| Literature DB >> 21879133 |
Donald Craig1, John W Harvey, Alexander G O'Brien, Andrew J P White.
Abstract
Equilibrating mixtures of allylic azide-containing allylic alcohols or allylic 2-tolylsulfonylacetic esters undergo Johnson-Claisen or Ireland-Claisen rearrangement reactions to give unsaturated γ-azidoesters and -acids, respectively. Decarboxylation of the acids under basic conditions gives azidosulfones, with moderate to high diastereoselectivity.Entities:
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Year: 2011 PMID： 21879133 DOI： 10.1039/c1ob05972f
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876