Literature DB >> 21905638

Dehydrogenative Diels-Alder reaction.

Takuya Ozawa1, Takuya Kurahashi, Seijiro Matsubara.   

Abstract

The dehydrogenative cycloaddition of dieneynes, which possess a diene in the form of a styrene moiety and a dienophile in the form of an alkyne moiety, produces naphthalene derivatives when heated. It was found that a key requirement of this process is the presence of a silyl group attached to the alkyne moiety, which forces a dehydrogenation reaction to occur.
© 2011 American Chemical Society

Entities:  

Year:  2011        PMID： 21905638     DOI： 10.1021/ol202283d

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Cyclopenta[b]naphthalene cyanoacrylate dyes: synthesis and evaluation as fluorescent molecular rotors.

Authors:  Laura S Kocsis; Kristyna M Elbel; Billie A Hardigree; Kay M Brummond; Mark A Haidekker; Emmanuel A Theodorakis
Journal:  Org Biomol Chem       Date:  2015-03-14       Impact factor: 3.876

2.  A thermal dehydrogenative Diels-Alder reaction of styrenes for the concise synthesis of functionalized naphthalenes.

Authors:  Laura S Kocsis; Erica Benedetti; Kay M Brummond
Journal:  Org Lett       Date:  2012-08-22       Impact factor: 6.005

3.  Microwave-assisted intramolecular dehydrogenative Diels-Alder reactions for the synthesis of functionalized naphthalenes/solvatochromic dyes.

Authors:  Laura S Kocsis; Erica Benedetti; Kay M Brummond
Journal:  J Vis Exp       Date:  2013-04-01       Impact factor: 1.355

4.  Biomimetic dehydrogenative Diels-Alder cycloadditions: total syntheses of brosimones A and B.

Authors:  Chao Qi; Huan Cong; Katharine J Cahill; Peter Müller; Richard P Johnson; John A Porco
Journal:  Angew Chem Int Ed Engl       Date:  2013-07-01       Impact factor: 15.336
  4 in total

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