Literature DB >> 21888434

Ion-controlled on-off switch of electron transfer from tetrathiafulvalene calix[4]pyrroles to Li+@C60.

Shunichi Fukuzumi1, Kei Ohkubo, Yuki Kawashima, Dong Sub Kim, Jung Su Park, Atanu Jana, Vincent M Lynch, Dongho Kim, Jonathan L Sessler.   

Abstract

Binding of chloride anion to a tetrathiafulvalene calix[4]pyrrole (TTF-C4P) donor results in ET to Li(+)@C(60) to produce the radical pair (TTF-C4P(•+)/Li(+)@C(60)(•-)), the structure of which was characterized by X-ray crystallographic analysis. The addition of tetraethylammonium cation, which binds more effectively than Li(+)@C(60)(•-) as a guest within the TTF-C4P cavity, leads to electron back-transfer, restoring the initial oxidation states of the donor and acceptor pair.

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Year:  2011        PMID: 21888434     DOI: 10.1021/ja207588c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  9 in total

1.  Charge transfer and first hyperpolarizability: cage-like radicals C59X and lithium encapsulated Li@C59X (X=B, N).

Authors:  Feng-Wei Gao; Rong-Lin Zhong; Shi-Ling Sun; Hong-Liang Xu; Liang Zhao; Zhong-Min Su
Journal:  J Mol Model       Date:  2015-09-14       Impact factor: 1.810

2.  Interactions of Metal-Based and Ligand-Based Electronic Spins in Neutral Tripyrrindione π Dimers.

Authors:  Ritika Gautam; Andrei V Astashkin; Tsuhen M Chang; Jason Shearer; Elisa Tomat
Journal:  Inorg Chem       Date:  2017-05-12       Impact factor: 5.165

Review 3.  New dimensions in calix[4]pyrrole: the land of opportunity in supramolecular chemistry.

Authors:  Ishfaq Ahmad Rather; Shafieq Ahmad Wagay; Md Saquib Hasnain; Rashid Ali
Journal:  RSC Adv       Date:  2019-11-22       Impact factor: 4.036

4.  The inner-induced effects of YCN in C76 on the structures and nonlinear optical properties.

Authors:  Feng-Wei Gao; Hong-Liang Xu; Zhong-Min Su
Journal:  J Mol Model       Date:  2016-07-06       Impact factor: 1.810

5.  Donor-acceptor type co-crystals of arylthio-substituted tetrathiafulvalenes and fullerenes.

Authors:  Xiaofeng Lu; Jibin Sun; Shangxi Zhang; Longfei Ma; Lei Liu; Hui Qi; Yongliang Shao; Xiangfeng Shao
Journal:  Beilstein J Org Chem       Date:  2015-06-19       Impact factor: 2.883

6.  Ultrafast photoinduced electron transfer in face-to-face charge-transfer π-complexes of planar porphyrins and hexaazatriphenylene derivatives.

Authors:  Toru Aoki; Hayato Sakai; Kei Ohkubo; Tomo Sakanoue; Taishi Takenobu; Shunichi Fukuzumi; Taku Hasobe
Journal:  Chem Sci       Date:  2014-11-28       Impact factor: 9.825

7.  Catalytic two-electron reduction of dioxygen catalysed by metal-free [14]triphyrin(2.1.1).

Authors:  Kentaro Mase; Kei Ohkubo; Zhaoli Xue; Hiroko Yamada; Shunichi Fukuzumi
Journal:  Chem Sci       Date:  2015-08-03       Impact factor: 9.825

8.  Acid/base-regulated reversible electron transfer disproportionation of N-N linked bicarbazole and biacridine derivatives.

Authors:  Palash Pandit; Koji Yamamoto; Toshikazu Nakamura; Katsuyuki Nishimura; Yuki Kurashige; Takeshi Yanai; Go Nakamura; Shigeyuki Masaoka; Ko Furukawa; Yumi Yakiyama; Masaki Kawano; Shuhei Higashibayashi
Journal:  Chem Sci       Date:  2015-05-21       Impact factor: 9.825

9.  Electrochemical reduction of cationic Li+@C60 to neutral Li+@C60˙-: isolation and characterisation of endohedral [60]fulleride.

Authors:  Hiroshi Ueno; Shinobu Aoyagi; Yu Yamazaki; Kei Ohkubo; Naohiko Ikuma; Hiroshi Okada; Tatsuhisa Kato; Yutaka Matsuo; Shunichi Fukuzumi; Ken Kokubo
Journal:  Chem Sci       Date:  2016-06-20       Impact factor: 9.825

  9 in total

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