| Literature DB >> 21897982 |
Josée Boudreau1, Marc-André Courtemanche, Frédéric-Georges Fontaine.
Abstract
Species R(2)PCH(2)AlMe(2) (R = Me, Ph) are stable Lewis adducts but still react with CO(2) both in solution and in the solid state. The CO(2) adducts undergo a rearrangement unprecedented for ambiphilic molecules to form aluminium carboxylates. A new spirocyclic compound was also obtained by double Lewis pair activation of CO(2).Entities:
Year: 2011 PMID： 21897982 DOI： 10.1039/c1cc14641f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222