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Literature DB >> 21931931

Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels.

Abstract

Lewis basic DABCO-functionalized 3D-like metal-organic framework, Zn-MOF, catalyzes nitroaldol (Henry) reaction of 4-nitrobenzaldehyde with nitroalkanes in a size-dependent manner. Small nitroalkanes give rise to higher conversion than larger ones. This MOF-based heterogeneous catalyst is very robust and can be recycled several times without losing its activity.

Entities: Chemical

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Year: 2011 PMID： 21931931 DOI： 10.1039/c1dt11274k

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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Cited

6 in total

1. Organic-inorganic supramolecular solid catalyst boosts organic reactions in water.

Authors: Pilar García-García; José María Moreno; Urbano Díaz; Marta Bruix; Avelino Corma
Journal: Nat Commun Date: 2016-02-25 Impact factor: 14.919

2. Synthesis of Metallomacrocycle and Coordination Polymers with Pyridine-Based Amidocarboxylate Ligands and Their Catalytic Activities towards the Henry and Knoevenagel Reactions.

Authors: Anirban Karmakar; Guilherme M D M Rúbio; M Fátima C Guedes da Silva; Armando J L Pombeiro
Journal: ChemistryOpen Date: 2018-11-05 Impact factor: 2.911

Size-dependent catalysis by DABCO-functionalized Zn-MOF with one-dimensional channels.

1. Organic-inorganic supramolecular solid catalyst boosts organic reactions in water.

2. Synthesis of Metallomacrocycle and Coordination Polymers with Pyridine-Based Amidocarboxylate Ligands and Their Catalytic Activities towards the Henry and Knoevenagel Reactions.

3. Single-Layered Hybrid Materials Based on 1D Associated Metalorganic Nanoribbons for Controlled Release of Pheromones.

4. Selective carbon dioxide sorption and heterogeneous catalysis by a new 3D Zn-MOF with nitrogen-rich 1D channels.

5. Cobalt(II)-coordination polymers containing glutarates and bipyridyl ligands and their antifungal potential.

Review 6. Metal-Organic Frameworks as Versatile Heterogeneous Solid Catalysts for Henry Reactions.