| Literature DB >> 21894888 |
Toru Amaya1, Maiko Hifumi, Michiaki Okada, Yasutomo Shimizu, Toshiyuki Moriuchi, Kouji Segawa, Yoichi Ando, Toshikazu Hirao.
Abstract
Oxosumanenes were synthesized through benzylic oxidation. The electronic and redox properties were revealed to exhibit the expanded π-conjugation compared to sumanene. Single-crystal X-ray analysis of monooxosumanene showed columnar π-stacking in a concave-convex fashion. Stereoselective trimethylation of the trioxo derivative was performed via 1,2-addition to the carbonyl groups.Entities:
Year: 2011 PMID： 21894888 DOI： 10.1021/jo2012412
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354