| Literature DB >> 21904767 |
Gerardo Martinez-Guajardo1, Zeferino Gómez-Saldoval, Daniel F Jana, Patrizia Calaminici, Clemence Corminboeuf, Gabriel Merino.
Abstract
Here we explore in silico an alternative to make planar eight π-electron bare ring systems with substitutions of some cyclooctatetraene ring carbon atoms by heavier group 14 elements. We found that the most stable eight membered rings with formulae C(4)Si(4)H(8), C(4)Ge(4)H(8), and C(4)Sn(4)H(8) have a perfect planar structure, enhancing delocalization energy as compared to cot.Entities:
Year: 2011 PMID: 21904767 DOI: 10.1039/c1cp22415h
Source DB: PubMed Journal: Phys Chem Chem Phys ISSN: 1463-9076 Impact factor: 3.676