| Literature DB >> 21910412 |
Jiajia Cheng1, Xuefeng Jiang, Shengming Ma.
Abstract
A three-component Pd(0)-catalyzed reaction of 1,5-bisallenes with organic halides in the presence of primary amines was observed to afford stereodefined not readily available ten-membered cyclic compounds highly chemo- and regioselectively. A mechanism involving two π-allylic palladium intermediates was proposed to account for the observed regio- and stereoselectivity.Entities:
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Year: 2011 PMID： 21910412 DOI： 10.1021/ol202074e
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005