chemical">cyclic dienes with a new taddol-derived phosphonite ligand occurs with excellent enantioselectivity. Oxidation delivers the derived 1,4-diol, whereas homologation can be used to deliver a chiral 1,6-diol.
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