Literature DB >> 21875088

Activation of CO2 by a heterobimetallic Zr/Co complex.

Jeremy P Krogman1, Bruce M Foxman, Christine M Thomas.   

Abstract

At room temperature, the early/late heterobimetallic complex Co((i)Pr(2)PNMes)(3)Zr(THF) has been shown to oxidatively add CO(2), generating (OC)Co((i)Pr(2)PNMes)(2)(μ-O)Zr((i)Pr(2)PNMes). This compound can be further reduced under varying conditions to generate either the Zr oxoanion (THF)(3)Na-O-Zr(MesNP(i)Pr(2))(3)Co(CO) or the Zr carbonate complex (THF)(4)Na(2)(CO(3))-Zr(MesNP(i)Pr(2))(3)Co(CO). Additionally, reactivity of the CO(2)-derived product has been observed with PhSiH(3) to generate the Co-hydride/Zr-siloxide product (OC)(H)Co((i)Pr(2)PNMes)(3)ZrOSiH(2)Ph.

Entities:  

Year:  2011        PMID： 21875088     DOI： 10.1021/ja2071847

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  12 in total

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