| Literature DB >> 21882830 |
Jin-Yi Wang1, Han-Xuan Zhang, Kun Jiang, Wen-Bin Cai.
Abstract
The decomposition of HCOOH on Pd surfaces over a potential range of practical relevance to hydrogen production and fuel cell anode operation was probed by combining high-sensitivity in situ surface-enhanced IR spectroscopy with attenuated total reflection and thin-layer flow cell configurations. For the first time, concrete spectral evidence of CO(ad) formation has been obtained, and a new main pathway from HCOOH to CO(ad) involving the reduction of the dehydrogenation product of HCOOH (i.e., CO(2)) is proposed.Entities:
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Year: 2011 PMID： 21882830 DOI： 10.1021/ja205747j
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419