Literature DB >> 21879740

Experimental and theoretical studies on the radical-cation-mediated imino-Diels-Alder reaction.

Raul Pérez-Ruiz1, Luis R Domingo, M Consuelo Jiménez, Miguel A Miranda.   

Abstract

The feasibility of an electron transfer imino-Diels-Alder reaction between N-benzylideneaniline and arylalkenes in the presence of a pyrylium salt as a photosensitizer has been demonstrated by a combination of product studies, laser flash photolysis (LFP), and DFT theoretical calculations. A stepwise mechanism involving two intermediates and two transition states is proposed.
© 2011 American Chemical Society

Entities:  

Year:  2011        PMID: 21879740     DOI: 10.1021/ol201984s

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Aromatic "Redox Tag"-assisted Diels-Alder reactions by electrocatalysis.

Authors:  Yohei Okada; Yusuke Yamaguchi; Atsushi Ozaki; Kazuhiro Chiba
Journal:  Chem Sci       Date:  2016-06-30       Impact factor: 9.825

2.  Radical cation Diels-Alder reactions of arylidene cycloalkanes.

Authors:  Kaii Nakayama; Hidehiro Kamiya; Yohei Okada
Journal:  Beilstein J Org Chem       Date:  2022-08-25       Impact factor: 2.544

  2 in total

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