Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Oxidation of chloride and subsequent chlorination of organic compounds by oxoiron(IV) porphyrin π-cation radicals.

Literature DB >> 21913293

Oxidation of chloride and subsequent chlorination of organic compounds by oxoiron(IV) porphyrin π-cation radicals.

Zhiqi Cong¹, Takuya Kurahashi, Hiroshi Fujii.

Abstract

Ironing it out: oxoiron(IV) porphyrin π-cation radical complexes serve as models for the oxidation of Cl(-) into an active chlorinating reagent that chlorinates various organic compounds. Evidence suggests that Cl(-) is oxidized to Cl(2) via Cl·. The mechanism involving either direct electron transfer or iron(III) hypochlorite formation, and then homolysis of the Cl-O bond is discussed.

Entities: Chemical

Mesh：

Substances：

Year: 2011 PMID： 21913293 DOI： 10.1002/anie.201104461

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

6 in total

1. Experimental and theoretical studies of the porphyrin ligand effect on the electronic structure and reactivity of oxoiron(iv) porphyrin π-cation-radical complexes.

Authors: Yuri Ishimizu; Zhifeng Ma; Masahiko Hada; Hiroshi Fujii
Journal: J Biol Inorg Chem Date: 2019-05-21 Impact factor: 3.358

2. Toward Environmentally Benign Electrophilic Chlorinations: From Chloroperoxidase to Bioinspired Isoporphyrins.

Authors: Silène Engbers; Ronald Hage; Johannes E M N Klein
Journal: Inorg Chem Date: 2022-05-15 Impact factor: 5.436

3. Singlet versus Triplet Reactivity in an Mn(V)-Oxo Species: Testing Theoretical Predictions Against Experimental Evidence.

Authors: Tzuhsiung Yang; Matthew G Quesne; Heather M Neu; Fabián G Cantú Reinhard; David P Goldberg; Sam P de Visser
Journal: J Am Chem Soc Date: 2016-09-14 Impact factor: 15.419

Oxidation of chloride and subsequent chlorination of organic compounds by oxoiron(IV) porphyrin π-cation radicals.

1. Experimental and theoretical studies of the porphyrin ligand effect on the electronic structure and reactivity of oxoiron(iv) porphyrin π-cation-radical complexes.

2. Toward Environmentally Benign Electrophilic Chlorinations: From Chloroperoxidase to Bioinspired Isoporphyrins.

3. Singlet versus Triplet Reactivity in an Mn(V)-Oxo Species: Testing Theoretical Predictions Against Experimental Evidence.

4. Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes.

Review 5. Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function.

6. Halogenase-Inspired Oxidative Chlorination Using Flavin Photocatalysis.