Literature DB >> 21909558

An unsymmetrical coordination environment leading to two slow relaxation modes in a Dy2 single-molecule magnet.

Po-Heng Lin1, Wen-Bin Sun, Mang-Fei Yu, Guang-Ming Li, Peng-Fei Yan, Muralee Murugesu.   

Abstract

A Dy(2) single-molecule magnet was isolated using a mixed ligand strategy in which the Dy(III) ions adopt distinct coordination environments. This leads to two unique relaxation modes due to a single-ion type relaxation mechanism. Energy barriers were obtained from individually fitting the overlapping peaks.

Year:  2011        PMID： 21909558     DOI： 10.1039/c1cc14223b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Structure and magnetism of two chair-shaped hexanuclear dysprosium(iii) complexes exhibiting slow magnetic relaxation.

Authors:  Zi-Yuan Liu; Hua-Hong Zou; Rong Wang; Man-Sheng Chen; Fu-Pei Liang
Journal:  RSC Adv       Date:  2018-01-03       Impact factor: 4.036

2.  Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih.

Authors:  D S Krylov; F Liu; S M Avdoshenko; L Spree; B Weise; A Waske; A U B Wolter; B Büchner; A A Popov
Journal:  Chem Commun (Camb)       Date:  2017-07-11       Impact factor: 6.222

3.  High symmetry or low symmetry, that is the question - high performance Dy(iii) single-ion magnets by electrostatic potential design.

Authors:  Wen-Bin Sun; Peng-Fei Yan; Shang-Da Jiang; Bing-Wu Wang; Yi-Quan Zhang; Hong-Feng Li; Peng Chen; Zhe-Ming Wang; Song Gao
Journal:  Chem Sci       Date:  2015-10-09       Impact factor: 9.825
  3 in total

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