Literature DB >> 21913661

Mild and tunable benzoic acid catalysts for rearrangement reactions of allylic alcohols.

J Adam McCubbin1, Samantha Voth, Oleg V Krokhin.   

Abstract

An efficient and simple catalytic method for the isomerization of readily prepared allylic alcohols is described. We focus particularly on cyclic examples and the synthesis of unusual enyne and dienols. The benzoic acid catalysts employed are commercially available and very inexpensive and can be tuned for reactivity and substrate sensitivity.

Entities:  

Year:  2011        PMID: 21913661     DOI: 10.1021/jo201540p

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Evidence for a Sigmatropic and an Ionic Pathway in the Winstein Rearrangement.

Authors:  Amy A Ott; Mary H Packard; Manuel A Ortuño; Alayna Johnson; Victoria P Suding; Christopher J Cramer; Joseph J Topczewski
Journal:  J Org Chem       Date:  2018-06-14       Impact factor: 4.354

2.  FeCl2-Mediated Rearrangement of Allylic Alcohols.

Authors:  Anita A Oppong-Quaicoe; Brenton DeBoef
Journal:  ACS Omega       Date:  2019-03-29
  2 in total

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