Literature DB >> 21875048

Lewis acid-promoted addition of 1,3-bis(silyl)propenes to aldehydes: a route to 1,3-dienes.

Tessie Borg1, Pavel Tuzina, Peter Somfai.   

Abstract

The Lewis acid-promoted addition of 1,3-bis(silyl)propenes to aldehydes to provide the corresponding (E)-1,3-dienes in excellent stereoselectivity and good to excellent yields is reported. The procedure is mild, base-free, and operationally straightforward.

Entities:  

Year:  2011        PMID: 21875048     DOI: 10.1021/jo2013466

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Synthesis of Novel C-Pivot Lariat 18-Crown-6 Ethers and their Efficient Purification.

Authors:  Susovan Jana; Vallabh Suresh; Salvatore D Lepore
Journal:  Synlett       Date:  2015-07-29       Impact factor: 2.454

Review 2.  Modern Synthetic Methods for the Stereoselective Construction of 1,3-Dienes.

Authors:  Raquel G Soengas; Humberto Rodríguez-Solla
Journal:  Molecules       Date:  2021-01-06       Impact factor: 4.411

  2 in total

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